Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-25T17:04:14.510Z Has data issue: false hasContentIssue false
  • English
  • Français

Properties of Pb0.71K0.145Sm0.145Nb2O6 analysed within piezoelectric, dielectric, impedance, electric modulusand conductivity

Published online by Cambridge University Press:  09 April 2008

K. Sambasiva Rao ,
D. Madhava Prasad ,
P. Murali Krishna  and
J.-H. Lee
K. Sambasiva Rao*
Affiliation:
Centre for Piezoelectric Transducer Materials, Department of Physics, Andhra University, Visakhapatnam – 530 003, India
D. Madhava Prasad
Affiliation:
Centre for Piezoelectric Transducer Materials, Department of Physics, Andhra University, Visakhapatnam – 530 003, India
P. Murali Krishna
Affiliation:
Centre for Piezoelectric Transducer Materials, Department of Physics, Andhra University, Visakhapatnam – 530 003, India
J.-H. Lee
Affiliation:
Department of Inorganic Materials Engineering, Kyungpook National University, Daegu, 702701, Korea
*
[email protected]
Get access

Abstract

Orthorhombic tungsten bronze Pb $_{1-x}$ K $_{2x-3y}$ Smy Nb2O6 (where x = 0.29 and y = 0.145) ceramic has been synthesized by the conventional sintering technique. Preliminary X-ray diffractogram analysis of crystal structure showed that a single phase compound has been formed with orthorhombic system. Frequency and temperature dependences of impedance, modulus, conductivity and dielectric permittivity have been performed in the frequency and temperature range 45 Hz–5 MHz and 35–595 °C respectively. Impedance spectroscopy study showed the presence of both bulk and grain boundary effects in the materials. The complex impedance spectra above 440 °C have been fitted by the superposition of two Cole-Cole types of relaxations. The ac conductivity spectrum obeyed the Jonscher's power law. Modulus analysis indicated the possibility of hopping mechanism for electrical process in the system.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 41 , Issue 3 , March 2008 , pp. 229 - 236
Copyright
© EDP Sciences, 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

