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3 - Poly(arylene vinylene)s

Published online by Cambridge University Press:  28 March 2024

Andrew Grimsdale
Affiliation:
Nanyang Technological University, Singapore
Paul Dastoor
Affiliation:
University of Newcastle, New South Wales
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Summary

The methods for synthesising by precursor routes films of insoluble poly(phenylene vinylene) (PPV), the prototypical poly(arylene vinylene) (PAV) are described and compared and its properties discussed. Methods for preparing soluble substituted PPVs are described and their structure–property relationships discussed. By suitable choice of structure, PAVs with emission colours ranging from the blue to the near infra-red have been made and tested in light-emitting diodes. The choice of substituents has also been used to enhance the charge accepting and transporting properties of PAVs, thus improving their efficiency in devices. The efficiency of polymer-based LEDs is also affected by the presence of defects in the polymer structures and methods have been developed to minimise these, enabling commercially-viable LEDs to be made using PAVs. The potential use of PAVs in OTFTs and OPVs is also discussed.

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Chapter
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Conjugated Polymers for Organic Electronics
Design and Synthesis
, pp. 29 - 53
Publisher: Cambridge University Press
Print publication year: 2024

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  • Poly(arylene vinylene)s
  • Andrew Grimsdale, Nanyang Technological University, Singapore, Paul Dastoor, University of Newcastle, New South Wales
  • Book: Conjugated Polymers for Organic Electronics
  • Online publication: 28 March 2024
  • Chapter DOI: https://doi.org/10.1017/9781139035262.004
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  • Poly(arylene vinylene)s
  • Andrew Grimsdale, Nanyang Technological University, Singapore, Paul Dastoor, University of Newcastle, New South Wales
  • Book: Conjugated Polymers for Organic Electronics
  • Online publication: 28 March 2024
  • Chapter DOI: https://doi.org/10.1017/9781139035262.004
Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Poly(arylene vinylene)s
  • Andrew Grimsdale, Nanyang Technological University, Singapore, Paul Dastoor, University of Newcastle, New South Wales
  • Book: Conjugated Polymers for Organic Electronics
  • Online publication: 28 March 2024
  • Chapter DOI: https://doi.org/10.1017/9781139035262.004
Available formats
×