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Structural, optical and nanomechanical properties of (1 1 1) oriented nanocrystalline ZnTe thin films

Published online by Cambridge University Press:  17 June 2010

M. S.R.N. Kiran
Affiliation:
Department of Materials Engineering, Indian Institute of Science, Bangalore, India
S. Kshirsagar
Affiliation:
Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad, India
M. G. Krishna*
Affiliation:
Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad, India School of Physics, University of Hyderabad, Hyderabad, India
Surya P. Tewari
Affiliation:
Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad, India School of Physics, University of Hyderabad, Hyderabad, India
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Abstract

Structural, optical and nanomechanical properties of nanocrystalline Zinc Telluride (ZnTe) films of thickness upto 10 microns deposited at room temperature on borosilicate glass substrates are reported. X-ray diffraction patterns reveal that the films were preferentially oriented along the (1 1 1) direction. The maximum refractive index of the films was 2.74 at a wavelength of 2000 nm. The optical band gap showed strong thickness dependence. The average film hardness and Young's modulus obtained from load-displacement curves and analyzed by Oliver-Pharr method were 4 and 70 GPa respectively. Hardness of (1 1 1) oriented ZnTe thin films exhibited almost 5 times higher value than bulk. The studies show clearly that the hardness increases with decreasing indentation size, for indents between 30 and 300 nm in depth indicating the existence of indentation size effect. The coefficient of friction for these films as obtained from the nanoscratch test was ~0.4.

Type
Research Article
Copyright
© EDP Sciences, 2010

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