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11 - Fundamentals of Gaseous Combustion

Published online by Cambridge University Press:  01 December 2022

By
Eric L. Petersen  and
Olivier Mathieu
Edited by
Jacqueline O'Connor ,
Bobby Noble  and
Tim Lieuwen
Jacqueline O'Connor
Affiliation:
Pennsylvania State University
Bobby Noble
Affiliation:
Electric Power Research Institute
Tim Lieuwen
Affiliation:
Georgia Institute of Technology
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Summary

Gaseous renewable fuel combustion is of primary interest for a range of applications including aircraft engines, ground power engines, reciprocating engines, and industrial furnaces, among others. While much of the combustion science and engineering that are needed to design and operate such devices is well developed and available in modern textbooks, the attainment of even higher efficiencies, greater performance, and reduced emissions for an ever-increasing array of new fuels and fuel blends requires an even deeper understanding of fundamental combustion concepts and the underlying physical and chemical phenomena. In many cases, these fundamental concepts are areas of much recent and ongoing research.  This chapter describes the basic combustion and chemical kinetic properties of the fuels, namely hydrogen, syngas, ammonia, methane, natural gas, and ethanol, considering the flame temperature, ignition delay time, flammability limit, laminar flame speed, and fuel stretch sensitivity.

Keywords

equilibriumadiabatic flame temperatureflame speedignitionstretch sensitivitykineticsflammability limitexplosion limitignition time delay
Type
Chapter
Information
Renewable Fuels
Sources, Conversion, and Utilization
 , pp. 371 - 413
Publisher: Cambridge University Press
Print publication year: 2022

