This article establishes the role white women played in shaping the urban labor force and the economy in late colonial times in Lima, roughly from 1790 to 1822. It focuses on the impoverished elite women who, by the end of the colonial period, had to ask for alms to avoid working with their own hands. An important part of the Limeño elites could not respond to the twofold challenge: the negative consequences of the economic and administrative reforms of the Bourbons, and the relative flexibilization of the social order in Lima by the end of the eighteenth century. Instead of adapting to new conditions, the Spanish elites generated a social discourse that reaffirmed status and ethnicity as a means to distinguish themselves from the “vicious” plebeian sectors. More than one thousand applications to Church relief programs serve as the main foundation of this article; they are made up of at least one fifth of the white female population of the city in 1806. The article enters into dialogue with studies on socio-labor practices and the history of gender and ethnicity by engaging with concrete experiences of poor elite women in a city considered to be the opulent center of the Spanish colonial power.