Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-25T19:23:31.571Z Has data issue: false hasContentIssue false
  • English
  • Français

Herbicide dynamics in the Bogue Phalia watershed in the Yazoo River basin of Mississippi

Published online by Cambridge University Press:  20 January 2017

David R. Shaw ,
Stephen M. Schraer ,
Joby Prince  and
Michele Boyette
Stephen M. Schraer
Affiliation:
Department of Plant and Soil Sciences, Mississippi State University, Box 9555, Mississippi State, MS 39762
Joby Prince
Affiliation:
Department of Plant and Soil Sciences, Mississippi State University, Box 9555, Mississippi State, MS 39762
Michele Boyette
Affiliation:
Department of Plant and Soil Sciences, Mississippi State University, Box 9555, Mississippi State, MS 39762
Get access Rights & Permissions [Opens in a new window]

Abstract

A two-year surface water reconnaissance of the Bogue Phalia and its tributaries was conducted in 1997 and 1998. Cyanazine and metolachlor in surface water samples were quantified using enzyme-linked immunosorbent assays (ELISA). Cyanazine and metolachlor were detected in 101 and 132 of 160 samples, respectively. Cyanazine concentrations ranged from 0.1 to 2.2 g L−1 and exceeded the U.S. Environmental Protection Agency (EPA) lifetime health advisory level (HAL) of 1 g L−1 in eight samples. However, concentrations never exceeded the HAL for shorter exposure times. Metolachlor concentrations never reached the lifetime HAL of 100 g L−1. Metolachlor concentrations ranged from 0.1 to 20.6 g L−1. Metolachlor was detected more frequently and found to be more persistent throughout the growing season than was cyanazine. Higher cyanazine and metolachlor concentrations were detected at sampling dates that coincided with herbicide applications. One of the Bogue Phalia's tributaries, Clear Creek, was found to be a point-source of cyanazine for the watershed.

Keywords

Cyanazine, metolachlorSurface water qualityMississippi Deltawatershedimmunoassayenzyme-linked immunosorbent assay
Type
Research Article
Information
Weed Science , Volume 54 , Issue 4 , August 2006 , pp. 807 - 813
Copyright
Copyright © Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

