Book contents
- Frontmatter
- Contents
- Preface
- 1 Energy in planetary processes and the First Law of Thermodynamics
- 2 Energy sources in planetary bodies
- 3 Energy transfer processes in planetary bodies
- 4 The Second Law of Thermodynamics and thermodynamic potentials
- 5 Chemical equilibrium. Using composition as a thermodynamic variable
- 6 Phase equilibrium and phase diagrams
- 7 Critical phase transitions
- 8 Equations of state for solids and the internal structure of terrestrial planets
- 9 Thermodynamics of planetary volatiles
- 10 Melting in planetary bodies
- 11 Dilute solutions
- 12 Non-equilibrium thermodynamics and rates of natural processes
- 13 Topics in atmospheric thermodynamics and radiative energy transfer
- 14 Thermodynamics of life
- Appendix 1 Physical constants and other useful numbers and conversion factors
- Appendix 2 Derivation of thermodynamic identities
- References
- Index
14 - Thermodynamics of life
Published online by Cambridge University Press: 07 September 2011
- Frontmatter
- Contents
- Preface
- 1 Energy in planetary processes and the First Law of Thermodynamics
- 2 Energy sources in planetary bodies
- 3 Energy transfer processes in planetary bodies
- 4 The Second Law of Thermodynamics and thermodynamic potentials
- 5 Chemical equilibrium. Using composition as a thermodynamic variable
- 6 Phase equilibrium and phase diagrams
- 7 Critical phase transitions
- 8 Equations of state for solids and the internal structure of terrestrial planets
- 9 Thermodynamics of planetary volatiles
- 10 Melting in planetary bodies
- 11 Dilute solutions
- 12 Non-equilibrium thermodynamics and rates of natural processes
- 13 Topics in atmospheric thermodynamics and radiative energy transfer
- 14 Thermodynamics of life
- Appendix 1 Physical constants and other useful numbers and conversion factors
- Appendix 2 Derivation of thermodynamic identities
- References
- Index
Summary
In this final chapter we examine life, and in particular how life may have originated, from a strictly thermodynamic point of view. I will not get anywhere close to biochemistry, biophysics or genetics, nor will I offer a definition of life. Rather, I begin from a concept that everybody must agree upon. This is the fact that a necessary (but not sufficient!) component of the definition of life is that it is a process that never reaches thermodynamic equilibrium, for if thermodynamic equilibrium is reached then the process stops, and life is no more. Life must therefore be powered by a gradient in free energy, which for the only type of life that we know takes the form of a chemical potential gradient, i.e. a non-zero affinity. Catabolic metabolism (henceforth simply metabolism, as I will not discuss anabolic metabolism in detail) is a chemical reaction (or rather a set of coupled chemical reactions) that transfers chemical energy from reactants in an organism's inorganic environment, known as the substrate, to complex organic molecules inside the organism, such as ATP (adenosine triphosphate), that are capable of delivering this energy to structures where the chemical energy is transformed to mechanical energy (e.g. motion), electrical energy (e.g. conscience), electromagnetic energy (e.g. fireflies), etc.
Atmospheric composition, and in particular the oxidation state of the atmosphere, is one of the factors in understanding the origin of life.
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- Thermodynamics of the Earth and Planets , pp. 645 - 670Publisher: Cambridge University PressPrint publication year: 2011