Published online by Cambridge University Press: 12 June 2017
The volatilities of iso and normal butyl esters of 2,4-D [(2,4-dichlorophenoxy)acetic acid] in a commercial formulation applied as thin films on pyrex and as aqueous droplets on pyrex and leaf surfaces increased directly with the available surface area/applied dose ratio (Q), and inversely with the adsorptive and absorptive characteristics of the surface, under the same conditions of temperature (39 ± 1.5 C), relative humidity (RH) (0%), geometry, airflow rate (750 ± 7 ml/min) and light. Partial pressures and rates of volatilization were computed. Herbicide in droplets below 200μ in diameter tended to volatilize faster than it penetrated, but the reverse occurred above this diameter.