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Synthesis and characterization of Pb(Yb1/2Nb1/2)O3-based high-Curie temperature piezoelectric ceramics

Published online by Cambridge University Press:  10 June 2014

Jianfeng Zheng
Affiliation:
School of Information Science and Engineering, School of Materials Science and Engineering, Changzhou University, Changzhou, Jiangsu 213164, P.R. China
Zhihui Chen
Affiliation:
School of Information Science and Engineering, School of Materials Science and Engineering, Changzhou University, Changzhou, Jiangsu 213164, P.R. China
Bijun Fang*
Affiliation:
School of Information Science and Engineering, School of Materials Science and Engineering, Changzhou University, Changzhou, Jiangsu 213164, P.R. China
Jianning Ding*
Affiliation:
School of Information Science and Engineering, School of Materials Science and Engineering, Changzhou University, Changzhou, Jiangsu 213164, P.R. China School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, P.R. China
Xiangyong Zhao
Affiliation:
Key Laboratory of Inorganic Function Material and Device, Chinese Academy of Sciences, Shanghai 201800, P.R. China
Haiqing Xu
Affiliation:
Key Laboratory of Inorganic Function Material and Device, Chinese Academy of Sciences, Shanghai 201800, P.R. China
Haosu Luo
Affiliation:
Key Laboratory of Inorganic Function Material and Device, Chinese Academy of Sciences, Shanghai 201800, P.R. China
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Abstract

xPb(Yb1/2Nb1/2)O3-(1 − x)Pb(Zr0.36Ti0.64)O3 (xPYN-(1 − x)PZT) piezoelectric ceramics were prepared by the conventional ceramic processing via a B-site oxide mixing route. The synthesized xPYN-(1 − x)PZT ceramics exhibit majority of perovskite structure with slight content of impurity, which exhibit typical tetragonal structure with slight orthorhombic distortion depending on compositions. All the xPYN-(1 − x)PZT ceramics exhibit high Curie temperature (TC/Tm), higher than 380 °C, and their dielectric behavior above TC/Tm can be fitted well by the Curie-Weiss law. The xPYN-(1 − x)PZT ceramics exhibit large resistivity, and excellent ferroelectric and piezoelectric properties, which provide promising for the high-power and high-temperature piezoelectric applications. However, electric energy density of the xPYN-(1 − x)PZT ceramics is small due to their nearly rectangular shape of polarization-electric field (P-E) hysteresis loop and early electric displacement saturation, which is not suitable for high energy and power storage applications.

Type
Research Article
Copyright
© EDP Sciences, 2014

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