Precise information on the location of charge in clay minerals and their charge density in smectite-dominant soils is rare. The present study was undertaken with three benchmark Vertisols to establish the relationship between the clay cation exchange capacity (CEC), charge density, as well as the location of charge in smectitic soil clay minerals and their relationship with potassium (K) fixation and release. Potassium fractions and their threshold levels in the Vertisols were determined by standard methods. Soils were segregated into silt, total clay and fine clay fractions for X-ray diffraction analysis and fine clay fractions were used to determine the CEC using standard methods. The Hofmann-Klemen effect (HK) and modified Greene-Kelly test was done with the fine clay to determine the CEC of the tetrahedral sheet. Subsequently, the CEC of the octahedral sheet was calculated as the difference between total CEC and the tetrahedral CEC. The results showed that ~60–64% of the total CEC is attributed to the tetrahedral layers. The tetrahedral CEC that is proportional to the tetrahedral charge density was significant and negatively correlated with K release threshold values and all fractions of K. The tetrahedral CEC contributed more toward the K fixation and release than the octahedral CEC. The study shows that the dominant presence of high-charge smectites in the fine clay fractions of these Vertisols contributed to the tetrahedral CEC and consequently to the charge density of these soils, which implied a tendency to fix K easily and release it with greater difficulty compared to soils with low-charge smectites.

Ferruginous beidellites with Al:Fe atomic ratios up to 2.36 were obtained when solutions containing Al, Fe2+ and H4SiO4 were adjusted to pH 8.5 with Ca(OH)2 and incubated at 95 °C in the presence of CaCO3 as a pH buffer. Incubation took place under cyclic reducing and oxidizing conditions achieved by adding 2 mM hydrazine at 14–15-d intervals over a period of 10–13 weeks. During the 14–15-d cycle, atmospheric oxygen slowly diffused through the high-density polyethylene bottles used, causing a slow oxidation of Fe(II) to Fe(III). The infrared (IR) spectra of the products approached that of natural beidellite, but indicated little change in octahedral Al:Fe ratio in the products for starting Al:Fe ratios from 2.5 up to 3.5, which was the highest Al:Fe ratio at which a well-crystallized product was obtained. Chemical analysis showed the presence of more Al+Fe in the products than could be incorporated into a dioctahedral formula. After the excess was assigned to a hydroxy-aluminium interlayer, the formula of the most Al-rich beidellite was calculated to be 0.575Ca(Si6.85A1.15)(Al2.47Fe1.53)O20(OH)4. This composition lay within the range recorded for the ferruginous beidellites that form in Vertisols.

The iron-rich calcareous soil (Typic Rhodustalf) from the Penghu island group represents a volcanic area. The black soils (Typic Haplustert, Vertic Endoaquoll, Typic Hapludolls) are typical of eastern Taiwan. Four A horizons and a pedon from the iron-rich calcareous soil and four pedons from the black soils were studied to analyze soil properties and clay compositions. The objective was to compare the properties of smectites developed from different parent materials. The materials were studied by using conventional X-ray diffraction (XRD) of K- and Mg-saturated clays and involved the alkylam-monium (C = 12) method and the Greene-Kelly test. The mean-layer charge of smectites (0.48–0.52 cmol(c)/O10(OH)2) in the iron-rich calcareous soil was found to be higher than the black soils (0.43–0.48 cmol(c)/O10(OH)2). A smectite of higher charge developed from the basalts. This smectite is enriched in Fe and Mg, and lacks Si, thereby forming beidellite and/or nontronite. In contrast, under high precipitation, elevated temperature, base saturation (e.g., Na, K, Ca, Mg), and about equal wet and dry cycles per year in the black soil environments, smectites developed from the complicated geologic site of eastern Taiwan. These smectites transformed to smectite-kaolinite mixed-layer clay and thus, resulted in lower-charge smectites. The K fixation capacity of the iron-rich calcareous soil was higher than the black soils.

The fertility of soils with respect to K+ and NH4+ is often difficult to measure, but is essential for achieving effective agronomic practices. This problem is especially important in the Vertisols of Thailand. The purpose of the study reported here was to characterize the composition and layer-charge behavior of Thai Vertisols in order to understand better their K+ and NH4+ fertility. Topsoil and subsoil clay of 12 representative highly smectitic Vertisols from Thailand were studied. Interlayer swelling of smectite with alkylammonium cations, cation exchange capacity (CEC), and chemical composition were determined. These data and the re-expansion on glycerol treatment of Li-saturated, heated smectite demonstrated that high-charge, Fe-rich beidellite is the major clay mineral in these soils. The beidellite has a heterogeneous layer-charge distribution as measured by the alkylammonium method, with mean values ranging from 0.43 to 0.62 charges per half unit cell. The layer charge determined by CEC and structural formula methods for some almost pure smectites is smaller (0.32–0.54) and greater (0.46–0.69), respectively, than determined by the alkylammonium method. The structural formulae of beidellite confirm that the layer charge originates mostly in the tetrahedral sheet.

Micromorphological studies were performed in order to understand the factors and processes involved in the formation of calcium carbonate (CaCO3) in twenty three soil series of Vertisols representing sub-humid, semi-arid and arid climatic regions of Peninsular India. The study indicates that Vertisols contain both pedogenic calcium carbonate (PC) and non-pedogenic calcium carbonate (NPC) irrespective of the ecosystems to which they belong. The NPCs are part of the parent material of Vertisols. Dissolution of NPCs and recrystallization of dissolved Ca2+ ions are responsible for the formation of PCs. Vertisols of arid and semi-arid climates contain more PC in their soil control section (SCS) than those of sub-humid climates. Formation of PC is the prime chemical reaction responsible for the increase in pH, the decrease in the Ca/Mg ratio of exchange site with depth and in the development of subsoil sodicity. Petrographic and scanning electron microscopic (SEM) examination of quartz, feldspars and micas indicate little or no alteration, discounting the possibile formation of smectite during Vertisol formation. X-ray diffraction (XRD) analysis of clays indicates that smectites of Vertisols are fairly well crystallized and do not show any sign of transformation except for hydroxy interlayering. The preservation of the crystallinity of smectite and the lack of transformation of primary minerals thus validate the hypothesis of positive entropy change during the formation of Vertisols.

The precise cause-effect relationship between CaCO3 of pedogenic and non-pedogenic origin, and exchangeable Mg, Na and Ca percentages (EMP, ESP and ECP) has been established in the study. This indicates that impoverishment of Ca2+ ions on the exchange sites of Vertisols needs to be controlled by rehabilitation methods that can replenish Ca2+ ions, and thus the study provides relevant information for future land resource management programmes not only on Vertisols of India but also on similar soils occurring elsewhere.

The response of wheat to the application of different rates of nitrogen (N), phosphorus (P), potassium (K), and sulfur (S) under balanced fertilization on different soil types and agroecologies has not been well studied in Ethiopia. Therefore, the objectives of this study were to (1) determine soil-specific responses of wheat to N, P, K, and S under balanced fertilization; (2) quantify agroecology-specific N, P, K, and S response of wheat under balanced fertilization; and (3) determine nutrient use efficiency of wheat on different soil types under balanced fertilization. Trials were conducted on farmers’ fields across 24 locations covering 4 soil types and 5 agroecological zones (AEZs) from 2013 to 2017. The mean grain yields of wheat significantly varied with applied N and P fertilizer rates with soil types and AEZs. With balanced application of other nutrients, the optimum N rates for wheat were 138 kg N ha−1 on Cambisols and Luvisols, 92 kg N ha−1 on Vertisols, and 176 kg N ha−1 on Nitisols, while the optimum P rate was 20 kg P ha−1 on Cambisols and Vertisols. The nutrient dose–response curve did not reveal consistent pattern for K and S applications on all soil types. The agronomic efficiency of wheat decreased with increasing rates N and P on all soil types. The highest agronomic efficiency of N (15.8 kg grain kg−1 applied N) was recorded with application of 92 kg N ha−1 on Vertisols, while the highest agronomic efficiency of P (49 kg grain kg−1 applied P) was achieved with application of 10 kg P ha−1 on Cambisols. We conclude that applications of 92–138 kg N ha−1, 20 kg P ha−1, 18 kg K ha−1, and 10 kg S ha−1 under balanced application of zinc and boron could be recommended depending on soil type for wheat production in the study areas.

