It is shown that the effective hot electron temperature, Thot, associated with the energetic electrons produced during the interaction of an ultra-intense laser with thin solid targets is dependent on the thickness of the target. We report the first direct experimental observations of electron energy spectra obtained from laser-solid interactions that indicates the reflexing of electrons in thin targets results in higher electron temperatures than those obtained in thick target interactions. This can occur for targets whose thickness, xt, is less than about half the range of an electron at the energy associated with the initial effective electron temperature, provided the laser pulse length is at least cτp > 2xt. A simple theoretical model that demonstrates the physical mechanism behind this enhanced heating is presented and the results of computer simulations are used to verify the model.