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Composition, pressure and thermodynamic properties calculated in plasma formed in insulator vapours of PC and POM at fixed volume

Published online by Cambridge University Press:  15 January 2002

P. André*
Affiliation:
Laboratoire Arc Électrique et Plasmas Thermiques, Université Blaise Pascal, 24 avenue des Landais, 63177 Aubière Cedex, France
L. Brunet
Affiliation:
GIAT Industries, Centre de Bourges, 7 route de Guerry, 18023 Bourges Cedex, France
E. Duffour
Affiliation:
Laboratoire Arc Électrique et Plasmas Thermiques, Université Blaise Pascal, 24 avenue des Landais, 63177 Aubière Cedex, France
J. M. Lombard
Affiliation:
GIAT Industries, Centre de Bourges, 7 route de Guerry, 18023 Bourges Cedex, France
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Abstract

From the Helmholtz free energy, the pressure, the mole fraction, the internal energy and the specific heat capacity at constant volume in temperature range of 1 000 to 20 000 K in the plasma formed of insulator vapours of PC and POM for various densities (0.05 kg/m3 to 5 kg/m3) and at LTE are calculated. The virial and Debye-Hückel corrections on pressure are discussed. The graphite formation is studied.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2002

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References

D. Grune, D. Hensel, Combustion Behavior of LOVA-Solid-Propellant by ignition with hot Plasma Gases and its influence on the Interior Ballistic Cycle, 17th Int. Symposium on ballistics, Midrand, South Africa, 1998, Vol. 1, pp. 359-366.
Proud, W.G., Bourne, N.K., Prop. Explos. Pyrotech. 22, 212 (1997). CrossRef
B. Baschung, D. Grune, The closed vessel, still an essential experimental device for interior ballistics in the future?, Proceedings European Forum on Ballistics of Projectiles, Saint Louis, April 11-14, 2000, pp. 105-115.
Zaghloul, M.R., Bourham, M.A., Doster, J.M., J. Phys. D: Appl. Phys. 34, 772 (2001). CrossRef
Y. Jordan, Modélisation de la balistique intérieure d'un lanceur électrothermique, Thèse de l'université d'Orléans, 1998.
P. Kovitya, IEEE Trans. Plasma Sci. PS 12, 38 (1984).
J.M. Lombard, B. Baschung, D. Grune, A. Carriere, P. Andre, First analysis of French ETC program manometric closed vessel tests, Axes 2.13 ISL, Saint Louis, Mars 2000.
Caillard, J., de Izarra, C., Brunet, L., Experimental Assessment of a 1 kJ Electro-Pyrotechnic Device Ignited in the 300-1000 V Range for ETC Studies, IEEE Trans. Magn. 37, 152 (2001). CrossRef
E. Duffour, Interaction Plasma-Isolant. Applications au lanceur électrothermique et à l'interaction SF6-Polyéthylène, Thèse de l'université Blaise Pascal, Clermont Ferrand, DU 1250, 2000.
L. Msika, Étude Spectroscopique d'un plasma dense faiblement non-ideal créé dans un lanceur électrothermique, Thèse de l'université Paris VI, 1995.
B. Baschung, Étude Phénoménologique des fluides moteurs utilisés dans un générateur de plasma d'un lanceur électrothermique, Thèse de l'université de Haute Alsace, DU 96Mulh0449, 1996.
Cheminat, B., Rev. Phys. Appl. 24, 277 (1989). CrossRef
J.O. Hirschfelder, C.F. Curtiss, R.B. Bird, Molecular Theory of Gases and Liquids (John Wiley & Sons, Inc., 1954).
M.I. Boulos, P. Fauchais, E. Pfender, Thermal Plasmas: Fundamentals and Applications (Plenum Press, 1994), Vol. 1.
F. Van Zeggeren, S.H. Storey, The Computation of Chemical Equilibria (Cambridge at the University Press, 1970).
JANAF, NIST-JANAF, Thermochemical tables, 4th edn., edited by M.W. Chases Jr., Journal of Physical and Chemical Reference Data, Monograph No. 9 (1998).
J. Aubreton, Étude des propriétés thermodynamiques et de transport dans les plasmas thermiques à l'équilibre et hors d'équilibre thermodynamique : applications aux plasmas de mélanges Ar-H2 et Ar-O2, Thèse d'État, Université de Limoges, France (1985).
Griem, H.R., Phys. Rev. 128, 997 (1962). CrossRef
Zaghoul, M.R., Bourham, M.A., Doster, J.M., J. Phys. D: Appl. Phys. 33, 977 (2000).
J.M. Lombard, L. Brunet, P. Andre, E. Duffour, A. Lefort, B. Baschung, Éléments de modélisation des interactions plasma-matière dans un lanceur électrothermique, Axes 2.13 ISL, