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1891: On a Graphical Representation of the Results of Dr Alder Wright's Experiments on Ternary Alloys

Published online by Cambridge University Press:  01 June 2011

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Summary

Suppose three liquids, such as water, ether, and alcohol, of which the third is miscible in all proportions with either of the others, are mixed together, the temperature being kept constant. According to circumstances, the mixture forms a single liquid mass, or separates into two. In the latter case, if we suppose that the liquids had been merely gently poured together, and imagine the upper and under portions separately to be homogeneous to start with, this state of things would not remain; an alteration of composition would take place close to the surface of separation on both sides, depending on the relative solubilities, &c., of the ingredients. If now the two altered strata were mixed up with the rest of the portions to which they respectively belong, the same thing would go on again, and so on till a condition was reached in which what we may call an equilibrium of composition on the two sides of the surface of separation had been attained. As this equilibrium depends only on the molecular forces, which are insensible at sensible distances, it is evident that the equilibrium would not be disturbed by removing a part of either the upper or the under liquid, or by adding to it liquid of exactly the same composition as itself.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1905

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