Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-26T18:28:33.026Z Has data issue: false hasContentIssue false

Fast-passage microwave molecular spectroscopy with frequency sweeping

Published online by Cambridge University Press:  17 February 2004

V. V. Khodos
Affiliation:
Institute for Physics of Microstructures, Russian Academy of Sciences, GSP-105, Nizhny Novgorod 603600, Russia
D. A. Ryndyk*
Affiliation:
Institute for Theoretical Physics, University of Regensburg, 93040 Regensburg, Germany
V. L. Vaks
Affiliation:
Institute for Physics of Microstructures, Russian Academy of Sciences, GSP-105, Nizhny Novgorod 603600, Russia
Get access

Abstract

We propose a new method of molecular microwave spectroscopy together with analysis ofresonance line shapes, based on the fast passage effect. The fast passage effect isthe excitation of coherent spontaneous radiation of tested molecules using a fastfrequency sweep over the absorption line. We show that the line shape can bereconstructed from the received detector signal with the use of Hilbert and Fouriertransformations. We find that sensitivity of a fast passage spectrometer is higherthan that of an ordinary pulsed Fourier-transform spectrometer. The proposed method isa useful tool for fast analysis of gas mixtures.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Akhsakhalyan, A.D., Gorshenkov, A.V., Pripolsin, S.I., Vaks, V.L., Schaff, W., Volf, F., SPIE Conf. Proc. 2250, 50 (1994)
R.D. Suenran, A.R. Walker, F.J. Lovas, Proceedings of the 51st International Symposium on Molecular Spectroscopy, Ohio, (1996), p. MF04
V.L. Vaks, A.A. Gudkov, C.J. Pripolsin, F. Neubert, Proceedings of the 5th Exibition and Conference for Industrial Measurements, 17-19 September 1991, Wiesbaden, Germany, (1991), p. 408
A.B. Brailovsky, V.V. Khodos, V.L. Vaks, Proceedings of Eur. Conf. for Ph.D. Students, Montpellier, France, (1994), p. CP8
Cazoli, G., Dore, L., J. Mol. Spectrosc. 141, 49 (1990) CrossRef
Vaks, V.L., Khodos, V.V., Spivak, E.V., Rev. Sci. Instrum. 70, 3447 (1999) CrossRef
Dreizler, H., Mol. Phys. 59, 1 (1986) CrossRef
Albert, S., Petkie, D.T., Bettens, R.P.A., Belov, S.P., De Lucia, F.C., Anal. Chem. News and Features 70, 719 (1998)
S.P. Belov, V.V. Khodos, V.L. Vaks, F.C. De Lucia, Proceedings of COE Conference “High Resolution Spectroscopy", 17–19 March, Okazani, Japan (1999)
Rothenberg, J.E., Grischkowsky, D., J. Opt. Soc. Am. B 2, 626 (1985); 3, 1235 (1986) CrossRef
Zamith, S., Degert, J., Stock, S., de Beauvoir, B., Blanchet, V., Bouchene, M.A., Girard, B., Phys. Rev. Lett. 87, 033001 (2001) CrossRef
R.G. Brewer, R.L. Shoemaker, Phys. Rev. Lett. 27, 631 (1971)
Macke, B., Glorieux, P., Chem. Phys. Lett. 14, 85 (1972) CrossRef
McGurk, J.C., Schmaltz, T.G., Flygare, W.H., J. Chem. Phys. 60, 4181 (1974) CrossRef
Vaks, V.L., Gershtein, L.I., Izv. Vuz.: Radiofiz. 27, 1344 (1984)
C.E. Cook, M. Bernfield, Radar Signals. An Introduction to Theory and Applications (Academic Press, N.Y.-London, 1967)