Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-25T16:54:51.069Z Has data issue: false hasContentIssue false

Fine modulations in the diffraction pattern of boron nitride nanotubes synthesised by non-ablative laser heating

Published online by Cambridge University Press:  30 August 2004

T. Laude*
Affiliation:
National Institute for Materials Science, Advanced Materials Laboratories, Namiki 1-1, Tsukuba, Ibaraki, 305-0044, Japan
Y. Matsui
Affiliation:
National Institute for Materials Science, Advanced Materials Laboratories, Namiki 1-1, Tsukuba, Ibaraki, 305-0044, Japan
Get access

Abstract

Non-ablative laser heating has recently turned out to be an efficient synthesis method for boron nitride (BN) nanotubes, offering flexibility in the control of experimental parameters. Long tubes are obtained as a hairy growth on the target around laser impact. Tubes are mostly assembled in bundles and thin. Selected area diffraction diagrams reveal that zigzag and armchair helicities are dominant, without preference. A field emission gun enabled to resolve the fine modulations in the diffraction diagrams for multi-walled nanotubes (MWNT) and for bundles of MWNT. The interpretation of the diffraction pattern of nanotubes is generalised for such modulations, considering the analytical expression of the diffracted amplitude at each graphite reflection. The fine modulations in the pattern are linked to roll diameters, bundle lattice, and interlayer distances. Experimentally, several roll diameter modulations are observed. Unusual modulations corresponding to an interlayer distance of 2 layers are also observed. They show a two-roll period, with an alternative shift along tube axis, in the piling of the rolls of MWNT.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Oberlin, A., Endo, M., J. Cryst. Growth 32, 335 (1976) CrossRef
Smith, E.A., Powder Metall. 14, 27 (1971) CrossRef
Lipp, A., Schwetz, K.A., Hunold, K., J. Eur. Ceram. Soc. 5, 3 (1989) CrossRef
Laude, T., Matsui, Y., Marraud, A., Jouffrey, B., Appl. Phys. Lett. 76, 22 (2000) CrossRef
T. Laude, Ph.D. thesis, University of Tsukuba and École Centrale Paris, March 2001 ([email protected] for a copy)
Speck, J.S., Endo, M., Dresselhaus, M.S., J. Cryst. Growth 94, 834 (1989) CrossRef
Iijima, S., Nature 354, 56 (1991) CrossRef
Zhang, X.F. et al., J. Cryst. Growth 130, 368 (1993) CrossRef
Din, L.C. et al., Chem. Phys. Lett. 268, 101 (1997)
Qin, L.C., J. Mater. Res. 9, 9 (1994) CrossRef
Lucas, A., Bruyninckx, V., Lambin, P., Europhys. Lett. 35, 355 (1996) CrossRef
Lambin, P., Lucas, A., Phys. Rev. B 56, 3571 (1997) CrossRef
Ijima, S., Ichihashi, T., Nature 363, 603 (1993) CrossRef
Henrard, L., A. loiseau, C. Journet, P. Bernier, Eur. Phys. J. B 13, 661 (2000) CrossRef
Colomer, J.-F., Henrard, L., Lambin, Ph., Van Tenderloo, G., Eur. Phys. J. B 27, 111 (2002)
Amelinckx, S., Lucas, A., Lambin, P., Rep. Prog. Phys. 62, 1471 (1999) CrossRef
Other, articles related to IM modulation were published during editorial process of present article: Kociak et al., Phys. Rev. Lett. 89, 15 (2002)
Blase, X., De Vita, A., Charlier, J.-C., Car, R., Phys. Rev. Lett. 80, 1666 (1998) CrossRef
Lee, R.S. et al., Phys. Rev. B 64, 121405(R) (2001) CrossRef
Bourgeois, L., Bando, Y., Sato, T., J. Phys. D 33, 1902 (2000) CrossRef