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Direct enhancement of any solution NMR signal using the distant dipolar fields createdby highly polarized and concentrated nuclear spin systems

Published online by Cambridge University Press:  06 October 2006

H. Desvaux*
Affiliation:
Laboratoire Structure et Dynamique par Résonance Magnétique, Service de Chimie Moléculaire, URA CEA/CNRS 331 Claude Fréjacques, CEA/Saclay, 91191 Gif-sur-Yvette, France
D. J. Marion
Affiliation:
Laboratoire Structure et Dynamique par Résonance Magnétique, Service de Chimie Moléculaire, URA CEA/CNRS 331 Claude Fréjacques, CEA/Saclay, 91191 Gif-sur-Yvette, France
G. Huber
Affiliation:
Laboratoire Structure et Dynamique par Résonance Magnétique, Service de Chimie Moléculaire, URA CEA/CNRS 331 Claude Fréjacques, CEA/Saclay, 91191 Gif-sur-Yvette, France
L. Dubois
Affiliation:
Laboratoire Structure et Dynamique par Résonance Magnétique, Service de Chimie Moléculaire, URA CEA/CNRS 331 Claude Fréjacques, CEA/Saclay, 91191 Gif-sur-Yvette, France
P. Berthault
Affiliation:
Laboratoire Structure et Dynamique par Résonance Magnétique, Service de Chimie Moléculaire, URA CEA/CNRS 331 Claude Fréjacques, CEA/Saclay, 91191 Gif-sur-Yvette, France
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Abstract

Peculiar nuclear spin systems can be polarized at a level ofthousands times the value obtained at thermal equilibrium, for instance byoptical pumping. When concentrated, these systems create a sizeable averagedipolar field which is experienced by any nuclear spin. We propose to use thesedistant dipolar fields for performing a polarization transfer in theHartmann-Hahn conditions. We report the maximum enhancement value calculatedusing the spin temperature approach and first theoretical insights on thepolarization transfer rate. Using, as an example, dissolved laser-polarizedxenon, we show that by spin-locking both xenon spins and a proton spin of asolute, the polarization of the latter is enhanced. This is obtained withoutthe existence of chemical interaction between the two entities and withcharacteristic rising time not directly correlated to the protonself-relaxation time. By its generality and its non-local feature, thisapproach could make possible nuclear magnetic resonance spectroscopy on verydilute systems.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2006

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