Skip to main content Accessibility help
×
Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-29T04:00:19.298Z Has data issue: false hasContentIssue false

ART. 253 - The Law of Partition of Kinetic Energy

Published online by Cambridge University Press:  05 July 2011

Get access

Summary

The law of equal partition, enunciated first by Waterston for the case of point molecules of varying mass, and the associated Boltzmann-Maxwell doctrine respecting steady distributions have been the subject of much difference of opinion. Indeed, it would hardly be too much to say that no two writers are fully agreed. The discussion has turned mainly upon Maxwell's paper of 1879, to which objections have been taken by Lord Kelvin and Prof. Bryan, and in a minor degree by Prof. Boltzmann and myself. Lord Kelvin's objections are the most fundamental. He writes: “But, conceding Maxwell's fundamental assumption, I do not see in the mathematical workings of his paper any proof of his conclusion ‘that the average kinetic energy corresponding to any one of the variables is the same for every one of the variables of the system.’ Indeed, as a general proposition its meaning is not explained, and it seems to me inexplicable. The reduction of the kinetic energy to a sum of squares leaves the several parts of the whole with no correspondence to any defined or definable set of independent variables.”

In a short note written soon afterwards I pointed out some considerations which appeared to me to justify Maxwell's argument, and I suggested the substitution of Hamilton's principal function for the one employed by Maxwell.

Type
Chapter
Information
Scientific Papers , pp. 433 - 451
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1903

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Save book to Kindle

To save this book to your Kindle, first ensure [email protected] is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

Available formats
×