Published online by Cambridge University Press: 05 January 2014
5.1 Introduction
Titan's atmosphere harbors a suite of hydrocarbons and nitrogen-bearing compounds formed from the dissociation of the two main species, nitrogen (N2)and methane (CH4). It also contains oxygen compounds, likely produced from an influx of water and/or oxygen. The mixing ratios of these photochemical species vary with altitude, latitude, and time as a consequence of various chemical sources and sinks and of the atmospheric transport that redistributes them both vertically and horizontally. It is important to characterize and monitor the distribution of these chemical species because they play an important role in the radiative budget and provide insight into the seasonally varying atmospheric circulation. They can also help us understand the complex chemistry at work in Titan's atmosphere, leading to the formation of thick haze layers, which in turn affect the heat balance and general circulation. This chapter reviews the neutral composition of Titan's atmosphere, from the troposphere up to the thermosphere (~ 1400 km), and its vertical, horizontal, and temporal variations. These topics are interwoven with the origin and evolution, the general circulation, the clouds and weather, and the atmospheric chemistry of Titan that are the subjects of Chapters 1, 4, 6, and 7.
5.1.1 Historical perspective
The first unquestionable evidence for an atmosphere on Titan was the discovery of several absorption bands of methane in near-infrared spectra of the satellite (Kuiper, 1944). But it was not until the 1970s that Titan became an object of intense study.
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