Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-26T17:49:15.083Z Has data issue: false hasContentIssue false
  • English
  • Français

Transamidation: A feasible approach of surface modification to improve absorbency under load of agricultural superabsorbent materials

Published online by Cambridge University Press:  28 August 2018

Akhtar Azizi ,
Kourosh Kabiri ,
Mohammad Jalal Zohuriaan-Mehr ,
Hossein Bouhendi  and
Zeinab Karami
Akhtar Azizi
Affiliation:
Adhesive and Resin Department, Polymer Processing Faculty, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran
Kourosh Kabiri*
Affiliation:
Adhesive and Resin Department, Polymer Processing Faculty, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran
Mohammad Jalal Zohuriaan-Mehr
Affiliation:
Adhesive and Resin Department, Polymer Processing Faculty, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran
Hossein Bouhendi
Affiliation:
Adhesive and Resin Department, Polymer Processing Faculty, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran
Zeinab Karami
Affiliation:
Adhesive and Resin Department, Polymer Processing Faculty, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

This research introduces a novel single-step approach to improve the absorbency under load (AUL) of agricultural superabsorbent polymers (SAPs) made of acrylamide. Crosslinked (acrylamide–potassium acrylate–acrylic acid) terpolymers were successfully prepared and modified via a transamidation (amide exchange) reaction. The surface of the polymer particles was treated using polyamine modifiers (i.e., diethylenetriamine and polyethyleneimine) in the presence or absence of AlCl3 as a catalyst. The modification reaction was confirmed via spectral, morphological, and rheological studies. The process variables including time and temperature, the modifier type and amount, and the catalyst concentration were found to affect the polymer swelling properties. The swelling capacity of the control and treated SAPs were determined in deionized water and saline. The AUL in saline, as a key swelling property of SAPs, was also determined. The AUL of the PEI-treated samples (19.82–24.8 g/g) was higher than those of the control (17.7 g/g) and the DETA-treated SAPs (18.3–23.5 g/g). In conclusion, the transamidation effectively improved the AUL of the terpolymer superabsorbents by about 25%.

