Published online by Cambridge University Press: 01 June 2011
The determination of the motion of the gas within the bulb, which would theoretically lead to a determination of the coefficient of viscosity of the gas, forms a mathematical problem of hopeless difficulty. Nevertheless we are able, by attending to the condition of similarity of the motion in different cases, to compare the viscosities of the different gases for as many groups of corresponding pressures as we please. Setting aside certain minute corrections, which would have vanished altogether had the moment of inertia of the vibrating body been sufficient to make the time of vibration sensibly independent of the gas, as was approximately the case, the condition of similarity is that the densities shall be as the log. decrements of the arc of vibration, and the conclusion from theory is that when that condition is satisfied, then the viscosities are in the same ratio. Pressures which satisfy the condition of similarity are said to “correspond.”
It was found that on omitting the high exhaustions, the experiments led to the following law :–
The ratios of the viscosities of the different gases are the same for any two groups of corresponding pressures. In other words, if the ratios of the viscosities of a set of gases are found (they are given by the ratios of the log. decrements) for one set of corresponding pressures, these pressures may be changed in any given ratio without disturbing the ratios of the viscosities.
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