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Dielectric measurements in large frequency and temperature ranges of an aromatic polymer

Published online by Cambridge University Press:  26 November 2009

S. Diaham ,
M.-L. Locatelli ,
T. Lebey  and
S. Dinculescu
S. Diaham*
Affiliation:
Université de Toulouse, UPS-INPT, LAPLACE (Laboratoire Plasma et Conversion d'Énergie), 118 route de Narbonne, 31062 Toulouse Cedex 9, France CNRS, LAPLACE, 31062 Toulouse, France
M.-L. Locatelli
Affiliation:
Université de Toulouse, UPS-INPT, LAPLACE (Laboratoire Plasma et Conversion d'Énergie), 118 route de Narbonne, 31062 Toulouse Cedex 9, France CNRS, LAPLACE, 31062 Toulouse, France
T. Lebey
Affiliation:
Université de Toulouse, UPS-INPT, LAPLACE (Laboratoire Plasma et Conversion d'Énergie), 118 route de Narbonne, 31062 Toulouse Cedex 9, France CNRS, LAPLACE, 31062 Toulouse, France
S. Dinculescu
Affiliation:
Université de Toulouse, UPS-INPT, LAPLACE (Laboratoire Plasma et Conversion d'Énergie), 118 route de Narbonne, 31062 Toulouse Cedex 9, France CNRS, LAPLACE, 31062 Toulouse, France
*
[email protected]

Abstract

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The characterization of the BPDA/PDA polyimide (PI) at high temperature up to 400 °C, thanks to dielectric relaxation spectroscopy (DRS) in the 10-1 Hz to 106 Hz frequency range, allows the determination of the dc electrical conductivity (σdc). In such a high temperature range, the dielectric spectra are modified by the extrinsic electrode polarization phenomenon (EP) response. A model is proposed which coupled to the DRS results allows evidencing and quantifying the effect of the EP. The proposed method gives a simple way to determine the intrinsic σdc values from the effective ac dielectric response, improving the accuracy and reducing the duration of measurement. For BPDA/PDA PI, the resulting σdc values range from 4 × 10-11 to 8 × 10-6 Ω-1 m-1 for temperatures between 200 and 400 °C, with an activation energy of the conduction phenomenon of 0.55 eV.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 49 , Issue 1: 17th International Colloquium on Plasma Processes (CIP 2009) , January 2010 , 10401
Copyright
© EDP Sciences, 2009

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