Keywords

superabsorbent polymertransamidationsurface crosslinkingabsorbency under load (AUL)
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 16 , 28 August 2018 , pp. 2327 - 2335
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Omidian, H., Doroudiani, S., and Kabiri, K.: Advances in non-hygienic applications of superabsorbent hydrogel materials. J. Mater. Sci. 45, 5711 (2010).Google Scholar
Zohuriaan-Mehr, M.J. and Kabiri, K.: Superabsorbent polymer materials: A review. Iran. Polym. J. 17, 451 (2008).Google Scholar
Sabzevari, A. and Kabiri, K.: Converting date seed biomass into highly absorbing hydrogel. Iran. Polym. J. 25, 597 (2016).CrossRefGoogle Scholar
Sabzevari, A., Kabiri, K., and Siahkamari, M.: Induced superabsorbency in polyester fiber. Iran. Polym. J. 25, 635 (2016).CrossRefGoogle Scholar
Moini, N. and Kabiri, K.: Effective parameters in surface cross-linking of acrylic-based water absorbent polymer particles using bisphenol A diethylene glycidyl ether and cycloaliphatic diepoxide. Iran. Polym. J. 24, 977 (2015).CrossRefGoogle Scholar
Moini, N., Kabiri, K., Zohuriaan-Mehr, M.J., Omidian, H., and Esmaeili, N.: Fine tuning of SAP properties via epoxy-silane surface modification. Polym. Adv. Technol. 28, 1132 (2017).CrossRefGoogle Scholar
Moini, N., Kabiri, K., Zohuriaan-Mehr, M.J., and Esmaeili, N.: Simple and efficient approach for recycling of fine acrylic-based superabsorbent waste. Polym. Bull. 73, 1119 (2016).CrossRefGoogle Scholar
Moini, N., Kabiri, K., and Zohuriaan-Mehr, M.J.: Practical improvement of SAP hydrogel properties via facile tunable cross-linking of the particles surface. Polym. Plast. Technol. Eng. 55, 278 (2016).CrossRefGoogle Scholar
Huang, J., Huang, Z.M., Bao, Y.Z., and Weng, Z.X.: Synthesis and characterization of reinforced acrylic-based superabsorbents crosslinked with divinylbenzene. J. Appl. Polym. Sci. 100, 1594 (2006).CrossRefGoogle Scholar
Mudiyanselage, T.K. and Neckers, D.C.: Highly absorbing superabsorbent polymer. J. Polym. Sci., Part A: Polym. Chem. 46, 1357 (2008).CrossRefGoogle Scholar
Ma, S., Liu, M., and Chen, Z.: Preparation and properties of a salt-resistant superabsorbent polymer. J. Appl. Polym. Sci. 93, 2532 (2004).CrossRefGoogle Scholar
Chen, Z., Liu, M., and Ma, S.: Synthesis and modification of salt-resistant superabsorbent polymers. React. Funct. Polym. 62, 85 (2005).CrossRefGoogle Scholar
Shahi, S. and Zohuriaan-mehr, M.J.: Antibacterial superabsorbing hydrogels with high saline-swelling properties without gel blockage: Toward ideal superabsorbents for hygienic applications. J. Bioact. Compact. Polym. 32, 1 (2016).Google Scholar
Shahi, S., Motasadizadeh, H.R., and Zohuriaan-Mehr, M.J.: Surface modification of superabsorbing hydrogels via a feasible esterification. Int. J. Polym. Mater. Polym. Biomater. 66, 544 (2017).CrossRefGoogle Scholar
Moini, N., Kabiri, K., and Zohuriaan-Mehr, M.J.: Surface treatment of superabsorbents. U.S. Patent No. US 2018/0008960 A1, 2018.Google Scholar
Ban, E., Bigg, D.C.H., and Bertrand, G.: Aluminum chloride-promoted transamidation reactions. J. Org. Chem. 59, 4035 (1994).CrossRefGoogle Scholar
Allen, C.L., Atkinson, N., and Williams, B.: Transamidation of primary amides with amines using hydroxylamine hydrochloride as an inorganic catalyst. Angew. Chem. Int. Ed. 51, 1383 (2012).CrossRefGoogle ScholarPubMed
Rao, S.N., Mohan, D.C., and Adimurthy, S.: An efficient catalyst for transamidation of carboxamides with amines L-proline. Org. Lett. 8, 8 (2013).Google Scholar
Ramazani-Harandi, M.J., Zohuriaan-Mehr, M.J., Yousefi, A.A., Ershad-Langroudi, A., and Kabiri, K.: Rheological determination of the swollen gel strength of superabsorbent polymer hydrogels. Polym. Test. 25, 470 (2006).CrossRefGoogle Scholar
Socrates, G.: Infrared and Raman Characteristic Group Frequencies, 3rd ed. (Wiley, New York, 2001); pp. 107 and 144.Google Scholar
Yedage, S.L., D’silva, D.S., and Bhanage, B.M.: MnO2 catalyzed formylation of amines and transamidation of amides under solvent-free conditions. RSC Adv. 5, 80441 (2015).CrossRefGoogle Scholar
Kabiri, K., Omidian, H., Hashemi, S.A., and Zohuriaan-Mehr, M.J.: Synthesis of fast-swelling superabsorbent hydrogels: Effect of crosslinker type and concentration on porosity and absorption rat. Eur. Polym. J. 39, 1341 (2003).CrossRefGoogle Scholar
Omidian, H., Hashemia, S.A., Sammesb, P.G., and Meldrumb, I.: A model for the swelling of superabsorbent polymers. Polymer 39, 6697 (1998).CrossRefGoogle Scholar
Ramazani-Harandi, M.J., Zohuriaan-Mehr, M.J., Yousefi, A.A., Ershad-Langroudi, A., and Kabiri, K.: Effects of structural variables on AUL and rheological behavior of SAP gels. J. Appl. Polym. Sci. 113, 3676 (2009).CrossRefGoogle Scholar
Supplementary material: File

Azizi et al. supplementary material

Supplementary figures

Download Azizi et al. supplementary material(File)
File 3.3 MB