Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-26T17:58:00.509Z Has data issue: false hasContentIssue false

Growth and nonlinear optical studies of N-acetyl-L-cysteine crystal

Published online by Cambridge University Press:  02 December 2011

L. Guru Prasad
Affiliation:
Department of Physics, Periyar University, Salem 636 011, India
V. Krishnakumar*
Affiliation:
Department of Physics, Periyar University, Salem 636 011, India
R. Nagalakshmi
Affiliation:
Department of Physics, National Institute of Technology, Tiruchirappalli 620 015, India
*
Get access

Abstract

Crystals of N-acetyl-L-cysteine have been grown by slow evaporation solution growth technique using water as solvent. Cell parameters of the crystals were confirmed by powder X-ray diffraction. Functional groups were identified and their vibrational activity was studied by investigating the FTIR spectrum. Decomposition nature of the grown material was studied in thermal analysis. Transparent nature of the crystal in UV-VIS-NIR region was examined by optical absorption spectrum. Frequency conversion process was tested and the title crystal has two times larger relative second harmonic conversion efficiency compared to the standard KDP. Static and dynamic values of first-order hyperpolarizability were calculated and also the electronic excitation mechanism was analyzed.

Type
Research Article
Copyright
© EDP Sciences, 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Fang, L., Yang, G.C., Qiu, Y.Q., Su, Z.M., Theor. Chem. Acc. 110, 329 (2008)CrossRef
Ravindra, H.J., Chandrashekaran, K., Harrision, W.T.A., Dharmaprakash, S.M., Appl. Phys. B 94, 503 (2009)CrossRef
Atalay, Y., Avci, D., Basogulu, A., Struct. Chem. 19, 239 (2008)CrossRef
Benkova, Z., Cernusak, I., Zahradnık, P., Struct. Chem. 17, 287 (2006)CrossRef
Barus, C., Gros, P., Comtat, M., Daunes-Marion, S., Tarroux, R., Electrochim. Acta 52, 7978 (2007)CrossRef
Mayer, M., Noble, M., Proc. Natl. Acad. Sci. USA 91, 7496 (1994)CrossRef
Menon, S.G., Sarsour, E.H., Kalen, A.L., Venkataraman, S., Hitchler, M.J., Domann, F.E., Oberley, L.W., Goswami, P.C., Cancer Res. 67, 6392 (2007)CrossRef
Gao, Z.-N., Zhang, J., Liu, W.-Y., J. Electroanal. Chem. 580, 9 (2005)CrossRef
Frish, M.J., Trucks, G.W., Schlegel, H.B., Schlegel, G.E., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Zakrzewski, V.G., Montgomery, J.A. Jr., Stratmann, R.E., Burant, J.C., Dapprich, S., Millam, J.M., Daniels, A.D., Kudin, K.N., Strain, M.C., Farkas, O., Tomasi, J., Barone, V., Cossi, M., Cammi, R., Mennucci, B., Pomelli, C., Adamo, C., Clifford, S., Ochterski, J., Petersson, G.A., Ayala, P.Y., Cui, Q., Morokuma, K., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Cioslowski, J., Qrtiz, J.V., Baboul, A.G., Stefanov, B.B., Liu, G., Nanayakkara, A., Gonzalez, C., Challacombe, M., Gill, P.M.W., Johnson, B., Chen, W., Wong, M.W., Andres, J.L., Gonzalez, C., Head-Gordon, M., Replogle, E.S., Pople, J.A., GAUSSIAN 98, Revision A.7 (Gaussian Inc., Pittsburg, PA, 1998)Google Scholar
Takusagawa, F., Koetzle, T.F., Kou, W.W.H., Parthasarathy, R., Acta Crystallogr. Sect. B: Struct. Crystallogr. Cryst. Chem. 37, 1591 (1981)CrossRef
Kleinman, D.A., Phys. Rev. 126, 1977 (1962)CrossRef
Socrates, G., Infrared and Raman Characteristic Group Frequencies, 3rd edn. (Wiley, New York, 2001)Google Scholar
Krishnakumar, V., Mathammal, R., Muthunatesan, S., Spectrochim. Acta A 70, 210 (2008)CrossRef
James, C., Ravikumar, C., Sundius, T., Krishnakumar, V., Kesavamoorthy, R., Jayakumar, V.S., Hubert Joe, I., Vib. Spectrosc. 47, 10 (2008)CrossRef
Sirohi, S., Sharma, T.P., Opt. Mater. 13, 267 (1999)CrossRef
Vijayan, N., Bhagavannarayana, G., Budakoti, G.C., Kumar, B., Upadhyaya, V., Das, S., Mater. Lett. 62, 1252 (2008)CrossRef
Park, G., Jung, W.S., Ra, C.S., Bull. Korean Chem. Soc. 25, 1427 (2004)
Abdel-Halim, H., Cowan, D.O., Robinson, D.W., Wiygul, F.M., Kimura, M., J. Phys. Chem. 90, 5654 (1986)CrossRef
Sheikshoaie, I., Saeid-Nia, S., Monadi, N., Khabazzadeh, H., J. Appl. Sci. 7, 145 (2007)
Yoon, Z.S., Cho, D.-G., Kim, K.S., Sessler, J.L., Kim, D.H., J. Am. Chem. Soc. 130, 6930 (2008)CrossRef
Bena Jothy, V., Jayakumar, T., Jayakumar, V.S., Udayalekshmi, K., Ramamoorthy, K., Hubert Joe, I., J. Raman Spectrosc. 38, 1148 (2007)CrossRef
van Gisbergen, S.J.A., Snijders, J.G., Baerends, E.J., J. Chem. Phys. 109, 10657 (1998)CrossRef
Jaszunski, M., Jorgensen, P., Koch, H., Agren, H., Helgaker, T., J. Chem. Phys. 98, 7229 (1993)CrossRef
Silva, J.L.F., Canuto, S., J. Mol. Struct. Theochem 394, 181 (1994)CrossRef
Mendes, P.J., Palace Carvalho, A.J., Prates Ramalho, J.P., J. Mol. Struct. Theochem 900, 110 (2009)CrossRef