Contaminant Chronologies from Hudson River Sedimentary Records

doi:10.1017/CBO9780511550539.028

26 - Contaminant Chronologies from Hudson River Sedimentary Records

Published online by Cambridge University Press: 06 January 2010

Richard F. Bopp ,

Steven N. Chillrud ,

Edward L. Shuster and

H. James Simpson

Edited by

Jeffrey S. Levinton and

John R. Waldman

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Richard F. Bopp: Affiliation:
Department of Earth and Environmental Sciences Rensselaer Polytechnic Institute
Steven N. Chillrud: Affiliation:
Lamont-Doherty Earth Observatory of Columbia University
Edward L. Shuster: Affiliation:
Department of Earth and Environmental Sciences Rensselaer Polytechnic Institute
H. James Simpson: Affiliation:
Department of Earth and Environmental Sciences, Lamont-Doherty Earth Observatory of Columbia University
Jeffrey S. Levinton: Affiliation:
State University of New York, Stony Brook

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Summary

abstract Analyses of sections from dated sediment cores have been used to construct contaminant chronologies in the Hudson River Basin and the New York/New Jersey Harbor complex. Dating information was derived primarily from radionuclide analyses. The known input history of 137Cs, a radionuclide derived from global fallout and nuclear reactor discharges, places important constraints on estimates of net sediment accumulation rates. 7Be, a natural radionuclide with a 53 day half-life is detectable in surficial samples with a significant component of particles deposited within a year of core collection. Persistent contaminants analyzed in dated Hudson sediments include PCBs, dioxins, chlorinated hydrocarbon pesticides, and trace metals such as copper, lead, zinc, cadmium, chromium, and mercury. The combination of temporal and geographic information from these analyses is most valuable and provides a general basinwide perspective on the significant improvement in contaminant levels in the Hudson over the past several decades. It has also allowed us to trace the influence of several major contamination incidents in the basin, including PCB and trace metal inputs to the Upper Hudson River and dioxin and DDT discharges to the Lower Passaic River.

Introduction

Over the past several decades, many thousands of sediment samples have been collected from the Hudson River, its tributaries and the New York/New Jersey (NY/NJ) Harbor complex (Fig. 26.1). This chapter will focus on insights gained from analyses on a very select subset of those samples – sections of dated sediment cores.

Type: Chapter
Information: The Hudson River Estuary , pp. 383 - 397

DOI: https://doi.org/10.1017/CBO9780511550539.028 [Opens in a new window]

Publisher: Cambridge University Press

Print publication year: 2006

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References

Alderton, D. H. M. 1985. Sediments, in Historical Monitoring, Monitoring and Assessment Research Center, MARC Report No. 31, London. pp. 1–95

Baker, J. E., Bohlen, W. F., Bopp, R., Brownawell, B., Collier, T. K., Farley, K. J., Geyer, W. R., and Nairn, R. 2001. PCBs in the Hudson River: The Science Behind the Controversy. White Paper prepared for the Hudson River Foundation, released October 29, 2001Google Scholar

Bedard, D. L., and Quensen, III, J. F. 1995. Microbial reductive dechlorination of polychlorinated biphenyls, in Young, L. Y. and Cerniglia, C. E. (eds.), Microbial Transformation and Degradation of Toxic Organic Chemicals. New York: Wiley-Liss, Inc. pp. 127–216Google Scholar

Benoit, G., Wang, E. X., Nieder, W. C., Levandowsky, M., and Breslin, V. T. 1999. Sources and history of heavy metal contamination and sediment deposition in Tivoli South Bay, Hudson River, New York. Estuaries 22:167–78CrossRef Google Scholar

Bopp, R. F. 1979. “The geochemistry of polychlorinated biphenyls in the Hudson River,” Ph. D. dissertation, Columbia University, New York

Bopp, R. F., Butler, J. A., Chaky, D. A., Shuster, E. L., Chillrud, S. N., and Estabrooks, F. D. 1996. Geographic and temporal distribution of particle-associated contaminants in sediments of the Hudson River Basin. Abstract, Society of Environmental Toxicology and Chemistry – 17th Annual Meeting, Washington, D.C.

