Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
  1. Home
  2. Search

Refine search

Refine search

Access:
Content type:
Publication date:
Apply   From and To filters
Subject: Show more
Journals Show more
Publishers: Show more
Societies Show more
Series: Show more
Collections: Show more

Actions for selected content:

Select all | Deselect all
  • View selected items
  • Export citations
  • Download PDF (zip)
  • Save to Kindle
  • Save to Dropbox
  • Save to Google Drive

Save Search

You can save your searches here and later view and run them again in "My saved searches".

Please provide a title, maximum of 40 characters.
Cancel
×

1 results

  • 10 - Atom Movements with the Vacancy Mechanism

  • from Part II - The Atomic Origins of Thermodynamics and Kinetics
  • Brent Fultz, California Institute of Technology
  • Book:
    Phase Transitions in Materials
    Published online:
    24 April 2020
    Print publication:
    14 May 2020, pp 250-286

  • Summary

    This chapter explains why atom jumps with a vacancy mechanism are not random, even if the vacancy itself moves by random walk. In an alloy with chemical interactions strong enough to cause a phase transformation, the vacancy frequently resides at energetically favorable locations, so any assumption of random walk can be seriously in error. When materials with different diffusivities are brought into contact, their interface is displaced with time because the fluxes of atoms across the interface are not equal in both directions. Even the meaning of the interface, or at least its position, requires new concepts. An applied field can bias the diffusion process towards a particular direction, and such a bias can also be created by chemical interactions between atoms. When thermal atom diffusion occurs in parallel with atom jumps forced without thermal activation, a steady state can be calculated, but it is not a state of thermodynamic equilibrium. Finally, the venerable statistical mechanics model of diffusion by Vineyard is described.