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References

Alturaifi, S. A., Mathieu, O., and Petersen, E. L. (2022) “An Experimental and Modeling Study of Ammonia Pyrolysis,” Combustion and Flame, Vol. 235, pp. 111694.CrossRefGoogle Scholar
Annamalai, K. and Puri, I. K. (2007) Combustion Science and Engineering, CRC Press.Google Scholar
ASTM (2019) “Standard Practice for Determining Limits of Flammability of Chemicals at Elevated Temperature and Pressure,” ASTM E918, Dec. 19.Google Scholar
Baigmohammadi, M., Patel, V., Nagaraja, S. et al. (2020) “Comprehensive Experimental and Simulation Study of the Ignition Delay Time Characteristics of Binary Blended Methane, Ethane, and Ethylene Over a Wide Range of Temperature, Pressure, Equivalence Ratio, and Dilution,” Energy & Fuels, Vol. 34, pp. 8808–8823.CrossRefGoogle Scholar
Beerer, D. J. and McDonell, V. G. (2008) “Autoignition of Hydrogen and Air Inside a Continuous Flow Reactor with Application to Lean Premixed Combustion,” Journal of Engineering for Gas Turbines and Power, Vol. 130, pp. 051507-8.Google Scholar
Bourque, G., Healy, D., Curran, H., Zinner, C., Kalitan, D., de Vries, J., Aul, C., and Petersen, E. (2010) “Ignition and Flame Speed Kinetics of Two Natural Gas Blends with High Levels of Heavier Hydrocarbons,” Journal of Engineering for Gas Turbines and Power, Vol. 132, pp. 021504-11.Google Scholar
Brooks, M. R. and Crowl, D. A. (2007) “Flammability Envelopes for Methanol, Ethanol, Acetonitrile, and Toluene,” Journal of Loss Prevention in the Process Industries, Vol. 20, pp. 144–150.CrossRefGoogle Scholar
Chaos, M., Burke, M. P., Ju, Y., and Dryer, F. L. (2010) “Syngas Chemical Kinetics and Reaction Mechanisms,” in Synthesis Gas Combustion: Fundamentals and Applications, Lieuwen, T., Yang, V., and Yetter, R. (eds.), CRC Press, pp. 29–98.Google Scholar
Chen, J., Jiang, X., Qin, X., and Huang, Z. (2021) “Effect of Hydrogen Blending on the High Temperature Auto-Ignition of Ammonia at Elevated Pressure,” Fuel, Vol. 287, Article 119563.CrossRefGoogle Scholar
Chen, Z. (2011) “On the Extraction of Laminar Flame Speed and Markstein Length from Outwardly Propagating Spherical Flames,” Combustion and Flame, Vol. 158, pp. 291–300.CrossRefGoogle Scholar
Coronado, C. J. R., Carvalho, J. A. Jr., Andrade, J. C. et al. (2012) “Flammability Limits: A Review with Emphasis on Ethanol for Aeronautical Applications and Description of the Experimental Procedure,” Journal of Hazardous Materials, Vol. 241–242, pp. 32–54.Google Scholar
Crowl, D. A. and Louvar, J. F. (2011) Chemical Process Safety: Fundamentals with Applications, 3rd ed., Prentice Hall.Google Scholar
Davidson, D. F. and Hanson, R. K. (2009) “Recent Advances in Shock Tube/Laser Diagnostic Methods for Improved Chemical Kinetics Measurements,” Shock Waves, Vol. 19, pp. 271–283.Google Scholar
Donato, N. S. and Petersen, E. L. (2008) “Simplified Correlation Models for CO/H2 Chemical Reaction Times,” International Journal of Hydrogen Energy, Vol. 33, No. 24, pp. 7565–7579.CrossRefGoogle Scholar
Donohoe, N., Heufer, A., Metcalfe, W.K., Curran, H.J., Davis, M.L., Mathieu, O., Plichta, D., Morones, A., Petersen, E.L. and Güthe, F. (2014) “Ignition Delay Times, Laminar Flame Speeds, and Mechanism Validation for Natural Gas/Hydrogen Blends at Elevated Pressures,” Combustion and Flame, Vol. 161, pp. 1432–1443.Google Scholar
Dryer, F. L., Chaos, M., Zhao, Z., Stein, J. N., Alpert, J. Y., and Homer, C. J. (2007) “Spontaneous Ignition of Pressurized Releases of Hydrogen and Natural Gas into Air,” Combustion Science and Technology, Vol. 179, pp. 663–694.Google Scholar