Bopp, R. F., Chillrud, S. N., Shuster, E. L., Simpson, H. J., and Estabrooks, F. D. 1998. Trends in chlorinated hydrocarbon levels in Hudson River Basin sediments. Environmental Health Perspectives 106(supplement 4):1075–81CrossRef Google Scholar PubMed

Bopp, R. F., Gross, M. L., Tong, H. Y., Simpson, H. J., Monson, S. J., Deck, B. L., and Moser, F. C. 1991. A major incident of dioxin contamination: Sediments of New Jersey estuaries. Environmental Science and Technology 25:951–56CrossRef Google Scholar

Bopp, R. F., and Simpson, H. J. 1989. Contamination of the Hudson River: The sediment record, in Contaminated Marine Sediments Assessment and Remediation. Washington, D.C., National Research Council, NAS, pp. 401–416Google Scholar

Bopp, R. F., Simpson, H. J., Chillrud, S. N., and Robinson, D. W. 1993. Sediment-derived chronologies of persistent contaminants in Jamaica Bay, New York. Estuaries 16:608–616CrossRef Google Scholar

Bopp, R. F., Simpson, H. J., Olsen, C. R., and Kostyk, N. 1981. Polychlorinated biphenyls in sediments of the tidal Hudson River, New York. Environmental Science and Technology 15:210–216CrossRef Google Scholar PubMed

Bopp, R. F., Simpson, H. J., Olsen, C. R., Trier, R. M., and Kostyk, N. 1982. Chlorinated hydrocarbons and radionuclide chronologies in sediments of the Hudson River and Estuary, New York. Environmental Science and Technology 16:666–76CrossRef Google Scholar

Bopp, R. F., and Walsh, D. C. 1994. Rivers and estuaries: A Hudson perspective, in Environmental Science in the Coastal Zone: Issues for Further Research. Washington, D.C. National Research Council, NAS, pp. 49–66Google Scholar

Bowen, H. J. M. 1979. Environmental Chemistry of the Elements. London: Academic PressGoogle Scholar

Bower, P. M., Simpson, H. J., Williams, S. C., and Li, Y. H. 1978. Heavy metals in the sediments of Foundry Cove, Cold Spring, New York. Environmental Science and Technology 12:683–7CrossRef Google Scholar

Brown, J. F. Jr., Wagner, R. E., Bedard, D. L., Brennan, M. J., Carnahan, J. C., May, R. J., and Tofflemire, T. J. 1984. PCB transformations in upper Hudson sediments. Northeastern Environmental Science 3:167–79Google Scholar

Bush, B., Shane, L. A., Wahlen, M., and Brown, M. P. 1987. Sedimentation of 74 PCB congeners in the Upper Hudson River. Chemosphere 16:733–44CrossRef Google Scholar

Chaky, D. A. 2003. “The geochemistry of polychlorinated biphenyls, dibenzo-p-dioxins and dibenzofurans in recent sediments of the New York Metropolitan Area,” Ph. D. dissertation, Rensselaer Polytechnic Institute, Troy, NY

Chaky, D. A., Chillrud, S. N., Bopp, R. F., Shuster, E. L., Estabrooks, F. D., and Swart, J. 1998. Chlorinated hydrocarbon contamination of the New York/New Jersey Metropolitan Area: The urban atmospheric influence. EOS, Transactions of the American Geophysical Union 79:S86Google Scholar

Chillrud, S. N. 1996. “Transport and fate of particle associated contaminants in the Hudson River basin,” Ph. D. dissertation, Columbia University, NY, 277 pp

Chillrud, S. N., Bopp, R. F., Ross, J. M., Chaky, D. A., Hemming, S., Shuster, E. L., Simpson, H. J., and Estabrooks, F. 2004. Radiogenic lead isotopes and time stratigraphy in the Hudson River, New York. Water, Air and Soil Pollution: Focus 4:469–82CrossRef Google Scholar

Chillrud, S. N., Bopp, R. F., Simpson, H. J., Ross, J., Shuster, E. L., Chaky, D. A., Walsh, D. C., Chin Choy, C., Tolley, L. R., and Yarme, A. 1999. Twentieth century atmospheric metal fluxes into Central Park Lake, New York City. Environmental Science and Technology 33(5):657–62CrossRef Google Scholar PubMed

