Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-03T01:36:41.183Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of highly oriented gold thin films by a UV-irradiation route

Published online by Cambridge University Press:  30 August 2004

K. Mallick ,
M. J. Witcomb  and
M. S. Scurrell
K. Mallick
Affiliation:
Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, WITS 2050, South Africa
M. J. Witcomb
Affiliation:
Electron Microscope Unit, University of the Witwatersrand, Private Bag 3, WITS 2050, South Africa
M. S. Scurrell*
Affiliation:
Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, WITS 2050, South Africa
*
[email protected]
Get access

Abstract

A synthetic route is presented for the preparation of a gold film in the presence of UV-radiation. Methoxypolyethylene glycol, a water-soluble polymer, was used as the reducing agent of gold ions in the presence of an ultra-violet source, and gold nanoparticles resulted. During stirring, a centrifugal force is generated at the center of the solution (at the point where the meniscus is at its lowest level with respect to the vertical orthogonal). At this point, the nanoparticles coalesce and form a self-assembly of smaller subunits that ultimately forms a film like network.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 29 , Issue 1 , January 2005 , pp. 45 - 49
Copyright
© EDP Sciences, 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ohara, P.C., Leff, D.V., Heath, J.R., Gelbart, W.M., Phys. Rev. Lett. 75, 3466 (1995) CrossRef
Murray, C.B., Kagan, C.R., Bawendi, M.G., Science 270, 1335 (1995) CrossRef
Cusack, L., Rizza, R., Gorelov, A., Fitzmaurice, D., Ang. Chem., Intl. Ed. Engl. 36, 848 (1997) CrossRef
Colvin, V.L., Schlamp, M.C., Alivisatos, A.P., Nature 370, 354 (1994) CrossRef
Andres, R.P., Bein, T., Derogi, M., Feng, S., Henderson, J.I., Kubiak, C.P., Mahoney, W., Osifchin, R.G., Reifenberger, R., Science 272, 1323 (1996) CrossRef
Zheng, J.W., Zhu, Z.H., Chen, H.F., Liu, Z.F., Langmuir 16, 4409 (2000) CrossRef
Cao, L.X., Huo, L.H., Ping, G.C., Wang, D.M., Zeng, G.F., Xi, S.Q., Thin Solid Films 374, 258 (1999) CrossRef
Jin, R., Cao, Y.-W., Mirkin, C.A., Kelly, K.L., Schatz, G.C., Zheng, J.G., Science 249, 1901 (2001) CrossRef
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadanavich, A., Alivisatos, A.P., Nature 404, 59 (2000)
M. El-Sayed, Acc. Chem. Res. 34, 257 (2001)
Belloni, J., Mostafavi, M., Marignier, J.L., Amblard, J., J. Imaging Sci. 35, 68 (1991)
Ware, M.J., J. Photogr. Sci. 42, 153 (1994)
G. Schmid, Clusters and Colloids: From Theory to Application (VCH, Weinheim, 1994)
Slot, J.W., Geuze, H.J., J. Cell Biol. 38, 87 (1983)
Carotenuto, G., Pepe, G.P., Nicolais, L., Eur. Phys. J. B 16, 11 (2000) CrossRef
Carotenuto, G., Appl. Organomet. Chem. 15, 344 (2001) CrossRef
Gehr, R.J., Boyd, R.W., Chem. Mater. 8, 1807 (1996) CrossRef
Fornasiero, D., Grieser, F., J. Colloid Interface Sci. 141, 168 (1991) CrossRef
Matejka, P., Vlckova, B., Vohlidal, J., Pancoska, P., Baumrunk, V., J. Phys. Chem. 96, 1361 (1992) CrossRef
