Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-23T12:02:28.642Z Has data issue: false hasContentIssue false
  • English
  • Français

Fabrication of highly porous TiAl3 intermetallics using titanium hydride as a reactant in the thermal explosion reaction

Published online by Cambridge University Press:  23 August 2018

Xinyang Jiao ,
Peizhong Feng ,
Yanan Liu ,
Xiaoping Cai ,
Jianzhong Wang  and
Tomasz Czujko
Xinyang Jiao
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, People’s Republic of China; and School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, People’s Republic of China
Peizhong Feng*
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, People’s Republic of China
Yanan Liu
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, People’s Republic of China
Xiaoping Cai
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, People’s Republic of China
Jianzhong Wang
Affiliation:
State Key Laboratory of Porous Metal Materials, Northwest Institute for Non-ferrous Metal Research, Xian 710016, China
Tomasz Czujko
Affiliation:
Department of Advanced Materials and Technologies, Faculty of Advanced Technologies and Chemistry, Military University of Technology, Warszawa 00-908, Poland
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Porous TiAl3 intermetallics were synthesized by the thermal explosion (TE) reaction from TiH2–75 at.% Al elemental powders combining with carbamide as the space holder. The results showed that the space holder particles were removed completely by dissolving in water before sintering and the violent exothermic reaction occurred from the temperature of 672–1193 °C within a few seconds. After TE, TiAl3 was the dominant phase in sintered products and the open porosity of 60.8% was obtained without space holder, while the porosity considerably increased to 81.4% with the addition of 60 vol% carbamide particles. The pore-forming mechanism can be concluded as follows: the sphere large pores replicated from carbamide particles and the small pores generated by the TE reaction. Moreover, porous TiAl3 intermetallics possess the excellent oxidation resistance at 650 °C in air, which enabled them good candidate materials for improving the service life and the accuracy of filtration under special conditions.

