Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-22T20:16:34.989Z Has data issue: false hasContentIssue false
  • English
  • Français

Generation three-dimensional nitrogen-doped graphene frameworks as advanced electrode for supercapacitors

Published online by Cambridge University Press:  25 October 2017

Wenxian Guo ,
Meiqiong Chen Open the ORCID record for Meiqiong Chen [Opens in a new window] ,
Yan Zhang ,
Wenna Yang ,
Qiyao Guo ,
Min Zhang  and
Faliang Cheng
Wenxian Guo
Affiliation:
Department of City and Environment Science, City College of Dongguan University of Technology, Dongguan, Guangdong 523419, China
Meiqiong Chen*
Affiliation:
Department of City and Environment Science, City College of Dongguan University of Technology, Dongguan, Guangdong 523419, China
Yan Zhang
Affiliation:
Department of City and Environment Science, City College of Dongguan University of Technology, Dongguan, Guangdong 523419, China
Wenna Yang
Affiliation:
Department of City and Environment Science, City College of Dongguan University of Technology, Dongguan, Guangdong 523419, China
Qiyao Guo
Affiliation:
Department of City and Environment Science, City College of Dongguan University of Technology, Dongguan, Guangdong 523419, China
Min Zhang
Affiliation:
Guangdong Engineering and Technology Research Center for Advanced Nanomaterials, Dongguan University of Technology, Dongguan, Guangdong 523808, China
Faliang Cheng
Affiliation:
Guangdong Engineering and Technology Research Center for Advanced Nanomaterials, Dongguan University of Technology, Dongguan, Guangdong 523808, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Three-dimensional nitrogen-doped graphene frameworks (3DNGFs) hold great promise in the application of supercapacitors for the advantages of superior conductivity, well-connected porous structure, and additional N-containing active sites for charge storage. Nevertheless, the developed techniques for preparing 3DNGFs always suffer from the drawbacks of high cost or complex processes for large-scale application. Herein, a new and cost-effective method has been developed to massively prepare monolithic 3DNGFs by a simple and scalable electrochemical oxidation process. Benefiting from the enhanced electrical conductivity, the increase in the pore volume for fast diffusion increased the electrode–electrolyte contact area and additional active sites resulting from the incorporation of nitrogen species, the 3DNGFs showed a high specific capacitance of 2250.3 mF/cm2 at 4 mA/cm2, with good rate capability. Furthermore, this 3DNGFs electrode also owns an excellent long-term cycling stability that can retain more than 97.5% of its original capacitance after 10,000 cycles.

Keywords

electrochemical synthesiselectrical propertiesenergy storage
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 9: Focus Issue: Porous Carbon and Carbonaceous Materials for Energy Conversion and Storage , 14 May 2018 , pp. 1131 - 1141
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Yat Li

