Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-25T17:11:25.225Z Has data issue: false hasContentIssue false
  • English
  • Français

Ultrasonic attenuation spectroscopy and light scattering study of the ageing of very fine emulsions

Published online by Cambridge University Press:  15 February 1999

N. Herrmann  and
P. Lemaréchal
N. Herrmann
Affiliation:
Biopolymers and Colloids Research Laboratory, Department of Food Science, University of Massachusetts, Amherst, MA 01003, USA
P. Lemaréchal
Affiliation:
Laboratoire de Dynamique des Fluides Complexes, Université Louis Pasteur, 4 rue Blaise Pascal, 67000 Strasbourg, France
Get access

Abstract

Very fine, 10% vol/vol, n-hexadecane and n-octadecane oil-in-water emulsions, stabilized by sodium dodecyl sulfate, have been prepared. Due to the very small size of the oil droplets, these emulsions are susceptible to undergo Ostwald ripening and/or coalescence. The maturation of the emulsions was studied over several months by three different techniques: ultrasonic attenuation spectroscopy, static light scattering and dynamic light scattering. Ultrasonic spectroscopy measurements between 0.5 and 10 MHz appeared as the most convenient technique for monitoring the changes in the size of such droplets. Moreover, the correlation of the results from the three different techniques allows a complete determination of the particle size and polydispersity during the ageing.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 5 , Issue 2 , February 1999 , pp. 127 - 134
Copyright
© EDP Sciences, 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

M.J.W. Povey, Ultrasonic techniques for fluids characterisation (Academic Press, 1997).
Holmes, A.K., Challis, R.E., Wedlock, D.J., J. Colloid Interface Sci. 68, 339 (1994). CrossRef
Dukhin, A.S., Goetz, P., Langmuir 12, 4987 (1996). CrossRef
Kaatze, U., Trachimov, C., Pottel, R., Brai, M., Ann. Phys. 5, 13 (1996).
McClements, D.J., J. Acoust. Soc. Am. 91, 849 (1992). CrossRef
Schroder, A., Raphael, E., Eur. Phys. Lett. 17, 565 (1992). CrossRef
Herrmann, N., Boltenhagen, P., Lemaréchal, P., J. Phys. II France 6, 1389 (1996). CrossRef
Hemar, Y., Herrmann, N., Lemaréchal, P., Hocquart, R., Lequeux, F., J. Phys. II France 7, 637 (1997). CrossRef
Æ. Nesse, K.-E. Fræysa, IEEE Utrasonic Sympos. Proc. 1, 499 (1996).
Aurenty, P., Schroder, A., Gandini, A., Langmuir 11, 4712 (1995). CrossRef
Dickinson, E., McClements, D.J., Povey, M.J.W., J. Coll. Interface Sci. 142, 103 (1991). CrossRef
Dickinson, E., Ma, J., Povey, M.J.W., J. Chem. Soc. Faraday Trans. 92, 1213 (1996). CrossRef
McClements, D.J., J. Colloid. Interf. Sci. 142, 103 (1991).
N. Herrmann, Y. Hemar, P. Lemaréchal, D.J. McClements (submitted).
McClements, D.J., Coll. Surf. A: Phys. Ing. Asp. 90, 25 (1994). CrossRef
Basaran, T.K., Demetriades, K., McClements, D.J., Coll. Surf. A: Phys. Ing. Asp. 136, 169 (1998). CrossRef
Epstein, P.S., Carhart, R.R., J. Acoust. Soc. Am. 25, 553 (1953). CrossRef
Waterman, P.C., Truell, R., J. Acoust. Soc. Am. 2, 512 (1961).
Allegra, J.R., Hawley, S.A., J. Acoust. Soc. Am. 51, 1545 (1972). CrossRef
Lloyd, P., Berry, M.V., Proc. Phys. Soc. 91, 678 (1967). CrossRef
Ma, Y., Varadan, V.K., Varadan, V.V., J. Acoust. Soc. Am. 87, 2779 (1990). CrossRef
N. Herrmann, Ph.D. thesis, University Louis Pasteur, Strasbourg, France, 1997.
Eggers, F., Funck, Th., Rev. Sci. Instrum. 44, 969 (1973). CrossRef
Pusey, P.N., van Megen, W., J. Chem. Phys. 80, 3513 (1984). CrossRef
McClements, D.J., Povey, M.J.W., J. Phys. D: Appl. Phys. 22, 38 (1989). CrossRef
H.Z. Cummins, E.R. Pike, Photon correlation and light beating spectroscopy (Plenum, New York, 1974).
Kabalnov, A.S., Makarov, K.N., Pertzov, A.V., Schukin, E.D., J. Coll. Interf. Sci. 138, 98 (1990). CrossRef
Voorhees, P.W., J. Stat. Phys. 38, 231 (1985). CrossRef