Chillrud, S. N., Hemming, S., Shuster, E. L., Simpson, H. J., Bopp, R. F., Ross, J., Pederson, D. C., Chaky, D. A., Tolley, L.-R., and Estabrooks, F. D. 2003. Stable lead isotopes, contaminant metals and radionuclides in upper Hudson River sediment cores: Implications for improved stratigraphy and transport processes. Chemical Geology 199:53–70CrossRef Google Scholar

Cochran, J. K., and Aller, R. C. 1979. Particle reworking in sediments from the New York Bight apex: Evidence from 234Th/238U disequilibrium. Estuarine and Coastal Marine Science 9:739–47CrossRef Google Scholar

Diamond Shamrock Corporation. 1983. Report on Lister Avenue Facility. Prepared for the New Jersey Department of Environmental Protection, Trenton, NJ

Eckenfelder, Inc. 1991. State-Wide Soil Sampling Report, Ciba-Geigy Main Plant Site, Glens Falls, NY. Prepared for Hercules Inc., Wilmington, DE

Feng, H., Cochran, J. K., Hirschberg, D. J., and Wilson, R. E. 1998. Small-scale spatial variations of natural radionuclide and trace metal distributions in sediments from the Hudson River Estuary. Estuaries 21:263–80CrossRef Google Scholar

Ferguson, P. L., Bopp, R. F., Chillrud, S. N., Aller, R. C., and Brownawell, B. J. 2003. Biogeochemistry of nonlyphenol ethoxylates in urban estuarine sediments. Environmental Science and Technology 37:3499–3506CrossRef Google Scholar

Gibbs, R. J. 1994. Metals in the sediments along the Hudson River Estuary. Environment International 20:507–516CrossRef Google Scholar

Goeller, A. F. III. 1989. “Heavy metals and radionuclides in sediments of the Hackensack River, New Jersey,” Master's thesis, Rutgers University, Newark, NJ

Hay, A. 1982. The Chemical Scythe: Lessons of 2,4,5-T and Dioxin. New York: Plenum PressCrossRef Google Scholar

Keane, D. P. 1998. “Temporal trends of saturated and polycyclic aromatic hydrocarbons in the sediments of the Hudson and Passaic River systems,” Master's thesis, Rensselaer Polytechnic Institute, Troy, NY

Knutson, A. B., Klerks, P. L., and Levinton, J. S. 1987. The fate of metal contaminated sediments in Foundry Cove, New York. Environmental Pollution 45: 291–304CrossRef Google Scholar PubMed

Kroenke, A. E., Bopp, R. F., Chaky, D. A., Chillrud, S. N., Shuster, E. L., Estabrooks, F. D., and Swart, J. 1998. Atmospheric Deposition and Fluxes of Mercury in Remote and Urban Areas of the Hudson River Basin, Abstract, EOS, Transactions of the American Geophysical Union 79:S86Google Scholar

McNulty, A. K. 1997. “In situ anaerobic dechlorination of PCBs in Hudson River sediments,” Master's thesis, Rensselaer Polytechnic Institute

National Oceanic and Atmospheric Administration. 1988. National Status and Trends Program – A summary of selected data on chemical contaminants in sediments collected during 1984, 1985, 1986, and 1987. NOAA Technical Memo. NOS OMA 44, Rockville, MD

NATO. 1988. International toxicity equivalency factor (I-tef) method of risk assessment for complex mixtures of dioxins and related compounds, North Atlantic Treaty Organization, Report Number 176

Olsen, C. R., Simpson, H. J., Bopp, R. F., Williams, S. C., Peng, T.-H., and Deck, B. L. 1978. A geochemical analysis of sediments and sedimentation in the Hudson Estuary. Journal of Sedimentary Petrology 48:401–418Google Scholar

Olsen, C. R., Simpson, H. J., Peng, T.-H., Bopp, R. F., and Trier, R. M. 1981. Sediment mixing and accumulation rate effects on radionuclide depth profiles in Hudson Estuary sediments. Journal of Geophysical Research 86:11020–28CrossRef Google Scholar

