Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-26T16:57:52.411Z Has data issue: false hasContentIssue false

Structural, optical and nanomechanical properties of (1 1 1) oriented nanocrystalline ZnTe thin films

Published online by Cambridge University Press:  17 June 2010

M. S.R.N. Kiran
Affiliation:
Department of Materials Engineering, Indian Institute of Science, Bangalore, India
S. Kshirsagar
Affiliation:
Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad, India
M. G. Krishna*
Affiliation:
Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad, India School of Physics, University of Hyderabad, Hyderabad, India
Surya P. Tewari
Affiliation:
Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad, India School of Physics, University of Hyderabad, Hyderabad, India
Get access

Abstract

Structural, optical and nanomechanical properties of nanocrystalline Zinc Telluride (ZnTe) films of thickness upto 10 microns deposited at room temperature on borosilicate glass substrates are reported. X-ray diffraction patterns reveal that the films were preferentially oriented along the (1 1 1) direction. The maximum refractive index of the films was 2.74 at a wavelength of 2000 nm. The optical band gap showed strong thickness dependence. The average film hardness and Young's modulus obtained from load-displacement curves and analyzed by Oliver-Pharr method were 4 and 70 GPa respectively. Hardness of (1 1 1) oriented ZnTe thin films exhibited almost 5 times higher value than bulk. The studies show clearly that the hardness increases with decreasing indentation size, for indents between 30 and 300 nm in depth indicating the existence of indentation size effect. The coefficient of friction for these films as obtained from the nanoscratch test was ~0.4.

