Newly developed erosion-plasma-source probe technique has been applied for virtually single shot recording of absorption/fluorescence spectra in the 190–510 nm spectral range of e-beam-excited Ar/Kr/NF3(F2 + N2) mixtures. The e-beam excitation rate of about 1 MW/cm3 is typical of large-volume rare-gas halide lasers. It is experimentally observed that, in Kr/F2 and Ar/F2 mixtures, fluorescence and absorption spectra of Rg2F species are shifted with respect to each other in the opposite direction. Continuous absorption spectrum of Ar2F excimer is reported, as far as we know, for the first time in the refereed literature. Strong overlapping between the fluorescence and absorption spectra of Ar2F is responsible for absence of lasing on Ar2F molecule. Absorption spectrum of Kr2F excimer is recorded in pure form using the mixture (Ne/Kr/F2) with no alternative broadband absorber. Minor additive of nitrogen to Ar/Kr/F2 mixture or use of NF3 instead of F2 has been found to result in broadband optical amplification centered at λ ~ 460 nm. The maximum optical gain is estimated as about 0.1 ± 0.05 m−1.