Glarborg, P., Miller, J.A., Ruscic, B., and Klippenstein, S. J. (2018) “Modeling Nitrogen Chemistry in Combustion,” Progress in Energy and Combustion Science, Vol. 67, pp. 31–68.CrossRefGoogle Scholar
Glassman, I., Yetter, R. A., and Glumac, N. G. (2015) Combustion, 5th ed., Elsevier.Google Scholar
Hayakawa, A., Goto, T., Mimoto, R., Arakawa, Y., Kudo, T., and Kobayashi, H. (2015) “Laminar Burning Velocity and Markstein Length of Ammonia/Air Premixed Flames at Various Pressures,” Fuel, Vol. 159, pp. 98–106.CrossRefGoogle Scholar
Hu, E., Juang, Z., He, J., Jin, C., Miao, H., and Wang, X. (2009) “Measurement of Laminar Burning Velocities and Analysis of Flame Stabilities for Hydrogen-Air-Diluent Premixed Mixtures,” Chinese Science Bulletin, Vol. 54, No. 5, pp. 846–857.Google Scholar
Ichikawa, A., Hayakawa, A., Kitagawa, Y., Somarathne, K.D.K.A., Kudo, T., and Kobayashi, H. (2015) “Laminar Burning Velocity and Markstein Length of Ammonia/Hydrogen/Air Premixed Flames at Elevated Pressures,” International Journal of Hydrogen Energy, Vol. 40, pp. 9570–9578.Google Scholar
Keesee, C. L., Petersen, E. L., Zhang, K., and Curran, H. J. (2015) “Laminar Flame Speed Measurements of Synthetic Gas Blends with Hydrocarbon Impurities,” Turbo Expo 2015, Montreal, Canada.Google Scholar
Kéromnès, A., Metcalfe, W. K., Heufer, K. A., Donohoe, N., Das, A. K., Sung, C. J., Herzler, J., Naumann, C., Griebel, P., Mathieu, O. and Krejci, M. C., Petersen, E. L., Pitz, W. J., and Curran, W. J. (2013) “An Experimental and Detailed Chemical Kinetic Modeling Study of Hydrogen and Syngas Mixture Oxidation at Elevated Pressures,” Combustion and Flame, Vol. 160, pp. 995–1011.Google Scholar
Kuo, K. K. (2005) Principles of Combustion, 2nd ed., John Wiley & Sons, Inc.Google Scholar
Law, C. K. (2006) Combustion Physics, Cambridge University Press.CrossRefGoogle Scholar
Li, J., Zhao, Z., Kazakov, A., Chaos, M., Dryer, F., and Scire, J. (2007) “A Comprehensive Kinetic Mechanism for CO, CH2O, and CH3OH Combustion,” International Journal of Chemical Kinetics, Vol. 39, pp. 109–136.Google Scholar
Li, Z. and Li, S. (2021) “Kinetics Modeling of NOx Emissions Characteristics of a NH3/H2 Fueled Gas Turbine Combustor,” International Journal of Hydrogen Energy, Vol. 46, pp. 4526–4537.Google Scholar
Lindstedt, R. P., Lockwood, F. C., and Selim, M. A. (1994) “Detailed Kinetic Modeling of Chemistry and Temperature Effects on Ammonia Oxidation,” Combustion Science and Technology, Vol. 99, pp. 253–276.Google Scholar
Markstein, G. H. (1964) Non-Steady Flame Propagation, Pergamon.Google Scholar
Miller, J. A., Smooke, M. D., Green, R. M., and Kee, R. J. (1983) “Kinetic Modeling of the Oxidation of Ammonia in Flames,” Combustion Science and Technology, Vol. 34, pp. 149–176.CrossRefGoogle Scholar
Nakamura, H., Hasegawa, H., and Tezuka, S. (2017) “Kinetic Modeling of Ammonia/Air Weak Flames in a Micro Flow Reactor with a Controlled Temperature Profile,” Combustion and Flame, Vol. 185, pp. 16–27.Google Scholar
Natarajan, J. and Seitzman, J. M. (2010) “Laminar Flame Properties of H2/CO Mixtures,” in Synthesis Gas Combustion: Fundamentals and Applications, Lieuwen, T., Yang, V., and Yetter, R. (eds.), CRC Press, pp. 71–98.Google Scholar
Petersen, E. L., Röhrig, M., Davidson, D. F., Hanson, R. K., and Bowman, C. T. (1996) “High-Pressure Methane Oxidation Behind Reflected Shock Waves,” Proceedings of the Combustion Institute, Vol. 26, pp. 799–806.Google Scholar
Petersen, E. L., Davidson, D. F., and Hanson, R. K. (1999) “Kinetics Modeling of Shock-Induced Ignition in Low-Dilution CH4/O2 Mixtures at High Pressures and Intermediate Temperatures,” Combustion and Flame, Vol. 117, pp. 272–290.CrossRefGoogle Scholar
