In this study, we present a phase-field model that describes the process of intercalation of Li ions into a layer of an amorphous solid such as amorphous silicon (a-Si). The governing equations couple a viscous Cahn–Hilliard-Reaction model with elasticity in the framework of the Cahn–Larché system. We discuss the parameter settings and flux conditions at the free boundary that lead to the formation of phase boundaries having a sharp gradient in lithium ion concentration between the initial state of the solid layer and the intercalated region. We carry out a matched asymptotic analysis to derive the corresponding sharp-interface model that also takes into account the dynamics of triple points where the sharp interface intersects the free boundary of the Si layer. We numerically compare the interface motion predicted by the sharp-interface model with the long-time dynamics of the phase-field model.

In this paper, we review the recent development of phase-field models and their numerical methods for multi-component fluid flows with interfacial phenomena. The models consist of a Navier-Stokes system coupled with a multi-component Cahn-Hilliard system through a phase-field dependent surface tension force, variable density and viscosity, and the advection term. The classical infinitely thin boundary of separation between two immiscible fluids is replaced by a transition region of a small but finite width, across which the composition of the mixture changes continuously. A constant level set of the phase-field is used to capture the interface between two immiscible fluids. Phase-field methods are capable of computing topological changes such as splitting and merging, and thus have been applied successfully to multi-component fluid flows involving large interface deformations. Practical applications are provided to illustrate the usefulness of using a phase-field method. Computational results of various experiments show the accuracy and effectiveness of phase-field models.

We review recent theoretical progress in the physical understanding of far-from-equilibrium phenomena seen experimentally in epitaxial growth and erosion on crystal surfaces. The formation and dynamics of various interface structures (pyramids, ripples, etc.), and also kinetic phase transitions observed between these structures, can all be understood within a simple continuum model based on the mass conservation law and respecting the symmetries of the growing crystal surface. In particular, theoretical predictions and experimental results are compared for (001), (110) and (111) crystal surfaces.

The Greenberg–Hastings model (GHM) is a simple cellular automaton which emulates two properties of excitable media: excitation by contact and a refractory period. We study two ways in which external stimulation can make ring dynamics in the GHM recurrent. The first scheme involves the initial placement of excitation centres which gradually lose strength, i.e. each time they become inactive (and then stay inactive forever) with probability 1 − pf. In this case, the density of excited sites must go to 0; however, their long–term connectivity structure undergoes a phase transition as pf increases from 0 to 1. The second proposed rule utilizes continuous nucleation in that new rings are started at every rested site with probability ps. We show that, for small ps, these dynamics make a site excited about every ps−1/3 time units. This result yields some information about the asymptotic shape of a closely related random growth model.