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Active Components in Clay Condensates and Extracts as Potential Geocatalysts

Published online by Cambridge University Press:  28 February 2024

L. Heller-Kallai ,
T. P. Goldstein  and
A. Navrotsky
L. Heller-Kallai
Affiliation:
Institute of Earth Sciences, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
T. P. Goldstein
Affiliation:
Worldwide Geosciences, Inc., 16 Springtree Lane, Yardley, Pennsylvania 19067, U.S.A.
A. Navrotsky
Affiliation:
Department of Geological and Geophysical Sciences, Princeton University, Princeton, New Jersey 08544, U.S.A.
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Abstract

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Conversion of tertiary butylacetate to isobutylene and acetic acid and cracking of n-octane were used as model reactions to monitor the catalytic activity of a condensate and aqueous extract derived from a sample of montmorillonite. The condensate was obtained by condensing the vapor phase evolved on heating the clay and the extract was derived from the clay by prolonged water extraction. Both condensate and extract were colloidal systems, which were separated into solid and liquid fractions by distillation. Reactions carried out in a dynamic system established that the solid components acted as true acid catalysts, whereas the liquid fractions were inactive under the experimental conditions adopted. The catalytic activity per weight of the condensate exceeded that of either the parent clay or the extract.

The present results confirm that colloidal size catalysts of high activity can be generated from clays. Such materials, mobilized and transported alone or with formation fluids, may act as catalysts in places removed in space and time from their source. This finding refutes objections previously raised to the operation of bulk clays as catalysts for reactions with particulate organics and supports the concept that acid catalysts derived from clays may participate in organic geochemical reactions in an aqueous medium.

Keywords

Clay condensateClay extractGeocatalystOctane crackingTertiary butylacetate decomposition
Type
Research Article
Information
Clays and Clay Minerals , Volume 44 , Issue 3 , June 1996 , pp. 393 - 397
Copyright
Copyright © 1996, The Clay Minerals Society

References

Corma, A. and Wojciechowski, B.W.. 1985. The chemistry of catalytic cracking. Catal Rev Sci Eng 27: 29–150.CrossRefGoogle Scholar
Fieser, L. and Fieser, M.. 1944. Organic chemistry. Boston: D.H. Heath & Co. p 178–179.Google Scholar
Goldstein, T.P.. 1983. Geocatalytic reactions in the formation and maturation of petroleum. AAPG Bull 67: 152–159.Google Scholar
Greensfelder, B.S.. 1955. The chemistry of petroleum hydrocarbons. Brooks BT, editor. Reinhold Pub. Co. 2: 137–164.Google Scholar
Heller-Kallai, L., Miloslavski, I. and Aizenshtat, Z.. 1987. Volatile products of clay mineral pyrolysis revealed by their effect on calcite. Clay Miner 22: 339–348.CrossRefGoogle Scholar
Heller-Kallai, L., Miloslavski, I., Halicz, L. and Aizenshtat, Z.. 1988. Chemical and mass spectrometric analysis of volatiles derived from clays. Am Miner 73: 376–382.Google Scholar
Heller-Kallai, L., Miloslavski, I. and Aizenshtat, Z.. 1989. Reactions of clay volatiles with n-alkanes. Clays & Clay Miner 37: 446–450.CrossRefGoogle Scholar
Heller-Kallai, L. and Miloslavski, I.. 1992. Reactions between clay volatiles and calcite reinvestigated. Clays & Clay Miner 40: 522–530.CrossRefGoogle Scholar
Johns, W.D. and McKallip, T.E.. 1989. Burial diagenesis and specific catalytic activity of illite-smectite clays from Vienna Basin, Austria. AAPG Bull 73: 472–478.Google Scholar
Keller, W.D.. 1986. Composition of condensates from heated clay minerals and shales. Am Mineral 71: 1420–1425.Google Scholar
Keller, W.D. and da Costa, L.M.. 1989. Comparative chemical compositions of aqueous extracts from representative clays. Am Mineral 74: 1142–1146.Google Scholar
Miloslavski, I., Heller-Kallai, L. and Aizenstat, Z.. 1991. Reactions of clay condensates with n-alkanes: Comparison between clay volatiles and clay condensates. Chem Geol 91: 287–296.CrossRefGoogle Scholar