Ragland, K. W. and Bryden, K. M. (2011) Combustion Engineering, 2nd ed., Taylor & Francis Group.Google Scholar
Ravi, S. and Petersen, E. L. (2012) “Laminar Flame Speed Correlations for Pure Hydrogen and High-Hydrogen-Content Syngas Blends with Various Diluents,” International Journal of Hydrogen Energy, Vol. 37, 2012, pp. 19177–19189.Google Scholar
Reynolds, W. C. (1986) “The Element Potential Method for Chemical Equilibrium Analysis: Implementation in the Interactive Program STANJAN,” Department of Mechanical Engineering, Stanford University.Google Scholar
Ribert, G., Thakre, P., Wang, Z., Yetter, R. A., and Yang, V. (2010) “Fundamental Combustion Characteristics of Syngas,” in Synthesis Gas Combustion: Fundamentals and Applications, Lieuwen, T., Yang, V., and Yetter, R. (eds.), CRC Press, pp. 99–128.Google Scholar
Smith, G. P., Golden, D. M., Frenklach, M., Moriarty, N. W., Eiteneer, B., Goldenberg, M., Bowman, C. T., Hanson, R. K., Song, S., Gardiner, W. C. Jr., Lissianski, V. V., and Qin, Z. (1999) GRI Mech 3.0 Reaction Mechanism, 1999, www.me.berkeley.edu/gri.mech/.Google Scholar
Sonntag, R. E., Borgnakke, C., and Van Wylen, G. J. (1998) Fundamentals of Thermodynamics, 5th ed., John Wiley & Sons, Inc.Google Scholar
Stagni, A., Cavallotti, C., Arunthanayothin, S., Song, Y., Herbinet, O., Battin-Leclerc, F., and Faravelli, T. (2020) “An Experimental, Theoretical and Kinetic-Modeling Study of the Gas-Phase Oxidation of Ammonia,” Reaction Chemistry & Engineering, Vol. 5, pp. 696–711.CrossRefGoogle Scholar
Sung, C.-J. and Curran, H. J. (2014) “Using Rapid Compression Machines for Chemical Kinetic Studies,” Progress in Energy and Combustion Science, Vol. 44, pp. 1–18.Google Scholar
Tang, C., Zhang, Y., and Huang, Z. (2014) “Progress in Combustion Investigations of Hydrogen Enriched Hydrocarbons,” Renewable and Sustainable Energy Reviews, Vol. 30, pp. 195–216.Google Scholar
Turner, M. A., Paschal, T. T., Parajuli, P., Kulatilaka, W. D., and Petersen, E. L. (2021) “Application of High-Speed, Species-Specific Chemiluminescence Imaging for Laminar Flame Speed and Markstein Length Measurements in Spherically Expanding Flames,” Experimental Thermal and Fluid Science, Vol. 129, Article 110477.Google Scholar
Turns, S. R. (2011) An Introduction to Combustion: Concepts and Applications, 3rd ed., McGraw-Hill.Google Scholar
Westbrook, C., Pitz, W., Herbinet, O., Curran, H., and Silke, E. (2009) “A Comprehensive Detailed Chemical Kinetic Reaction Mechanism for Combustion of n-Alkane Hydrocarbons from n-Octane to n-Hexadecane,” Combustion and Flame, Vol. 156, pp. 181–199.CrossRefGoogle Scholar
Wu, Y., Panigrahy, S., Sahu, A. B., Bariki, C., Beeckmann, J., Liang, J., Mohamed, A. A., Dong, S., Tang, C., Pitsch, H., Huang, Z., and Curran, H. J. (2021) “Understanding the Antagonistic Effect of Methanol as a Component in Surrogate Fuel Models: A Case Study of Methanol/n-Heptane Mixtures,” Combustion and Flame, Vol. 226, pp. 229–242.CrossRefGoogle Scholar
Zhou, C. W., Li, Y., Burke, U., Banyon, C., Somers, K. P., Ding, S., Khan, S., Hargis, J. W., Sikes, T., Mathieu, O., Petersen, E. L., AlAbbad, M., Farooq, A., Pan, Y., Zhang, Y., Huang, Z., Lopez, J., Loparo, Z., Vasu, S. S., and Curran, H. J. (2018) “An Experimental and Chemical Kinetic Modeling Study of 1,3-Butadiene Combustion: Ignition Delay Time and Laminar Flame Speed Measurements,” Combustion and Flame, Vol. 197, pp. 423–438.Google Scholar

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