M.E. Lines, A.M. Glass, Principles and applications of ferroelectrics and related materials. Ed. Clarendon Press, Oxford, p. 281 (1977)
Elaatmani, M., Zegzouti, A., Ravez, J., Hagenmuller, P., Rev. Chimie Minérale t. 23, 290 (1986)
Ph. Sciau, G. Calvarin, J. Ravez, Acta Cryst. B 55, 429 (1999) CrossRef
Z.G. Lu, J-P. Bonnet, J. Ravez, P. Hagenmuller, Eur. J. Solid State Inorg. Chem., t. 30, 817 (1993)
Hodge, I.M., Ingram, M.D., West, A.R., J. Electronal. Chem. 74, 125 (1976) CrossRef
Irvine, J.T.S., Sinclair, D.C., West, A.R., Adv. Mater. 2, 132 (1990) CrossRef
Bauerle, J.E., Hriko, J., J. Phys. Chem. Solids 30, 565 (1969) CrossRef
Bauerle, J.E., J. Phys. Chem. Solids 30, 2657 (1969) CrossRef
M. Kleitz, J.H. Kennedy, “Resolution of Multicomponent Impedance Diagrams”; in Fast Ion Transport in Solids, edited by Vashishta, Mundy, Shenoy (Elsevier, London, 1979) pp. 185–88
P.H. Bottelberghs, Low-Frequency Measurements on Solid Electrolytes and Their Interpretation, in Solid Electrolytes, General Principles, Materials and Applications, edited by P. Hagenmuller, W. van Goul (Academic Press, New York, 1978) pp. 145–72
Kawamura, J., Sato, R., Mishina, S., Shimoji, M., Solid State Ionics 25, 155 (1987) CrossRef
Denk, I., Claus, J., Maier, J., J. Electrochem. Soc. 144, 3526 (1997) CrossRef
Hirose, N., West, A.R., J. Am. Ceram. Soc. 79, 1633 (1996) CrossRef
Huanosta, A., West, A.R., J. Appl. Phys. 61, 5386 (1987) CrossRef
Sinclair, D.C., West, A.R., Phys. Rev. B 39, 13486 (1989)
Lanfredi, S., Rodrigues, A.C.M., J. Appl. Phys. 86, 2215 (1999) CrossRef
Sen, S., Choudhary, R.N.P., Tarafdar, O., Pramanik, P., J. Appl. Phys. 99, 124114 (2006) CrossRef
Park, J.H., Bae, J.S., Choi, B.C., Jeong, J.H., J. Phys. D: Appl. Phys. 40, 579 (2007) CrossRef
Rao, K.S., Murali Krishna, P., Swarna La, T.tha. D. Madhava Prasad, Mat. Sci. Eng. B 131, 127 (2006) CrossRef
Rao, K.S., Murali Krishna, P.,. D. Madhava Prasad, J.H. Lee, IJMP B 21, 1 (2007)
Rao, K.S., Madhava Prasad, D., Murali Krishna, P., Tilak, B., Varadarajulu, K.Ch., Mat. Sci. Eng. B 133, 141 (2006)
Yamada, T., J. Appl. Phys. 46, 2894 (1975) CrossRef
O'Connell, R.M., J. Appl. Phys. 46, 530 (1980)
Giess, E.A., Scott, B.A., Burns, G., O'Kane, D.F., Segmuller, A., J. Amer. Cera. Soc. 52, 276 (1969) CrossRef
Ravez, J., Elouadi, B., Mat. Res. Bull. 19, 1249 (1975) CrossRef
Thoret, J., Ravaz, J., Revue de Chimie Minerale, T 24, 288 (1987)
Zegzout, A., Elaatmani, M., Sil. Ind. 62, 149 (1997)
Yamada, T., Appl. Phys. Lett. 23, 213 (1973) CrossRef
Yamauchi, H., Appl. Phys. Lett. 32, 599 (1978) CrossRef
Nakano, J., Yamada, T., J. Appl. Phys. 46, 2361 (1975) CrossRef
K. Sambasiva Rao, D. Madhava Prasad, P. Murali Krishna, J.H. Lee, communicated to Mat. Sci. Eng. B
Belding, G.H., McLaren, M.G., J. Am. Ceram. Soc. 49, 1025 (1970)
Neurgoanker, R.R., Oliver, J.R., Cory, W.K., Mat. Res. Bull. 18, 735 (1983) CrossRef
SambasivaRao, K., Subramanyam, A.S.V., Murali Mohana Rao, S., Ferroelectrics 109, 215 (1997)
Shrout, T.R., Cross, L.E., Hukin, D.A., Ferroelectrics Lett. 44, 325 (1983) CrossRef
Kim, J.S., Song, T.K., J. Phys. Soc. Jpn 70, 3419 (2001) CrossRef
Saha, S., Sinha, T.P., J. Appl. Phys. 99, 014109 (2006) CrossRef
Ambrus, J.H., Moynihan, C.T., Marcedo, P.B., J. Phys. Chem. 76, 3287 (1972) CrossRef
Macedo, P.B., Moynihan, C.T., Bose, R., Phys. Chem. Glasses 13, 171 (1972)
A.K. Jonscher, Dielectric Relaxation in Solids (Chelsea Dielectrics Press, London, 1983), pp. 63–115
Villegas, M., Caballero, A.C., Fernandez, J.F., Ferrolelectrics 267, 165 (2002) CrossRef
Kim, J.S., Cho, J.A., Song, T.K., Jeong, C.H., Lee, H.S., Ferroelectrics 324, 133 (2005) CrossRef
Dutta, S., Choudhary, R.N.P., Sinha, P.K., Ferroelectrics 330, 75 (2006) CrossRef
N.F. Mott, E.A. Davis, Electronic Progresses in Non-crystalline Solids (Oxford: Clarendon, 1970)
Dyre, J.C., J. Appl. Phys. 64, 2456 (1988) CrossRef
Maass, P., Meyer, M., Bunde, A., Phys. Rev. B 51, 8164 (1995) CrossRef
Morri, K. et al., J. Appl. Phys. 78, 1914 (1995) CrossRef
Venkateswarlu, P., Victor, P., Krupanidhi, S.B., Integrated Ferroelectrics 46, 143 (2002) CrossRef