Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-20T08:27:29.012Z Has data issue: false hasContentIssue false

Subsolidus phase equilibria in the La2O3–Ga2O3–NiO system

Published online by Cambridge University Press:  31 January 2011

Marko Hrovat
Affiliation:
Jožef Stefan Institute, Jamova 39, 1001 Ljubljana, Slovenia
Slavko Bernik
Affiliation:
Jožef Stefan Institute, Jamova 39, 1001 Ljubljana, Slovenia
Janez Holc
Affiliation:
Jožef Stefan Institute, Jamova 39, 1001 Ljubljana, Slovenia
Zoran Samardžija
Affiliation:
Jožef Stefan Institute, Jamova 39, 1001 Ljubljana, Slovenia
Get access

Abstract

Subsolidus equilibria in air in the La2O3–Ga2O3–NiO system were studied with the aim of obtaining information on possible interactions between a LaGaO3-based solid electrolyte and NiO during preparation of the anode in solid oxide fuel cells (SOFC). No ternary compound was found. The tie lines are between La4Ga2O7 and La2NiO4, LaGaO3 and La2NiO4, LaGaO3 and NiO, and LaGaO3 and NiGa2O4.

Type
Articles
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Mogensen, M. and Christiansen, N., Europhys. News 24, 79 (1993).CrossRefGoogle Scholar
2.Tagawa, H., in Proc. 3rd Int. Symp. on Solid Oxide Fuel Cells, Honolulu, HI, edited by Singhal, S. C. and Iwahara, H. (The Electrochemical Society, Pennington, NJ, 1993), pp. 615.Google Scholar
3.Kartha, S. and Grimes, P., Physics Today 47 (11), 5461 (1994).CrossRefGoogle Scholar
4.Minh, N.Q., J. Am. Ceram. Soc. 76 (3), 563588 (1993).CrossRefGoogle Scholar
5.Nagata, M., Iwasawa, C., Yamaoka, S., Seino, Y., and Ono, M., in Proc. 4th Int. Symp. on Solid Oxide Fuel Cells IV, Yokohama, edited by Dokiya, M., Yamamoto, O., Tagawa, T., and Singhal, S.C. (The Electrochemical Society, Pennington, NJ, 1995), pp. 173179.Google Scholar
6.Buckremer, H.P., Diekmann, U., de Haart, L. G. J., Kabs, H., Stimming, U., and Stover, D., in Proc. 5th Int. Symp. on Solid Oxide Fuel Cells V, Aachen, edited by Stimming, U., Singhal, S. C., Tagawa, H., and Lehnert, W. (The Electrochemical Society, Pennington, NJ, 1997), pp. 160170.Google Scholar
7.Tuller, H.L. and Nowick, A. S., J. Electrochem. Soc. 122 (1), 255259 (1975).CrossRefGoogle Scholar
8.Steele, B.C. H., Proc. 1st European Solid Oxide Fuel Cell Forum, European Fuel Cell Group, Ltd., and IEA Advanced Fuel Cell Programme, Lucerne, edited by Bossel, U. (1994), pp. 375397.Google Scholar
9.Ishihara, T., Matsuda, H., and Takita, Y., J. Am. Ceram. Soc. 116 (9), 38013803 (1994).Google Scholar
10.Feng, M. and Goodenough, J.B., Eur. J. Solid State Inorg. Chem. T31, 663672 (1944).Google Scholar
11.Huang, P.N. and Petric, A., J. Electrochem. Soc. 143 (5), 16441648 (1996).CrossRefGoogle Scholar
12.Azad, A.M., Larose, S., and Akbar, S. A., J. Mater. Sci. 29 (16), 41354151 (1994).CrossRefGoogle Scholar
13.Godickemeier, M., Sasaki, K., and Gauckler, L.J., Proc. 4th Int. Symp. on Solid Oxide Fuel Cells IV, Yokohama, edited by Dokiya, M., Yamamoto, O., Tagawa, T., and Singhal, S.C. (The Electrochemical Society, Pennington, NJ, 1995), pp. 10721081.Google Scholar
14.Steele, B.C. H., Zheng, K., Rudkin, R.A., Kiratzis, N., and Cristie, M., Proc. 4th Int. Symp. on Solid Oxide Fuel Cells IV, Yokohama, edited by Dokiya, M., Yamamoto, O., Tagawa, T., and Singhal, S. C. (The Electrochemical Society, Pennington, NJ, 1995), pp. 10281030.Google Scholar
15.Huang, K., Feng, M., Goodenough, J.B., and Milliken, C., J. Electrochem. Soc. 144 (10), 36203624 (1997).CrossRefGoogle Scholar
16.Huang, P.N., Horky, A., and Petric, A., unpublished.Google Scholar
17. JCPDS-ICDD 24–1208, Strontium Lanthanum Gallium Oxide SrLaGaO4.Google Scholar
18. JCPDS-ICDD 34–314, Nickel Lanthanum Oxide La2NiO4.Google Scholar
19.Mizuno, M., Yamada, T., and Ohtake, T., Yogyo Kyokaishi 93 (6), 295300 (1985).CrossRefGoogle Scholar
20.Kolar, D., Skapin, S., Suvorov, D., and Valant, M., Proc. 9th Int. Conf. High Temperature Materials Chemistry, edited by Spear, K. E., Electrochemical Society Proceeding 97–39, 109115 (1997).Google Scholar
21.Phase Diagrams for Ceramists, Vol. VI, 1987 Supplement, edited by Roth, R.S., Dennis, J.R., and McMurdie, H.F. (The American Ceramic Society, 1987), Fig. 6781, p. 368 (after N. Kimizuka and E. Takayama, J. Solid State Chem. 42 (1), 22 (1982)).Google Scholar
22.Drennan, J., Tavares, C.P., and Steele, B. C. H., Mater. Res. Bull. 17 (5), 621626 (1982).CrossRefGoogle Scholar
23.Petrov, A.N., Cherepanov, V. A., Ziyev, A.Y., and Zhukovsky, V. M., J. Solid State Chem. 77, 114 (1988).CrossRefGoogle Scholar