References

REFERENCES

Yu, M., Zhao, S., Feng, H., Hu, L., Zhang, X., Zeng, Y., Tong, Y., and Lu, X.: Engineering thin MoS2 nanosheets on TiN nanorods: Advanced electrochemical capacitor electrode and hydrogen evolution electrocatalyst. ACS Energy Lett. 2, 1862 (2017).Google Scholar
Wang, X. and Lee, P.S.: A polydopamine coated polyaniline single wall carbon nanotube composite material as a stable supercapacitor cathode in an organic electrolyte. J. Mater. Res. 30(23), 3575 (2015).Google Scholar
Zeng, Y., Yu, M., Meng, Y., Fang, P., Lu, X., and Tong, Y.: Iron-based supercapacitor electrodes: Advances and challenges. Adv. Energy Mater. 6(24), 1601053 (2016).Google Scholar
Zhai, T., Wan, L., Sun, S., Chen, Q., Sun, J., Xia, Q., and Xia, H.: Phosphate ion functionalized Co3O4 ultrathin nanosheets with greatly improved surface reactivity for high performance pseudocapacitors. Adv. Mater. 29(7) (2017).Google Scholar
Zhai, T., Lu, X., Wang, H., Wang, G., Mathis, T., Liu, T., Li, C., Tong, Y., and Li, Y.: An electrochemical capacitor with applicable energy density of 7.4 W h/kg at average power density of 3000 W/kg. Nano Lett. 15(5), 3189 (2015).Google Scholar
Yu, M., Lin, D., Feng, H., Zeng, Y., Tong, Y., and Lu, X.: Boosting the energy density of carbon-based aqueous supercapacitors by optimizing the surface charge. Angew. Chem., Int. Ed. Engl. 56(20), 5454 (2017).CrossRefGoogle ScholarPubMed
Wang, Z.F., Han, Y., Zeng, Y.X., Qie, Y.L., Wang, Y.C., Zheng, D.Z., Lu, X.H., and Tong, Y.X.: Activated carbon fiber paper with exceptional capacitive performance as a robust electrode for supercapacitors. J. Mater. Chem. A 4(16), 5828 (2016).Google Scholar
Li, D., Li, Y., Zhao, J., Xu, Z., and Zhang, H.: Three-dimensional porous layered double hydroxides growing on carbon cloth as binder-free electrodes for supercapacitors. J. Mater. Res. 32(13), 2487 (2017).CrossRefGoogle Scholar
Usman, M., Pan, L., Asif, M., and Mahmood, Z.: Nickel foam–graphene/MnO2/PANI nanocomposite based electrode material for efficient supercapacitors. J. Mater. Res. 30(21), 3192 (2015).Google Scholar
Zhang, L., Lin, H., Zhai, L., Nie, M., Zhou, J., and Zhuo, S.: Enhanced supercapacitor performance based on 3D porous graphene with MoO2 nanoparticles. J. Mater. Res. 32(02), 292 (2016).Google Scholar
Kim, K.H., Oh, Y., and Islam, M.: Graphene coating makes carbon nanotube aerogels superelastic and resistant to fatigue. Nat. Nanotechnol. 7(9), 562 (2012).Google Scholar
Wu, Z-S., Sun, Y., Tan, Y-Z., Yang, S., Feng, X., and Müllen, K.: Three-dimensional graphene-based macro-and mesoporous frameworks for high-performance electrochemical capacitive energy storage. J. Am. Chem. Soc. 134(48), 19532 (2012).Google Scholar
Moon, I.K., Yoon, S., Chun, K.Y., and Oh, J.: Highly elastic and conductive N-doped monolithic graphene aerogels for multifunctional applications. Adv. Funct. Mater. 25(45), 6976 (2015).CrossRefGoogle Scholar
Wu, Z.S., Winter, A., Chen, L., Sun, Y., Turchanin, A., Feng, X., and Müllen, K.: Three-dimensional nitrogen and boron Co-doped graphene for high-performance all-solid-state supercapacitors. Adv. Mater. 24(37), 5130 (2012).Google Scholar
Xu, Y., Sheng, K., Li, C., and Shi, G.: Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 4(7), 4324 (2010).Google Scholar
Chen, P., Yang, J-J., Li, S-S., Wang, Z., Xiao, T-Y., Qian, Y-H., and Yu, S-H.: Hydrothermal synthesis of macroscopic nitrogen-doped graphene hydrogels for ultrafast supercapacitor. Nano Energy 2(2), 249 (2013).Google Scholar
Xu, Y., Lin, Z., Huang, X., Liu, Y., Huang, Y., and Duan, X.: Flexible solid-state supercapacitors based on three-dimensional graphene hydrogel films. ACS Nano 7(5), 4042 (2013).CrossRefGoogle ScholarPubMed