Blumhorst, M. R. and Weber, J. B. 1992. Cyanazine dissipation as influenced by soil properties. J. Agric. Food Chem 40:894–897.CrossRefGoogle Scholar
Burgard, D. J., Koskinien, W. C., Dowdy, R. H., and Cheng, H. H. 1993. Metolachlor distribution in a sandy soil under irrigated potato production. Weed Sci 41:648–655.Google Scholar
Cochran, W. G. and Cox, G. M. 1992. Experimental Designs, 2nd ed. Indianapolis: J. Wiley. Pp. 148–181.Google Scholar
Coupe, R. H., Thurman, E. M., and Zimmerman, L. R. 1998. Relation of usage to the occurrence of cotton and rice herbicides in three streams of the Mississippi Delta. Environ. Sci. Technol 32:3673–3680.Google Scholar
Crawford, C. G. 2001. Factors affecting pesticide occurrence and transport in a large Midwestern river basin. J. Am. Water Resour. Assoc 37:1–15.Google Scholar
Gish, T. J., Helling, C. S., and Mojasevic, M. 1991. Preferential movement of atrazine and cyanazine under field conditions. Trans. ASAE 34:1699–1705.Google Scholar
Kolpin, D. W., Thurman, E. M., and Linhart, S. M. 2001. Occurrence of cyanazine compounds in groundwater: degradates more prevalent than the parent compound. Environ. Sci. Technol 35:1217–1222.Google Scholar
Littell, R. C., Milliken, G. A., Stroup, W. W., and Wolfinger, R. D. 1996. SAS System for Mixed Models. SAS Institute, Inc., Cary, NC.Google Scholar
Meade, R. H. ed. 1995. Contaminants in the Mississippi River, 1987–92. Reston, VA: U.S. Geological Survey Circular 1133.CrossRefGoogle Scholar
[MARIS] Mississippi Automated Resource Information System. 1997. MARIS GIS: State Digital Geographic Database. www.maris.state.ms.us.Google Scholar
[MCES] Mississippi Cooperative Extension Service. 1998. Mississippi Agriculture: 1972–1998. Mississippi State, MS: Mississippi Cooperative Extension Service, Mississippi State University.Google Scholar
Mojasevic, M., Helling, C. S., Gish, T. J., and Doherty, M. A. 1996. Persistence of seven pesticides as influenced by soil moisture. J. Environ. Sci. Health B31:469–476.Google Scholar
[NASS] National Agricultural Statistics Service. 2005. Agriculture Statistics 2005. Washington, DC: U.S. Government Printing Office.Google Scholar
[NASS] National Agricultural Statistics Service. 2002. 2002 Census of Agriculture, Volume 1 Geographic Area Series Census, State—County Data. Washington, DC: U.S. Government Printing Office.Google Scholar
Novak, J. M., Watts, D. W., Stone, K. C., and Johnson, M. H. 2001. Seasonal occurrence and export of five herbicides from a North Carolina coastal plain watershed. Trans. ASAE 44:1201–1206.Google Scholar
Pereira, W. E. and Hostettler, F. D. 1993. Nonpoint source contamination of the Mississippi River and its tributaries by herbicides. Environ. Sci. Technol 27:1542–1552.Google Scholar
Pereira, W. E. and Rostad, C. E. 1990. Occurrence, distributions, and transport of herbicides and their degradation products in the lower Mississippi River and its tributaries. Environ. Sci. Technol 24:1400–1406.Google Scholar
Petersen, B. B., Shea, P. J., and Wicks, G. A. 1988. Acetanilide activity and dissipation as influenced by formulation and wheat stubble. Weed Sci 36:243–249.CrossRefGoogle Scholar
Pettry, D. E. 1977. Soil Resource Areas of Mississippi. Mississippi State, MS: Mississippi Agricultural and Forestry Experimental Station Information Sheet No. 1278.Google Scholar
Plunkett, M. L., Morris, F., Oakley, W. T., and Turnipseed, D. P. 1998. Water Resources Data: Mississippi Water Year 1997. Pearl, MS: Water Resources Division, U.S. Geological Survey Water-Data Report MS-97–1.Google Scholar
[SAS] Statistical Analysis Systems. 1988. SAS Procedures Guide, Release 6.03 ed. Cary, NC: Statistical Analysis Systems Institute.Google Scholar
Schraer, S. M., Shaw, D. R., Boyette, M., Coupe, R. H., and Thurman, E. M. 2000. Comparison of enzyme-linked immunosorbent assay and gas chromatography procedure for the detection of cyanazine and metolachlor in surface water samples. J. Agric. Food Chem 48:5881–5886.Google Scholar
Senseman, S. A., Lavy, T. L., Mattice, J. D., Gbur, E. D., and Skulman, B. W. 1997. Trace level pesticide detections in Arkansas surface waters. Environ. Sci. Technol 31:395–401.Google Scholar
Seybold, C. A., Mersie, W., and McNamee, C. 2001. Anaerobic degradation of atrazine and metolachlor and metabolite formation in wetland soil and water microcosms. J. Environ. Qual 30:1271–1277.CrossRefGoogle ScholarPubMed
Smith, A. E. and Walker, A. 1989. Prediction of the persistence of the triazine herbicides atrazine, cyanazine, and metribuzin in Regina Heavy Clay. Can. J. Soil Sci 69:587–595.CrossRefGoogle Scholar
Takacs, P., Martin, P. A., and Struger, J. 2002. Pesticides in Ontario: A Critical Assessment of Potential Toxicity of Agricultural Products to Wildlife, with Consideration for Endocrine Disruption, Volume 2: Triazine Herbicides, Glyphosate, and Metolachlor. Burlington, Ontario, Canada: Canadian Wildlife Service, Ontario Region, Technical Report Series 369.Google Scholar
Thurman, E. M., Goolsby, D. A., Meyer, M. T., and Kolpin, D. W. 1991. Herbicides in surface waters of the midwestern United States: the effect of spring flush. Environ. Sci. Technol 25:1794–1796.Google Scholar
Thurman, E. M., Goolsby, D. A., Meyer, M. T., Mills, M. S., Pomes, M. L., and Kolpin, D. W. 1992. A reconnaissance study of herbicides and their metabolites in surface water of the midwestern United States using immunoassay and gas chromatography/mass spectrometry. Environ. Sci. Technol 26:2440–2447.Google Scholar
[US EPA] U.S. Environmental Protection Agency. 2004. Drinking Water Standards and Health Advisories. Washington, DC: U.S. Environmental Protection Agency, Office of Water 822-R-04-005.Google Scholar
Wauchope, R. D., Buttler, T. M., Hornsby, A. G., Augustijn-Beckers, P. W. M., and Burt, J. P. 1992. The SCS/ARS/CES pesticide properties database for environmental decision-making. Rev. Environ. Contam. Toxicol 123:1–164.Google Scholar