The importance of buoyancy relative to free-stream flow is described using an adapted Froude number $Fr' = U/f_0^{1/3}$, where $U$ is the flow speed and $f_0$ is the exhaust buoyancy flux per unit length. We varied $Fr'$ by changing the free-stream flow rate, the exhaust flow rate and the buoyancy of the exhaust. We have experimentally identified two flow regimes, depending on the value of $Fr'$. For high $Fr'$ (low buoyancy), dispersion is driven by inertial forces in the wake and the amount of a pollutant in the wake is independent of $Fr'$. For moderate $Fr'$, a wall plume develops up the back of the step, directly feeding the pollutant into the shear layer, but without altering the shape of the wake. This wall plume reduces the amount of pollutant trapped behind the step. We developed an analytic model to describe the quantity of pollutant trapped behind the step. The model predicts the transition from buoyancy being negligible to being the dominant transport mechanism within the wake. We have hypothesised and observed some evidence of a third regime at low $Fr'$, when the buoyancy is sufficient to distort the macrostructure of the shear layer and wake.