Hostname: page-component-6bf8c574d5-nvqbz Total loading time: 0 Render date: 2025-03-09T14:37:31.915Z Has data issue: false hasContentIssue false
  • English
  • Français

Influence of tabletting pressure upon internal morphology of a Fe2O3Cr2O3catalyst

Published online by Cambridge University Press:  15 December 2001

P. Rotaru  and
Ş. I. Blejoiu
P. Rotaru*
Affiliation:
University of Craiova, A.I. Cuza 13, 1100 Craiova, Romania
Ş. I. Blejoiu
Affiliation:
University of Craiova, A.I. Cuza 13, 1100 Craiova, Romania
*
[email protected]
Get access

Abstract

A study on the influence of tabletting pressure upon the internal morphology of Fe2O3-Cr2O3 catalytic system shows the behaviour of that system at crystallite level or even below it. On increasing tabletting pressure of catalytic powder, remanent stresses are left in the tablets formed which can be calculated in terms of the remanent strain. The macrostresses are constant and small at tabletting pressures ranging within 108 − 5 × 108 Pa and increase linearly between 6 × 108 and 14 × 108 Pa. The microstresses take measurable values only in samples tabletted at pressures higher than 7 × 108 Pa. Besides the formation of remanent stresses, the increase of tabletting pressure brings about the overall change of porous structure and mechanical resistance of the catalytic system. The remanent stresses that appeared at tabletting result in cracks along some planes which, in most instances, are parallel to the planar faces of tablets. The maximum acceptable tabletting pressure of the catalytic system studied amounts to 5 × 108 Pa.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 16 , Issue 3 , December 2001 , pp. 167 - 173
Copyright
© EDP Sciences, 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Somorjai, G.A., J. Phys. Chem. 94, 1013 (1990). CrossRef
Uemiya, S., Sao, N., Ando, H., Matsuda, T., Kikucki, E., Appl. Catalysis 67, 223 (1991). CrossRef
Lamber, R., Schulz Ekloff, G., Surf. Sci. 258, 107 (1991). CrossRef
Zielinski, J., Appl. Catalysis A 94, 107 (1993). CrossRef
Youssef, N.A., Youssef, A.M., Bull. Soc. Chim. Fr. 128, 864 (1991).
Huang, Y.J., Schwarz, J.A., Appl. Catalysis 30, 225 (1987). CrossRef
E.I. Segal, C. Iditoiu, N. Doca, D. Fatu, Catalysis and catalysts (Facla Publishing House, Timisoara, 1989).
S.A. Stevenson, J.A. Dumesic, R.T.K. Baker, E. Ruckenstein, Metal - support interactions in catalysis, sintering and redispersion (Van Nostrad Reinhold Company, New York, 1987).
Uhara, I., Kishimoto, S., Hikino, T., Kageyama, Y., Haonada, H., Nuonata, Y., J. Phys. Chem. 67, 996 (1963). CrossRef
Besenbacher, F., Sprunger, P.T., Ruan, L., Olsen, L., Stensgaard, I., Laegsgaard, E., Topics in Catalysis 1, 325 (1994). CrossRef
Keating, K.B., Rozner, A.G., Youngblood, I.L., J. Catal. 4, 608 (1965). CrossRef
E.L. Furen, D.V. Geret, T.A. Semenova, Khim. Prom. 4 285 (1972).
Furen, E.L., Geret, D.V., Semenova, T.A., Katal. Katal. 13, 107 (1975).
Popa, O., Rotaru, P., Blejoiu, S.I., Pandele, L., Bunescu, O., Brasoveanu, I., Marchidan, D.I., Rev. Roumaine Chim. 24, 153 (1979).
Filoti, G., Nistor, L., Doca, I., Brasoveanu, I., Spânu, V., Teodorescu, V., Rotaru, P., Blejoiu, S.I., Rev. Roumaine Chim. 24, 1101 (1979).
Steinbrecher, G., Rotaru, P., Saliu, L., Bunescu, O., Muresan, N., Bucur, I., Rev. Roumaine Chim. 26, 1077 (1981).
G.E. Dieter, Mechanichal metallurgy (Technical Publishing, Bucuresti, 1970).
Traina, F., Pernicone, N., Chim. Ind. 52, 235 (1970).
H.P. Klug, L.R. Alexander, X-Ray Diffraction Procedures (John Wiley and Sons, New York, 1966).
D.P. Kistinen, E.R. Marburger, M. Semchyshen, The measurement of Stress by X-Ray (SAE Inc., New York, 1980).
Williamson, G.K., Hall, W.H., Acta Met. 1, 22 (1953). CrossRef
Rachinger, W.A., J. Sci. Instrum. 25, 254 (1948). CrossRef
B.E. Warren, X-Ray Diffraction (Addison-Wesley, Massachussetts, 1969).