Keywords

combustion synthesisporositymicrostructure
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 18 , 28 September 2018 , pp. 2680 - 2688
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Kayani, S.H. and Park, N.K.: Effect of Cr and Nb on the phase transformation and pore formation of Ti–Al base alloys. J. Alloys Compd. 708, 308 (2017).CrossRefGoogle Scholar
Sina, H. and Iyengar, S.: Reactive synthesis and characterization of titanium aluminides produced from elemental powder mixtures. J. Therm. Anal. Calorim. 122, 1 (2015).CrossRefGoogle Scholar
Wang, Z., Jiao, X., and Feng, P.: Highly porous open cellular TiAl-based intermetallics fabricated by thermal explosion with space holder process. Intermetallics 68, 95 (2016).CrossRefGoogle Scholar
Cui, H., Cao, L., and Chen, Y.: Unique microstructure of porous NiAl intermetallic compound prepared by combustion synthesis. J. Porous Mater. 19, 415 (2012).CrossRefGoogle Scholar
Zhang, H., Feng, P., and Akhtar, F.: Aluminium matrix tungsten aluminide and tungsten reinforced composites by solid-state diffusion mechanism. Sci. Rep. 7, 12391 (2017).CrossRefGoogle ScholarPubMed
Nakamura, M., Hashimoto, K., and Tsujimoto, T.: Environmental effect on mechanical properties of TiAl base alloys. J. Mater. Res. 8, 68 (1993).CrossRefGoogle Scholar
Feng, P., Jian, S., and Zhou, Y.: Microstructure and formation mechanism of porous Ti–Al intermetallics prepared by pressureless sintering. Rare Met. Mater. Eng. 44, 2721 (2015).Google Scholar
Yeh, C.L. and Sun, W.E.: Use of TiH2 as a reactant in combustion synthesis of porous Ti5Si3 and Ti5Si3/TiAl intermetallics. J. Alloys Compd. 66, 669 (2016).Google Scholar
Jokisaari, J.R., Bhaduri, S., and Bhaduri, S.B.: Microwave activated combustion synthesis of titanium aluminides. Mater. Sci. Eng., A 394, 385 (2005).CrossRefGoogle Scholar
Jiao, X., Wang, X., and Kang, X.: Hierarchical porous TiAl3 intermetallics synthesized by thermal explosion with a leachable space-holder material. Mater. Lett. 181, 261 (2016).CrossRefGoogle Scholar
Li, S., Zou, X., and Zheng, K.: Direct production of TiAl3 from Ti/Al-containing oxides precursors by solid oxide membrane (SOM) process. J. Alloys Compd. 727, 1243 (2017).CrossRefGoogle Scholar
Mirjalili, M. and Soltanieh, M.: On the kinetics of TiAl3 intermetallic layer formation in the titanium and aluminum diffusion couple. Intermetallics 32, 297 (2013).CrossRefGoogle Scholar
He, Y. H., Jiang, Y., and Xu, N. P.: Fabrication of Ti–Al micro/nanometer-sized porous alloys through the kirkendall effect. Adv. Mater. 19, 2102 (2010).CrossRefGoogle Scholar
Fu, Y., Shi, R., and Zhang, J.: Microstructure and mechanical behavior of a multiphase Al3Ti-based intermetallic alloy. Intermetallics 8, 1251 (2000).CrossRefGoogle Scholar
Karpets, M.V., Milman, Y.V., and Barabash, O.M.: The influence of Zr alloying on the structure and properties of AlTi. Intermetallics 11, 241 (2003).CrossRefGoogle Scholar
Zhang, Q., Xiao, B.L., and Wang, D.: Formation mechanism of in situ Al3Ti in Al matrix during hot pressing and subsequent friction stir processing. Mater. Chem. Phys. 130, 1109 (2011).CrossRefGoogle Scholar
Cai, X., Liu, Y., and Feng, P.: Fe–Al intermetallic foam with porosity above 60% prepared by thermal explosion. J. Alloys Compd. 732, 443 (2017).CrossRefGoogle Scholar
Jiao, X., Ren, X., and Wang, X.: Porous TiAl3 intermetallics with symmetrical graded pore-structure fabricated by leaching space holder and thermal explosion process. Intermetallics 95, 144 (2018).CrossRefGoogle Scholar
Khoptiar, Y. and Gotman, I.: Ti2AlC ternary carbide synthesized by thermal explosion. Mater. Lett. 57, 72 (2002).CrossRefGoogle Scholar
Liang, Y.H., Qian, Z., and Han, Z.W.: Reaction behavior of TiC/Cu composite via thermal explosion reaction (TE) under Ar and air atmosphere. Corros. Sci. 93, 283 (2015).CrossRefGoogle Scholar
Kim, S., Kim, G., and Lee, W.: A novel method to fabricate reinforced Ti composites by infiltration of Al (Mg) into porous titanium. J. Alloys Compd. 715, 404 (2017).CrossRefGoogle Scholar
Peng, Q., Yang, B., and Liu, L.: Porous TiAl alloys fabricated by sintering of TiH2 and Al powder mixtures. J. Alloys Compd. 656, 530 (2016).CrossRefGoogle Scholar
Jiang, Y., He, Y.H., and Xu, N.P.: Effects of the Al content on pore structures of porous Ti–Al alloys. Intermetallics 16, 327 (2008).CrossRefGoogle Scholar
Liu, Z., Han, Q., and Li, J.: Fabrication of in situ Al3Ti/Al composites by using ultrasound assisted direct reaction between solid Ti powders and liquid Al. Powder Technol. 247, 55 (2013).CrossRefGoogle Scholar
Wang, Z., Shao, H.P., and Ye, Q.: Preparation of TiAl alloy powders by reaction of titanium hydride and aluminum in high vacuum. J. Funct. Mater. 45, 10045 (2014).Google Scholar
Łazińska, M., Durejko, T., and Lipiński, S.: Porous graded FeAl intermetallic foams fabricated by sintering process using NaCl space holders. Mater. Sci. Eng., A 636, 407 (2015).CrossRefGoogle Scholar
Ye, S., Hao, H., and Mo, W.: Effects of cold compacting pressure on the expansion behavior of Ti–48Al during sintering. J. Alloys Compd. 673, 399 (2016).CrossRefGoogle Scholar
Liang, Y., Yang, F., and Zhang, L.: Reaction behavior and pore formation mechanism of TiAl–Nb porous alloys prepared by elemental powder metallurgy. Intermetallics 44, 1 (2014).CrossRefGoogle Scholar
Shi, Q., Qin, B., and Feng, P.: Synthesis, microstructure and properties of Ti–Al porous intermetallic compounds prepared by thermal explosion reaction. RSC Adv. 5, 46339 (2015).CrossRefGoogle Scholar
Kennedy, A.R. and Lopez, V.H.: The decomposition behavior of as-received and oxidized TiH2 foaming-agent powder. Mater. Sci. Eng., A 357, 258 (2003).CrossRefGoogle Scholar

Jiao et al. supplementary material

Jiao et al. supplementary material 1

Download Jiao et al. supplementary material(Video)
Video 3.9 MB