Heterostructures formed by nanoparticles hybridized with porous hosts are of great potential in many practical applications such as catalysis, adsorption, and environmental remediation, based on their intrinsic properties. The objectives of this study were to synthesize zerovalent iron nanoparticles/montmorillonite heterostructures and to investigate their textural evolution under different Fe loadings. Iron nanoparticles were hybridized with montmorillonite by impregnation of montmorillonite by ferric ions followed by chemical reduction with sodium borohydride in solution. These hybridized Fe nanoparticles were well dispersed on the montmorillonite surface, size adjustable, and resistant to oxidation under the protection of native Fe-oxide shells. The textural evolution of these heterostructures under various Fe loadings was investigated using nitrogen physisorption, X-ray diffraction, electron microscopy, and elemental analyses. As the Fe loadings increased, the total pore and mesopore volumes were almost unchanged; the total, micropore, and external surface areas as well as the micropore volume decreased; and the average pore diameter increased. These textural changes could be attributed to the filling of the interparticle pores of montmorillonite by a variable amount of Fe nanoparticles. In addition, with increasing Fe loadings, the mesoporous character was enhanced for these heterostructures. These fundamental results are important in understanding the structure of these heterostructures as well as in developing some novel applications in related fields.

The primary focus of this review is on P-T conditions, mineralogical indicators of melt or fluid composition and textural evolution; lesser treatment is given to pegmatite sources or to pegmatite-wallrock interactions. Investigations of stable and radiogenic isotopes have revealed that the source materials for pegmatites are likely to be more heterogeneous or varied than previously thought, especially for peraluminous pegmatites, but that overall pegmatites bear a clear intrusive relationship with their hosts, as opposed to an origin in situ. The P-T conditions of crystallisation of some lithium-rich pegmatites have been constrained by lithium aluminosilicate stability relations in combination with stable isotope or fluid inclusion methods. Experimental studies have elucidated the effects of components such as Li, B, P and F, which are common in some classes of pegmatites, to liquidus relations in the hydrous haplogranite system. Experimentation has also provided corroboration of an old concept of pegmatite crystallisation—that pegmatites owe their distinctive textures and mineral/chemical zonation to relatively rapid crystallisation of melt from the margins inwards at conditions far from the equilibrium (i.e. from supercooled liquids). The origin of aplites, whether alone, layered, or paired with pegmatites, remains an active area of research. Studies of fluid inclusions, crystal-vapour equilibria and wallrock alteration have helped to define the timing and compositions of vapour phases in pegmatites and to aid in the economic evaluation of deposits.