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Superconducting Cu2Mo6S8 thin films deposited in-situ by laser ablation on R-plane sapphire*

Published online by Cambridge University Press:  15 February 1998

N. Lemée
Affiliation:
Laboratoire de Chimie du Solide et Inorganique Moléculaire (UMR CNRS 6511), Université de Rennes I, campus de Beaulieu, 35042 Rennes Cedex, France
M. Guilloux-Viry*
Affiliation:
Laboratoire de Chimie du Solide et Inorganique Moléculaire (UMR CNRS 6511), Université de Rennes I, campus de Beaulieu, 35042 Rennes Cedex, France
A. Perrin
Affiliation:
Laboratoire de Chimie du Solide et Inorganique Moléculaire (UMR CNRS 6511), Université de Rennes I, campus de Beaulieu, 35042 Rennes Cedex, France
M. Sergent
Affiliation:
Laboratoire de Chimie du Solide et Inorganique Moléculaire (UMR CNRS 6511), Université de Rennes I, campus de Beaulieu, 35042 Rennes Cedex, France
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Abstract

Thin films of ${\rm Cu_2Mo_6S_8}$ have been in-situ deposited by pulsed laser deposition on R-plane ${\rm Al_2O_3}$ on which an epitaxial growth has been achieved for the first time, with the $(100)_R$ orientation, as shown by X-ray diffraction. The superconducting transition temperature has been determined from DC resistive and AC susceptibility measurements. The critical temperature Tc is typically between 9.5 and 10.3 K and the transitions are narrow: the full width at half maximum of the inductive signal $\chi ''$ ranges between 0.1 and 0.5 K. The critical current densities have been obtained by standard four probe electrical measurements: in zero field a value larger than $10^8\; {\rm A}/{\rm m}^2$ has been measured at only 1 K from the end of the transition, and values typically larger than $10^7\;{\rm A}/{\rm m}^2$ at 4.2 K in an applied magnetic field of 7 T have been observed. The upper critical magnetic field, Bc2, has been determined from the critical current measurements performed at 4.2 K in an applied magnetic field, for two samples. The experimental values of 11 and 12.5 T at 4.2 K are close to those reported on bulk samples (12.5 T). For the first time to our knowledge a surface resistance $(R_{\rm s})$ measurement has been carried out on a Chevrel phase-type compound: a value of 4.5 mΩ at 10 GHz and 4.2 K has been obtained.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 1998

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Footnotes

*

In honour of Dr. Jean Padiou on the occasion of his retirement. This paper was presented at "5es Journées de Cryogénie et de Supraconductivité" held at Aussois in April 1997.

References

* In honour of Dr. Jean Padiou on the occasion of his retirement. This paper was presented at "5es Journées de Cryogénie et de Supraconductivité" held at Aussois in April 1997.