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Decarbonation Behavior of Mg-Al-CO3 Hydrotalcite-like Compounds during Heat Treatment

Published online by Cambridge University Press:  28 February 2024

Toshiyuki Hibino ,
Yasumasa Yamashita ,
Katsunori Kosuge  and
Atsumu Tsunashima
Toshiyuki Hibino
Affiliation:
Materials Processing Department, National Institute for Resources and Environment, 16-3 Onogawa, Tsukuba, 305 Japan
Yasumasa Yamashita
Affiliation:
Materials Processing Department, National Institute for Resources and Environment, 16-3 Onogawa, Tsukuba, 305 Japan
Katsunori Kosuge
Affiliation:
Materials Processing Department, National Institute for Resources and Environment, 16-3 Onogawa, Tsukuba, 305 Japan
Atsumu Tsunashima
Affiliation:
Materials Processing Department, National Institute for Resources and Environment, 16-3 Onogawa, Tsukuba, 305 Japan
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Abstract

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Historically, the decarbonation of Mg-Al-CO3 hydrotalcite-like compounds (HTlc) has been thought to occur between 400° and 500°C. The present work demonstrates that when HTlcs having the maximum Al content, Al/(Al + Mg) = 0.33, are heated to 500°C, 20–30% of the carbonates remain. The evolution of the remaining carbonates was observed as two maxima, at 600 and 900°C At these temperatures, Al ions go into MgO, and spinel (MgAl2O4) forms. Therefore, the carbonates are released as the Al ions migrate.

At a lower Al content, Al/(Al + Mg) = 0.25, CO2 evolution is almost complete at 500°C. This HTlc has no maximum of CO2 evolution above 500°C. Lower charge densities, due to lower Al contents, lead to lower amounts of remaining carbonate anions.

Keywords

DecarbonationHeat treatmentHydrotalcite
Type
Research Article
Information
Clays and Clay Minerals , Volume 43 , Issue 4 , August 1995 , pp. 427 - 432
Copyright
Copyright © 1995, The Clay Minerals Society

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