O'Malley, V. P., Abrajano, T. A. Jr., and Hellou, J. 1996. Stable carbon isotopic apportionment of individual polycyclic aromatic hydrocarbons in St. John's Harbour, Newfoundland. Environmental Science and Technology 30:634–9CrossRef Google Scholar

Perry, E. A., Bopp, R., Keane, D., and Abrajano, T. A. 2002. History of polycyclic aromatic hydrocarbon (PAH) deposition in the New York Harbor. Abstract, Geological Society of America Northeastern Section – 37th Annual Meeting, Springfield, MAGoogle Scholar

Ritchie, J. C., and McHenry, J. R. 1990. Application of radioactive fallout 137Cs for measuring soil erosion and sediment accumulation rates and patterns: A review. Journal of Environmental Quality 19:215–33CrossRef Google Scholar

Robideau, R. M. 1997. “Sedimentation rates in Hudson River marshes as determined by radionuclide dating techniques,” Master's thesis, Rensselaer Polytechnic Institute, Troy, NY

Robinson, K. A. 2002. “Chlordane and DDT in the Hudson River Basin, Master's thesis,” Rensselaer Polytechnic Institute, Troy, NY

Rohmann, S. O. 1985. Tracing a River's Toxic Pollution: A Case Study of the Hudson. New York: Inform, Inc.Google Scholar

Servos, M. R. 1999. Review of the aquatic toxicity, estrogenic responses and bioaccumulation of alkylphenols and alkylphenol polyethoxylates. Water Quality Research Journal of Canada 34: 123–77Google Scholar

Sloan, R. J. 1999. Hudson River Fish and the PCB Perspective. Presentation to the NRC Committee on Remediation of PCB Contaminated Sediments, November 8, 1999, Albany, NYGoogle Scholar

Smith, S. L., MacDonald, D. D., Keenleyside, K. A., Ingersoll, C. G., and Field, L. J. 1996. A preliminary evaluation of sediment quality assessment values for freshwater ecosystems. Journal of Great Lakes Research 22:624–38CrossRef Google Scholar

TAMS Consultants, Inc. and Gradient Corporation. 1996. Database for the Hudson River PCBs Reassessment, Phase 2 Report, Further Site Characterization and Analysis Database Report, Volume 2A, U.S. Environmental Protection Agency, Washington, D.C.

USEPA. 2000. Hudson River PCBs Superfund Site, New York. Superfund proposed plan, EPA Region 2

Berg, M., Birnbaum, L., Bosveld, A. T. C., Brunström, B., Cook, P., Feeley, M., Giesy, J. P., Hanberg, A., Hasegawa, R., Kennedy, S. W., Kubiak, T., Larsen, J. C., Leeuwen, F. X. R., Liem, A. K. D., Nolt, C., Peterson, R. E., Poellinger, L., Safe, S., Schrenk, D., Tillitt, D., Tysklind, M., Younes, M., Wærn, F., and Zacharewski, T . 1998. Toxic equivalency factors (TEFs) for PCBs, PCDDs, and PCDFs for humans and wildlife. Environmental Health Perspectives 106:775–92CrossRef Google Scholar PubMed

Williams, S. C., Simpson, H. J., Olsen, C. R., and Bopp, R. F. 1978. Sources of heavy metals in sediments of the Hudson River Estuary. Marine Chemistry 6:195–213CrossRef Google Scholar

Yan, B. 2004. “PAH sources and depositional history in sediments from the lower Hudson River basin,” Ph. D. dissertation, Rensselaer Polytechnic Institute, Troy, NY

Yan, B., Benedict, L. A., Chaky, D. A., Bopp, R. F., and Abrajano, T. A. 2004. Levels and patterns of PAH distribution in sediments of the New York/New Jersey Harbor complex. Northeastern Geology and Environmental Science 26(1&2):113–22Google Scholar

Zamek, E. 2002. “Trace metal chronologies in sediments of the upper Hudson and Mohawk Rivers,” Master's thesis, Rensselaer Polytechnic Institute, Troy, NY