Hostname: page-component-cd9895bd7-fscjk Total loading time: 0 Render date: 2024-12-25T17:14:13.923Z Has data issue: false hasContentIssue false

Solid polymer fuel cell synthesis by low pressure plasmas:a short review

Published online by Cambridge University Press:  04 May 2006

P. Brault*
Affiliation:
Groupe de Recherches sur l'Énergétique des Milieux Ionisés, UMR 6606, CNRS-Université d'Orléans, BP 6744, 45067 Orléans Cedex 2, France
S. Roualdès
Affiliation:
Institut Européen des Membranes, UMR 5635, CNRS-Université de Montpellier II - CC 47, place Eugène Bataillon, 34095 Montpellier Cedex 5, France
A. Caillard
Affiliation:
Groupe de Recherches sur l'Énergétique des Milieux Ionisés, UMR 6606, CNRS-Université d'Orléans, BP 6744, 45067 Orléans Cedex 2, France
A.-L. Thomann
Affiliation:
Groupe de Recherches sur l'Énergétique des Milieux Ionisés, UMR 6606, CNRS-Université d'Orléans, BP 6744, 45067 Orléans Cedex 2, France
J. Mathias
Affiliation:
Groupe de Recherches sur l'Énergétique des Milieux Ionisés, UMR 6606, CNRS-Université d'Orléans, BP 6744, 45067 Orléans Cedex 2, France
J. Durand
Affiliation:
Institut Européen des Membranes, UMR 5635, CNRS-Université de Montpellier II - CC 47, place Eugène Bataillon, 34095 Montpellier Cedex 5, France
C. Coutanceau
Affiliation:
Laboratoire de Catalyse en Chimie Organique, UMR 6503, CNRS-Université de Poitiers, 40 avenue du Recteur Pineau, 86022 Poitiers Cedex, France
J.-M. Léger
Affiliation:
Laboratoire de Catalyse en Chimie Organique, UMR 6503, CNRS-Université de Poitiers, 40 avenue du Recteur Pineau, 86022 Poitiers Cedex, France
C. Charles
Affiliation:
Plasma Research Laboratory, Research School of Physical Science and Engineering Australian National University, Canberra ACT 0200, Australia
R. Boswell
Affiliation:
Plasma Research Laboratory, Research School of Physical Science and Engineering Australian National University, Canberra ACT 0200, Australia
Get access

