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Optical and electrical properties of nanostructured heterojunction (Au|PdPc|ClAlPc|Al) and using as O2 sensor

Published online by Cambridge University Press:  18 August 2011

M.E. Azim-Araghi
Affiliation:
Applied Physics Division, Physics Department, Tarbiat Moallem University, 49 Mofateh Avenue, Tehran, Islamic Republic of Iran
E. Karimi-Kerdabadi*
Affiliation:
Applied Physics Division, Physics Department, Tarbiat Moallem University, 49 Mofateh Avenue, Tehran, Islamic Republic of Iran
M.J. Jafari
Affiliation:
Applied Physics Division, Physics Department, Tarbiat Moallem University, 49 Mofateh Avenue, Tehran, Islamic Republic of Iran
*
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Abstract

Nanostructure thin films and sandwich devices of palladium phthalocyanine (PdPc) and chloro-aluminum-phthalocyanine (ClAlPc) were prepared by thermal evaporation technique. Optical and struc- tural properties of nanostructure thin films were investigated by XRD, SEM and optical absorption. The SEM images demonstrated PdPc (40–60 nm) and ClAlPc (30–50 nm) nanostructures. XRD pat- terns showed that thin films are in α-phase at room temperature. Also, optical bandgap energy of thin films was calculated by optical absorption spectra. Heterojunction (Au|PdPc|ClAlPc|Al) and single layer (Au|PdPc|Al and Au|ClAlPc|Al) devices were fabricated. Electrical measurements demonstrated the semi-conducting and photo-conducting behavior of thin films. After that, devices were exposed to different concentrations of O2 at 300 K and 350 K and conductivity of thin films was increased on exposure to O2 . Heterojunction devices were more sensitive than other thin films and had better response and reversibility in comparison with single layer devices at 350 K. Finally, 10% O2 was mixed with different percentages of relative humidity and all results showed that the conductivity of thin films is reduced on exposure to O2 mixed to humidity.

Type
Research Article
Copyright
© EDP Sciences, 2011

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