Cao, X., Shi, Y., Shi, W., Lu, G., Huang, X., Yan, Q., Zhang, Q., and Zhang, H.: Preparation of novel 3D graphene networks for supercapacitor applications. Small 7(22), 3163 (2011).Google Scholar
Chen, Z., Ren, W., Gao, L., Liu, B., Pei, S., and Cheng, H-M.: Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nat. Mater. 10(6), 424 (2011).Google Scholar
Chen, J., Sheng, K., Luo, P., Li, C., and Shi, G.: Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors. Adv. Mater. 24(33), 4569 (2012).Google Scholar
Lv, L., Zhang, P., Cheng, H., Zhao, Y., Zhang, Z., Shi, G., and Qu, L.: Solution-processed ultraelastic and strong air-bubbled graphene foams. Small 12(24), 3229 (2016).Google Scholar
Wang, J., Shi, Z., Fan, J., Ge, Y., Yin, J., and Hu, G.: Self-assembly of graphene into three-dimensional structures promoted by natural phenolic acids. J. Mater. Chem. 22(42), 22459 (2012).Google Scholar
Yu, M., Huang, Y., Li, C., Zeng, Y., Wang, W., Li, Y., Fang, P., Lu, X., and Tong, Y.: Building three-dimensional graphene frameworks for energy storage and catalysis. Adv. Funct. Mater. 25(2), 324 (2015).Google Scholar
Wang, Y., Wei, Z., Nie, Y., and Zhang, Y.: Generation of three dimensional pore-controlled nitrogen-doped graphene hydrogels for high-performance supercapacitors by employing formamide as the modulator. J. Mater. Chem. A 5(4), 1442 (2017).Google Scholar
Luan, F., Wang, G.M., Ling, Y.C., Lu, X.H., Wang, H.Y., Tong, Y.X., Liu, X.X., and Li, Y.: High energy density asymmetric supercapacitors with a nickel oxide nanoflake cathode and a 3D reduced graphene oxide anode. Nanoscale 5(17), 7984 (2013).Google Scholar
Li, C., Hu, Y., Yu, M.H., Wang, Z.F., Zhao, W.X., Liu, P., Tong, Y.X., and Lu, X.H.: Nitrogen doped graphene paper as a highly conductive, and light-weight substrate for flexible supercapacitors. RSC Adv. 4(94), 51878 (2014).Google Scholar
Song, X., Lin, L., Rong, M., Wang, Y., Xie, Z., and Chen, X.: Mussel-inspired, ultralight, multifunctional 3D nitrogen-doped graphene aerogel. Carbon 80, 174 (2014).Google Scholar
Lin, T., Chen, I-W., Liu, F., Yang, C., Bi, H., Xu, F., and Huang, F.: Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science 350(6267), 1508 (2015).Google Scholar
Wang, T., Wang, L., Wu, D., Xia, W., Zhao, H., and Jia, D.: Hydrothermal synthesis of nitrogen-doped graphene hydrogels using amino acids with different acidities as doping agents. J. Mater. Chem. A 2(22), 8352 (2014).Google Scholar
Qin, Y., Yuan, J., Li, J., Chen, D., Kong, Y., Chu, F., Tao, Y., and Liu, M.: Crosslinking graphene oxide into robust 3D porous N-doped graphene. Adv. Mater. 27(35), 5171 (2015).Google Scholar
Zhang, L.L., Zhao, X., Ji, H., Stoller, M.D., Lai, L., Murali, S., Mcdonnell, S., Cleveger, B., Wallace, R.M., and Ruoff, R.S.: Nitrogen doping of graphene and its effect on quantum capacitance, and a new insight on the enhanced capacitance of N-doped carbon. Energy Environ. Sci. 5(11), 9618 (2012).CrossRefGoogle Scholar
Sui, Z-Y., Meng, Y-N., Xiao, P-W., Zhao, Z-Q., Wei, Z-X., and Han, B-H.: Nitrogen-doped graphene aerogels as efficient supercapacitor electrodes and gas adsorbents. ACS Appl. Mater. Interfaces 7(3), 1431 (2015).CrossRefGoogle ScholarPubMed
Wei, D., Liu, Y., Wang, Y., Zhang, H., Huang, L., and Yu, G.: Synthesis of N-doped graphene by chemical vapor deposition and its electrical properties. Nano Lett. 9(5), 1752 (2009).Google Scholar
Jin, Z., Yao, J., Kittrell, C., and Tour, J.M.: Large-scale growth and characterizations of nitrogen-doped monolayer graphene sheets. ACS Nano 5(5), 4112 (2011).Google Scholar
Li, N., Wang, Z., Zhao, K., Shi, Z., Gu, Z., and Xu, S.: Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method. Carbon 48(1), 255 (2010).Google Scholar
