Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-26T12:30:05.908Z Has data issue: false hasContentIssue false
  • English
  • Français

Crystallization and dielectric properties of SrO–BaO–Nb2O5–GeO2 tungsten–bronze glass–ceramics

Published online by Cambridge University Press:  31 January 2011

Jiin-Jyh Shyu  and
Hsin-Wei Peng
Jiin-Jyh Shyu
Affiliation:
Department of Materials Engineering, Tatung University, Taipei 104, Taiwan, People's Republic of China
Hsin-Wei Peng
Affiliation:
Department of Materials Engineering, Tatung University, Taipei 104, Taiwan, People's Republic of China
Get access

Abstract

The crystallization and dielectric properties of SrO–BaO–Nb2O5–GeO2 glass–ceramics were investigated. One- and two-stage heat-treatment methods were used to convert the parent glass to glass–ceramics. Strontium barium niobate (SBN) with a tetragonal tungsten-bronze structure formed as the major crystalline phase. When the crystallizing temperature/time was increased, the secondary crystalline BaGe2O5 phase coexisted with SBN. BaGe2O5 formed as a surface layer grown from the surface into the interior of the sample. The dendritic morphology of SBN crystals was examined. The glass–ceramics crystallized by two-stage heat treatment have higher dielectric constants than those crystallized by one-stage heat treatment. The highest dielectric constant that was obtained in the present glass–ceramics was 320. The glass–ceramics showed relaxor-type dielectric behavior.

Type
Articles
Information
Journal of Materials Research , Volume 16 , Issue 7 , July 2001 , pp. 2057 - 2063
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

.Herczog, A., J. Am. Ceram. Soc. 47, 107 (1964).CrossRefGoogle Scholar
.Bhargava, , Shelby, J.E., and Snyder, R.L., J. Non-Cryst. Solids 102, 136 (1988).CrossRefGoogle Scholar
.McCauley, D., Newnham, R.E., and Randall, C.A., J. Am. Ceram. Soc. 81, 979 (1998).CrossRefGoogle Scholar
.Grossman, D.G. and Isard, J.O., J. Phys. D, 3, 1058 (1970).Google Scholar
.Kokubo, T. and Tashiro, M., J. Non-Cryst. Solids 13, 328 (1973/1974).Google Scholar
.Lynch, S.M. and Shelby, J.E., J. Am. Ceram. Soc. 67, 424 (1984).CrossRefGoogle Scholar
.Shyu, J.J. and Yang, Y.S., J. Am. Ceram. Soc. 78, 1463 (1995).CrossRefGoogle Scholar
.Vernacotola, D.E., in Rare Elements in Glasses, edited by Shelby, J.E. (Trans Tech Publications Ltd., Vetikon-Zuerich, Swit-zerland, 1994), p. 379.Google Scholar
.Zeng, H.C., Tanaka, K., Hirao, K., and Soga, N., J. Non-Cryst. Solids 209, 112 (1997).CrossRefGoogle Scholar
.Todorović, M. and Radonjić, Lj., Ceram. Int. 23, 55 (1997).CrossRefGoogle Scholar
.Todorović, M. and Radonjić, Lj., in Ceramics Today-Tomorrow’s Ceramics, edited by P. Vincenzini (Elsevier, Amsterdam, The Netherlands, 1991), p. 1999.Google Scholar
.Borelli, N.F. and Layton, M.M., J. Non-Cryst. Solids 6, 197 (1971).CrossRefGoogle Scholar
.Layton, M.M. and Smith, J.M., J. Am. Ceram. Soc. 58, 435 (1975).CrossRefGoogle Scholar
.Herczog, A., J. Am. Ceram. Soc. 73, 2743 (1990).CrossRefGoogle Scholar
.Komatsu, T., Onuma, J., Kim, H.G., and Kim, J.R., J. Mater. Sci. Lett. 15, 2130 (1996).Google Scholar
.Reece, M.J., Worrell, C.A., Hill, G.J., and Morrell, R., J. Am. Ceram. Soc. 79, 17 (1996).CrossRefGoogle Scholar
.Herczog, A., IEEE Trans. Parts, Hybrids, Packag. PHP–9, 247 (1973).CrossRefGoogle Scholar
.Cherukuri, S.C. and Dey, S.K., in Ceramic Transactions, Vol. 20: Glasses for Electronic Applications, edited by Nair, K.M. (The American Ceramic Society, Inc., Westerville, OH, 1991), p. 355.Google Scholar
.Xu, Y., inFerroelectric Materials and Their Applications (Elsevier Science, New York, 1991), p. 254.Google Scholar
.Deshpande, S.B., Potdar, H.S., Godbole, P.D., and Date, S.K., J. Am. Ceram. Soc. 75, 2581 (1992).CrossRefGoogle Scholar
.VanDamme, N.S., Sutherland, A.E., Jones, L., Bridger, K., and Winzer, S.R., J. Am. Ceram. Soc. 74, 1785 (1991).CrossRefGoogle Scholar
.Chen, C.J., Xu, Y., Xu, R., and Mackenzie, J.D., in Ceramic Trans-actions, Vol. 14: Electro-Optics and Nonlinear Optic Materials, edited by Bhalla, A.S., Vogel, E.M., and Nair, K.M. (The American Ceramic Society, Westerville, OH, 1990), p. 211.Google Scholar
.Shyu, J.J. and Wang, J.R., J. Am. Ceram. Soc. 83, 3135 (2000).CrossRefGoogle Scholar
.Uhlmann, D.R. and Uhlmann, E.V., in Ceramic Transactions, Vol. 30: Nucleation and Crystallization in Liquids and Glasses, edited by Weinberg, M.C. (The American Ceramic Society, Westerville, OH, 1993), p. 109.Google Scholar
.Swartz, S., Breval, E., Randall, C.A., and Fox, B.H., J. Mater. Sci. 23, 3997 (1988).CrossRefGoogle Scholar
.Kokubo, T., Ito, S., and Sakka, S., J. Mater. Sci. 21, 536 (1986).CrossRefGoogle Scholar
.Tsurumi, T. and Hoshino, Y., J. Am. Ceram. Soc. 72, 278 (1989).CrossRefGoogle Scholar
.Takashige, M., Mitsui, T., Nakamura, T., Aikawa, Y., and Jang, M.S., Jpn. J. Appl. Phys. 20, L159 (1981).CrossRefGoogle Scholar
.Uchino, K., Sadanaga, E., Oonishi, K., Morohashi, T., and Yamamura, H., in Ceramic Transactions, Vol. 8: Ceramic Dielec-trics: Composition, Processing and Properties, edited by Ling, H.C. and Yan, M.F. (The American Ceramic Society, Westerville, OH, 1990), p. 107.Google Scholar
.Arit, G., Hennings, D., and de With, G., J. Appl. Phys. 58, 1619 (1985).Google Scholar
.Yamaji, A., Enomoto, Y., Kinoshita, K., and Murakami, T., J. Am. Ceram. Soc. 60, 97 (1977).CrossRefGoogle Scholar
.Glass, A.M., J. Appl. Phys. 40, 4699 (1969).CrossRefGoogle Scholar
.Trubelja, M.P., Ryba, E., and Smith, D.K., J. Mater. Sci. 34, 1435 (1996).CrossRefGoogle Scholar