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A new dielectric effect in viscous liquids

Published online by Cambridge University Press:  13 June 2013

Vittorio Capano
Affiliation:
Università Statale di Bergamo, Facoltà di Ingegneria, viale Marconi 5, 24044 Dalmine (BG), Italy
Salvatore Esposito*
Affiliation:
Istituto Nazionale di Fisica Nucleare, Sezione di Napoli, Complesso Universitario di Monte S. Angelo, via Cinthia, 80126 Naples, Italy
Giovanni Salesi*
Affiliation:
Università Statale di Bergamo, Facoltà di Ingegneria, viale Marconi 5, 24044 Dalmine (BG), Italy Istituto Nazionale di Fisica Nucleare, Sezione di Milano, via Celoria 16, 20133 Milan, Italy
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Abstract

An accurate experimental and theoretical study has been performed about a phenomenon, not previously reported in the literature, occurring in highly viscous liquids: the formation of a definite pipe structure induced by the passage of a heavy body, this structure lasting for quite a long time. A very rich phenomenology (including mechanical, optical and structural effects) associated with the formation of the pipe has been observed in different liquids. Actually, the peculiar dynamical evolution of that structure does not appear as a trivial manifestation of standard relaxation or spurious effects. In particular, we have revealed different time scales during the evolution of the pipe and a non-monotonous decrease of the persistence time with decreasing viscosity (with the appearance of at least two different maxima). We put forward a microscopic model, consistent with the experimental data, where the pipe behaves as a “dielectric shell” whose time evolution is described through a simple thermodynamical approach, predicting several properties effectively observed.

Type
Research Article
Copyright
© EDP Sciences, 2013

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References

Dixon, P.K., Wu, L., Nagel, S.R., Phys. Rev. Lett. 65, 1108 (1990)CrossRef
Götze, W., Sjögren, L., Rep. Prog. Phys. 55, 241 (1992)CrossRef
Lunkenheimer, P., Pimenov, A., Dressel, M., Goncharov, Y.G., Böhmer, R., Loidl, A., Phys. Rev. Lett. 77, 318 (1996)CrossRef
Hansen, C., Stickel, F., Berger, T., Richert, R., Fischer, E.W., J. Chem. Phys. 107, 1086 (1997)CrossRef
Angell, C.A., Ngai, K.L., McKenna, G.B., McMillan, P.F., Martin, S.W., J. Appl. Phys. 88, 3113 (2000)CrossRef
Sudo, S., Shimomura, M., Shinyashiki, N., Yagihara, S., J. Non-Cryst. Solids 307–310, 356 (2002)CrossRef
Blochowicz, T., Tschirwitz, C., Benkhof, S., Róssler, E.A., J. Chem. Phys. 118, 7544 (2003)CrossRef
Sanz, A., Jimenez-Ruiz, M., Nogales, A., Martín y Marero, D., Ezquerra, T.A., Phys. Rev. Lett. 93, 015503 (2004)CrossRef
Wang, L.-M., Shahriari, S., Richert, R., J. Phys. Chem. B 109, 23255 (2005)CrossRef
Donth, E., The Glass Transition: Relaxation Dynamics in Liquids and Disordered Materials (Springer, Berlin, 2001)CrossRefGoogle Scholar
Kremer, F., Schonhals, A. (eds.), Broadband Dielectric Spectroscopy (Springer, Berlin, 2003)CrossRefGoogle Scholar
Lawrie, J.W., Glycerol and the Glycols: Production, Properties and Analyses (Chemical Catalog Company, New York, 1928)Google Scholar
Miner, C.S., Dalton, N.N., Glycerol (Reinhold, Baltimore, 1953)Google Scholar
Ubbelohde, A.R., The Molten State of Matter (Wiley, New York, 1978) Chap. 16Google Scholar
Lee, R.E. Jr., Chen, C.P., Denlinger, D.L., Science 238, 1415 (1987)CrossRef
Franks, F. (eds.), Water: A comprehensive Treatise, vol. 7 (Plenum, New York, 1982)Google Scholar
Mazur, P., Science 168, 939 (1970)CrossRef
Fahy, G.M., Levy, D.I., Ali, S.E., Cryobiology 24, 196 (1987)CrossRef
Chang, Z., Baust, J.G., Cryobiology 28, 268 (1991)CrossRef
Vigier, G., Vassoille, R., Cryobiology 24, 345 (1987)CrossRef
Boutron, P., Arnaud, F., Cryobiology 21, 348 (1984)CrossRef
Angell, C.A., in Relaxations in Complex Systems, edited by Ngai, K.L., Wright, G.B. (NRL, Washington DC, 1985)Google Scholar
Bóhmer, R., Angell, C.A., Phys. Rev. B 45, 10091 (1992)CrossRef
Eyring, H., Henderson, D., Jost, W. (eds.), Physical Chemistry: An Advanced Treatise, vol. VIIIA – Liquid State, edited by Henderson, D. (Academic Press, New York, 1971)Google Scholar
Bottcher, C.J.F., Theory of Electric Polarization (Elsevier, Amsterdam, 1973)Google Scholar
Croxton, C.A., Statistical Mechanics of the Liquid Surface (Wiley, New York, 1980)Google Scholar
Frenkel, J., Kinetic Theory of Liquids (Dover, New York, 1955)Google Scholar