Mamedov, A.A., Belov, A., Giersig, M., Mamedova, N.N., Kotov, N.A., J. Am. Chem. Soc. 123, 7738 (2001) CrossRef
Ramos, A.M., Rispens, M.T., van Duran, J.K.T., Hummelen, J.C., Janssen, R.A., J. Am. Chem. Soc. 123, 6714 (2001) CrossRef
Abruna, H.D., Denisevich, P., Umana, M., Meyer, T.J., Murray, R.W., J. Am. Chem. Soc. 103, 1 (1981) CrossRef
Kovtyukhova, N.I., Ollivier, P.J., Chizhik, S., Dubravin, A., Buzaneva, E., Gorchinskiy, A.D., Marchenko, A., Smirnova, N., Thin Solid Films 337, 166 (1999) CrossRef
Kovtyukhova, N.I., Gorchinskiy, A.D., Waraksa, C.C., Mater. Sci. Eng. 70, 424 (2000) CrossRef
Cassagneau, T., Fendler, J.H., Mallouk, T.E., Langmuir 16, 241 (2000) CrossRef
Kovtyukhova, N.I., Martin, B.R., Mbindyo, J.K.N., Smith, P.A., Razavi, B., Mayer, T.S., Mallouk, T.E., J. Phys. Chem. B 105, 8762 (2001) CrossRef
Gittins, D.I., Caruso, F., J. Phys. Chem. B 105, 6846 (2001) CrossRef
Boal, A., Ilhan, F., DeRouchey, J., Russell, T., Rotello, V., Nature 404, 746 (2000)
Markinakos, S.M., Schlutz, D.A., Feldheim, D.L., Adv. Mater. 11, 34 (1999)
Kyunghee, C.Y., Mendieta, V.S., Castanares, R.L., Meldrum, F.C., Wu, C., Fendler, J.H., J. Phys. Chem. 99, 9869 (1995)
Fendler, J.H., Chem. Mater. 13, 3196 (2001) CrossRef
Yamada, Y., Van Drent, W.P., Abarra, E.N., Suzuki, T.J., Appl. Phys. A 83, 6527 (1998) CrossRef
Ishida, A., Miyazaki, S., J. Eng. Mater. Technol. 121, 2 (1999) CrossRef
Geyer, U., Von Hulsen, U., Thiyagarajan, P., Appl. Phys. Lett. 72, 1691 (1997) CrossRef
Kahng, S.-J., Chio, Y.J., Park, J.-Y., Kuk, Y., Appl. Phys. Lett. 74, 1087 (1999) CrossRef
Vernon, S.M., Appl. Phys. Lett. 74, 1382 (1999)
Iwamoto, N., Chujo, H., Akao, N., Sugimoto, K., J. Jap. Inst. Mat. 62, 877 (1998) CrossRef
Xhong, S., Wang, J., Liu, H.K., Dou, S.X., Skyllas-Kazacos, M., J. Appl. Electrochem. 29, 1 (1999)
Yongqiang, Y., Appl. Surf. Sci. 140, 19 (1998)
S.M. Rossnagel, J. Vac. Sci. Technol. B 16, 2585 (1998)
Oskam, G., Long, J.G., Natarajan, A., Searson, P.C., J. Phys. D: Appl. Phys. 31, 1927 (1998) CrossRef
Boyd, E.P., Ketchum, D.R., Deng, H., Shore, S.G., Chem. Mater. 9, 1154 (1997) CrossRef
Jervis, T.R., J. Appl. Phys. 58, 1400 (1985) CrossRef
Geohegan, D.B., Edgen, J.G., Appl. Phys. Lett. 45, 1145 (1984)
George, P.M., Beauchamp, J.L., Thin Solid Films 67, L25 (1980) CrossRef
Brown, K.R., Andrew, L.L., Fox, A.P., Reiss, B.D., Natan, M.J., Chem. Mater. 12, 314 (2000) CrossRef
Hussain, I., Brust, M., Popworth, A.J., Cooper, A.I., Langmuir 19, 4831 (2003) CrossRef
Leff, D.V., Brandt, L., Heath, J.R., Langmuir 12, 4723 (1996) CrossRef
Swami, A., Kumar, A., Selvakannan, P.R., Mandal, S., Pasricha, R., Sastry, M., Chem. Mater. 15, 17 (2003) CrossRef
B. Cercek, M. Ebert, A.J. Swallow, J. Chem. Soc. A 612 (1966)
Y. Tabata, Y. Ito, S. Tagawa, Handbook of Radiation Chemistry (CRC Press, Boca Raton, 1991)
J. Belloni, M. Mostafavi, in Radiation-Induced Metal Clusters Nucleation Mechanism and Chemistry, Metal Clusters in Chemistry, edited by P. Braunstein, L.A. Oro, P.R. Raithby (J. Wiley, VCH, 1999), Vol. III
K. Mallick, M.J. Witcomb, M.S. Scurrell, Appl. Phys. A (in press)