Jafri, R.I., Rajalakshmi, N., and Ramaprabhu, S.: Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell. J. Mater. Chem. 20(34), 7114 (2010).Google Scholar
Jeong, H.M., Lee, J.W., Shin, W.H., Choi, Y.J., Shin, H.J., Kang, J.K., and Choi, J.W.: Nitrogen-doped graphene for high-performance ultracapacitors and the importance of nitrogen-doped sites at basal planes. Nano Lett. 11(6), 2472 (2011).Google Scholar
Li, H., Liang, S., Li, J., and He, L.: The capacitive deionization behaviour of a carbon nanotube and reduced graphene oxide composite. J. Mater. Chem. A 1(21), 6335 (2013).Google Scholar
Wen, X., Zhang, D., Yan, T., Zhang, J., and Shi, L.: Three-dimensional graphene-based hierarchically porous carbon composites prepared by a dual-template strategy for capacitive deionization. J. Mater. Chem. A 1(39), 12334 (2013).Google Scholar
Sun, L., Wang, L., Tian, C., Tan, T., Xie, Y., Shi, K., Li, M., and Fu, H.: Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage. RSC Adv. 2(10), 4498 (2012).Google Scholar
Xu, X., Pan, L., Liu, Y., Lu, T., and Sun, Z.: Enhanced capacitive deionization performance of graphene by nitrogen doping. J. Colloid Interface Sci. 445, 143 (2015).Google Scholar
Chen, M., Zeng, Y., Zhao, Y., Yu, M., Cheng, F., Lu, X., and Tong, Y.: Monolithic three-dimensional graphene frameworks derived from inexpensive graphite paper as advanced anodes for microbial fuel cells. J. Mater. Chem. A 4(17), 6342 (2016).Google Scholar
Chen, K. and Xue, D.: Preparation of colloidal graphene in quantity by electrochemical exfoliation. J. Colloid Interface Sci. 436, 41 (2014).Google Scholar
Zhu, Y., Murali, S., Cai, W., Li, X., Suk, J.W., Potts, J.R., and Ruoff, R.S.: Graphene and graphene oxide: Synthesis, properties, and applications. Adv. Mater. 22(35), 3906 (2010).Google Scholar
Xiao, K., Ding, L-X., Chen, H., Wang, S., Lu, X., and Wang, H.: Nitrogen-doped porous carbon derived from residuary shaddock peel: A promising and sustainable anode for high energy density asymmetric supercapacitors. J. Mater. Chem. A 4(2), 372 (2016).Google Scholar
Gorgulho, H.F., Gonçalves, F., Pereira, M.F.R., and Figueiredo, J.L.: Synthesis and characterization of nitrogen-doped carbon xerogels. Carbon 47(8), 2032 (2009).Google Scholar
Yang, K., Peng, L., Shu, D., Lv, C., He, C., and Long, L.: Capacitive performance of a heteroatom-enriched activated carbon in concentrated sulfuric acid. J. Power Sources 239, 553 (2013).Google Scholar
Shao, Y., Wang, J., Engelhard, M., Wang, C., and Lin, Y.: Facile and controllable electrochemical reduction of graphene oxide and its applications. J. Mater. Chem. 20(4), 743 (2010).Google Scholar
Chen, Y., Zhang, X., Zhang, D., Yu, P., and Ma, Y.: High performance supercapacitors based on reduced graphene oxide in aqueous and ionic liquid electrolytes. Carbon 49(2), 573 (2011).Google Scholar
Zhai, T., Wang, F.X., Yu, M.H., Xie, S.L., Liang, C.L., Li, C., Xiao, F.M., Tang, R.H., Wu, Q.X., Lu, X.H., and Tong, Y.X.: 3D MnO2-graphene composites with large areal capacitance for high-performance asymmetric supercapacitors. Nanoscale 5(15), 6790 (2013).CrossRefGoogle ScholarPubMed
Ramadoss, A., Yoon, K-Y., Kwak, M-J., Kim, S-I., Ryu, S-T., and Jang, J-H.: Fully flexible, lightweight, high performance all-solid-state supercapacitor based on 3-dimensional-graphene/graphite-paper. J. Power Sources 337, 159 (2017).Google Scholar
Zhou, Q., Ye, X., Wan, Z., and Jia, C.: A three-dimensional flexible supercapacitor with enhanced performance based on lightweight, conductive graphene-cotton fabric electrode. J. Power Sources 296, 186 (2015).Google Scholar
Supplementary material: File

Guo et al supplementary material

Figures S1-S10

Download Guo et al supplementary material(File)
File 3.7 MB