Abstract

In this review, we report on the use of low pressure plasmas for elaboratingmaterials at the heart of solid polymer fuel cells (SPFC), especially electrodes and themembrane electrolyte. Electrodes are formed using plasma sputtering techniques while theion conducting membranes are built up using plasma polymerization. Fuel cell performance willbe improved by these approaches. The electrode catalyst profile is optimized whilemembrane working temperature is increased and methanol crossover is lowered compared to conventional PEM fuel cells.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Fuel Cell Handbook 6th Edition (DOE/NETL-2002/1179, US Dept Of Energy, 2002)
Gasteiger, H.A., Panels, J.E, Yan, S.G., J. Power Sources 127, 162 (2004) CrossRef
Litster, S., McLean, G., J. Power Sources 130, 61 (2004) and references therein CrossRef
Yang, T.H., Yoon, Y.G., Kim, C.S., Kwak, S.H., Yoon, K.H., J. Power Sources 106, 328 (2002) CrossRef
Haug, A.T., White, R.E., Weidner, J.W., Huang, W., Shi, S., Stoner, T., Rana, N., J. Electrochem. Soc. 149, A280 (2002) CrossRef
Haug, A.T., White, R.E., Weidner, J.W., Huang, W., J. Electrochem. Soc. 149, A862 (2002) CrossRef
Haug, A.T., White, R.E., Weidner, J.W., Huang, W., Shi, S., Rana, N., Grunow, S., Stoner, T., J. Electrochem. Soc. 149, A868 (2002) CrossRef
Cha, S.Y., Lee, W.M., J. Electrochem. Soc. 146, 4055 (1999) CrossRef
Hirano, S., Kim, J., Srinivasan, S., Electrochim. Acta 42, 1587 (1997) CrossRef
Mukerjee, S., Srinivasan, S., Appleby, A.J., Electrochim. Acta 38, 1661 (1993) CrossRef
O'Hayre, R., Lee, S.J., Cha, S.W., Prinz, F.B., J. Power Sources 109, 483 (2002) CrossRef
Chun, Y.-G., Kim, C.-S., Peck, D.-H., Shin, D.-R., J. Power Sources 71, 174 (1998) CrossRef
Mex, L., Müller, J., Membrane Technology 115, 5 (1999) CrossRef
Mex, L., Ponath, N., Müller, J., Fuel Cell Bulletin 39, 9 (2001) CrossRef
Brault, P., Caillard, A., Thomann, A.L., Mathias, J., Charles, C., Boswell, R.W., Escribano, S., Durand, J., Sauvage, T., J. Phys. D 37, 3419 (2004) CrossRef
Caillard, A., Brault, P., Mathias, J., Charles, C., Boswell, R.W., Sauvage, T., Surf. Coat. Tech. 200, 391 (2005) CrossRef
Yasuda, H., J. Membrane Sci. 18, 273 (1984) CrossRef
X. Ren, T.A. Zawodzinski, F. Uribe, H. Dai, S. Gottesfeld, Proton Conducting Membrane Fuel Cells I, edited by S. Gottesfeld, G. Halpert, A. Landgrebe (The Electrochemical Society, Pennington, NJ, 1995), p. 284
Inagaki, N., Tasaka, S., Horikawa, Y., J. Polym. Sci. Pol. Chem. 27, 3495 (1989) CrossRef
Inagaki, N., Tasaka, S., Kurita, T., Polym. Bull. 22, 15 (1989) CrossRef
Inagaki, N., Tasaka, S., Chengfei, Z., Polym. Bull. 26, 187 (1991) CrossRef
Z. Ogumi, Y. Uchimoto, K. Yasuda, Z.-I. Takehara, Chem. Lett. 953 (1990)
Ogumi, Z., Uchimoto, Y., Takehara, Z.-I., J. Electrochem. Soc. 137, 3319 (1990) CrossRef
Uchimoto, Y., Yasuda, K., Ogumi, Z., Takehara, Z.-I., Tasaka, A., Imahigashi, T., Ber. Bunsenges. Phys. Chem. 97, 625 (1993) CrossRef
Uchimoto, Y., Endo, E., Yasuda, K., Yamasaki, Y., Takehara, Z.-I., Ogumi, Z., Kitao, O., J. Electrochem. Soc. 147, 111 (2000) CrossRef
Yasuda, K., Uchimoto, Y., Ogumi, Z., Takehara, Z.-I., J. Electrochem. Soc. 141, 2350 (1994) CrossRef
Yasuda, K., Uchimoto, Y., Ogumi, Z., Takehara, Z.-I., Ber. Bunsenges. Phys. Chem. 98, 631 (1994) CrossRef
Brumlik, C.J., Parthasarathy, A., Chen, W.-J., Martin, C.R., J. Electrochem. Soc. 141, 2273 (1994) CrossRef
Yoshimura, K., Minaguchi, T., Nakano, H., Tatsuta, T., Tsuji, O., Toyozawa, K., Abe, T., Ogumi, Z., J. Photopolym. Sci. Techn. 13, 13 (2000) CrossRef
Finsterwalder, F., Hambitzer, G., J. Membr. Sci. 185, 105 (2001) CrossRef
Mahdjoub, H., Roualdès, S., Sistat, P., Pradeilles, N., Durand, J., Pourcelly, G., Fuel Cells 5, 277 (2005) CrossRef
Zawodzinski Jr, T.A.., C. Derouin, S. Rodzinski, R.J. Sherman, V.T. Smith, T.E. Springer, S. Gottesfeld, J. Electrochem. Soc. 140, 1041 (1993) CrossRef
Zawodzinski Jr, T.A.., T.E. Springer, F. Uribe, S. Gottesfeld, Solid State Ionics 60, 199 (1993) CrossRef
Sone, Y., Ekdunge, P., Simonsson, D., J. Electrochem. Soc. 143, 1254 (1996) CrossRef