Nutrient deficiency is a major constraint in tef (Eragrostis tef (Zucc.) Trotter) production in Ethiopia. In the past, a blanket recommendation of nitrogen (N) and phosphorus (P) fertilizers has been applied regardless of the diversity of agroecological zones and soil types. As crop responses declined with widespread deficiencies of nutrients, farmers have lost interest in applying the recommended fertilizer rates. The present study was conducted with the objective of quantifying the response of tef to different rates of N, P, potassium (K) and sulphur (S) fertilizers under balanced application of the nutrients other than the one under investigation. In each region, the same set of trials was implemented on farmers’ fields for three years. All trials were implemented on Vertisols across four agroecological zones (AEZs). The treatments were seven rates of N, six rates each of P and S and eight rates of K with a basal application of zinc (Zn) and boron (B). The results showed that the most limiting nutrient is N followed by P in each agroecological zone on the Vertisols. There was clear evidence of increases in grain yield with increasing rates of N and P, but the responses to K and S rates did not follow clear trends across AEZs. With balanced application of the other nutrients, 23–92 kg N ha−1 increased grain yield by 11–92%, while 10–40 kg P ha−1 increased yields by 12–33% over the control in the different AEZs. Based on results from dose–response models, it is concluded that the agronomic optimum rates for tef production are 69 kg N, 20 kg P, 30 kg K and 10 kg S ha−1 in the cool sub-moist mid-highlands and the tepid sub-humid mid highlands; 92 kg N, 30 kg P, 15 kg K and 10 kg S ha−1 in tepid moist mid highlands but 69 kg N, 10 kg P, 15 kg K and 10 kg S ha−1 in the tepid sub-moist mid highlands. On Vertisols not covered by this study, these recommendations should be subject to appropriate soil and plant analysis. We also recommend further studies on the nutrient requirement of tef on other soil types and AEZs.

Smectite formation in a vertisol developed from a granitic parent rock in the Kaélé region of Cameroon in a tropical, dry climate was studied by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), chemical analyses, cation exchange capacity (CEC) and low temperature gas adsorption. The soil profile comprises three horizons (from base to top): (1) a saprolite, (2) an intermediate horizon, and (3) an upper dark grey horizon. In the saprolite, the progressive alteration of feldspars gave rise to the exclusive neoformation of beidellite exhibiting a typical honeycomb fabric. This process resulted in Al, Fe, Ca, Mg, Ti and Mn enrichment, a depletion of Si and Na and a significant negative Eu anomaly. In the upper horizons, beidellite evolves and is transformed into montmorillonite and kaolinite, probably through a series of smectite-kaolinite mixed layers. This transformation, from the saprolite to the upper horizons, causes the observed decrease in the CEC and the increase in specific surface area and mesoporosity of the clay. The REE patterns of the bulk soil and clay fraction display similar behaviour, indicating that the three horizons, and hence the clay minerals, have a common source in the underlying granite. Mass-balance calculations show that the intense weathering of the granite leads to a mass reduction of ~80–90%.

Soil and water conservation and improved crop management programs were initiated in 1983 to increase the productivity of a dryland vertisol watershed in the state of Andhra Pradesh in the semi-arid tropical region of India. This was one of 47 model watersheds developed by the Government of India. The integrated program consisted of measures to conserve soil and water, such as a percolation tank, grading, checks, and deep tillage, on which were superimposed improved crop management practices (e.g., cultivars, fertilizers, and timeliness in operations), carried out with the farmers' cooperation and partial payment. All participants were surveyed in 1983, before starting the program, and 1988, after completing the program. The equilibrium water levels in open wells increased about 50 cm, which allowed sugarcane to be introduced. About 10% additional area was reclaimed and cultivated after construction of a diversion dam. Fodder supply improved because of the growth of natural grasses on terraces formed by stone checks in waterways. Soil and water conservation efforts reduced runoff about 26%. Ground cover increased by 38% because of increased cropping intensity, and income per capita grew by 67% per year. Thus, the integrated approach conserved natural resources and improved productivity.