Type
Research Article
Copyright
© EDP Sciences, 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Merchant, J.D., Cocievera, M., J. Electrochem. Soc. 143, 4054 (1996) CrossRef
Ota, T., Takahashi, K., Solid-State Electron. 16, 1089 (1973) CrossRef
Nishio, M., Hayashida, K., Guo, Q., Ogawa, H., Appl. Surf. Sci. 169, 223 (2001) CrossRef
Guo, Q., Kume, Y., Fukuhara, Y., Tanaka, T., Nishio, M., Ogawa, H., Hiratsuka, M., Tani, M., Hangyo, M., Solid State Commun. 141, 188 (2007) CrossRef
Leitenstorfer, A., Hunsche, S., Shah, J., Nuss, M.C., Knox, W.H., Appl. Phys. Lett. 74, 1516 (1999) CrossRef
Raju, K.N., Vijayalakshmi, R.P., Venugopal, R., Reddy, D.R., Reddy, B.K., Mater. Lett. 13, 336 (1992) CrossRef
Su, C.H., Volz, M.P., Gilles, D.C., Szofran, F.R., Lehoczky, M.R., J. Cryst. Growth 128, 627 (1993) CrossRef
Khan, M.R.H., J. Phys. D: Appl. Phys. 27, 2190 (1994) CrossRef
Tao, W.I., Jurkovice, M., Wang, I.W., Appl. Phys. Lett. 64, 1848 (1994) CrossRef
Maiti, B., Gupta, S., Chaudhuri, S., Pal, A.K., Thin Solid Films 239, 104 (1994) CrossRef
Wolf, K., Stanzl, H., Naumov, A., Wagner, H.P., Kuhn, W., Kahn, B., Gebhardt, W., J. Cryst. Growth 138, 412 (1994) CrossRef
Neumann-Spallart, M., Konigstein, C., Thin Solid Films 265, 33 (1995) CrossRef
Bozzini, B., Lenardi, C., Lovergine, N., Mater. Chem. Phys. 66, 219 (2000) CrossRef
Jun, Y., Kim, K.J., Kim, D., Met. Mater. 5, 279 (1999) CrossRef
Arico, S., Silvestro, D., Antonucci, P.L., Giodano, N., Antonucci, V., Adv. Perform. Mater. 4, 115 (1997) CrossRef
Ibrahim, A.A., Vacuum 81, 527 (2006) CrossRef
Mahalingam, T., John, V.S., Rajendran, S., Sebastian, P.J., Semicond. Sci. Technol. 17, 465 (2002) CrossRef
Basol, B.M., Kapur, V.K., Thin Solid Films 165, 237 (1988) CrossRef
Patel, S.M., Patel, N.G., Mater. Lett. 2, 131 (1983) CrossRef
Rao, G.K., Bangera, K.V., Shivakumar, G.K., Vacuum 83, 1485 (2009) CrossRef
Purçek, G., Bacaksız, E., Miskioğlu, I., J. Mat. Process. Technol. 198, 202 (2008) CrossRef
Saha, R., Nix, W.D., Acta Mater. 50, 23 (2002) CrossRef
Jen, S.U., Wu, T.C., Thin Solid Films 492, 166 (2005) CrossRef
Portinha, A., Teixeire, V., Carneiro, J.O., Dup, S.N., Shmegera, R., Tavares, C.J., Surf. Coat. Technol. 200, 765 (2005) CrossRef
Simunkova, S., Blahova, O., Stepanek, I., J. Mater. Process. Technol. 133, 189 (2003) CrossRef
Fang, T.H., Chang, W.J., Microelectron. Eng. 65, 231 (2003) CrossRef
Carneiro, J.O., Teixeira, V., Portinha, A., Dub, S.N., Shmegera, R., Rev. Adv. Mater. Sci. 7, 83 (2004)
Shaaban, E.R., Kansal, I., Mohamed, S.H., Ferreira, J.M.F., Physica B: Condens. Matter 404, 3571 (2009) CrossRef
Swanepoel, R., J. Phys. E: Sci. Instrum. 16, 121 (1983) CrossRef
Swanepoel, R., J. Phys. E: Sci. Instrum. 17, 896 (1984) CrossRef
Khawaja, E.E., Al-Daous, M.A., Durrani, S.M.A., Al-Kuhaili, M.F., Thin Solid Films 485, 16 (2005) CrossRef
Davis, E.A., Mott, N.F., Philos. Mag. 22, 903 (1970) CrossRef
Fagen, E.A., Fritzsche, H., J. Non-Cryst. Solids 2, 180 (1970) CrossRef
Shaaban, E.R., Abdel-Rahman, M., Yousef, E.S., Dessouky, M.T., Thin Solid Films 515, 3810 (2007) CrossRef
Krishna, M.G., Bhattacharya, A.K., Mater. Sci. Eng. B 86, 41 (2001) CrossRef
Kiran, M.S.R.N., Krishna, M.G., Padmanabhan, K.A., Appl. Surf. Sci. 255, 1934 (2008) CrossRef
Yakuphanoglu, F., Sekerci, M., Balaban, A., Opt. Mater. 27, 1369 (2005) CrossRef
Mahalingam, T., John, V.S., Rajendran, S., Ravi, G., Sebastian, P.J., Surf. Coat. Technol. 155, 245 (2002) CrossRef
Oliver, W.C., Pharr, G.M., J. Mater. Res. 7, 1564 (1992) CrossRef
Oliver, W.C., Pharr, G.M., J. Mater. Res. 19, 3 (2004) CrossRef
L.I. Berger, Semiconductor Materials, 1st edn. (CRC Press, New York, 1996)
Grillo, S.E., Glénat, H., Tite, T., Pages, O., Maksimov, O., Tamargo, M.C., Appl. Phys. Lett. 93, 081901 (2008) CrossRef
Simunkova, S., Blahova, O., Stepanek, I., J. Mater. Process. Technol. 133, 189 (2003) CrossRef
Durst, K., Goken, M., Pharr, G.M., J. Phys. D: Appl. Phys. 41, 074005 (2008) CrossRef
Fleck, N.A., Muller, G.M., Ashby, M.F., Hutchinson, J.W., Acta Metall. Mater. 42, 475 (1994) CrossRef
Fleck, N.A., Hutchinson, J.W., Adv. Appl. Mech. 33, 295 (1997) CrossRef
Nix, W.D., Gao, H., J. Mech. Phys. Solids 46, 411 (1998) CrossRef
Ashby, M.F., Philos. Mag. 21, 399 (1970) CrossRef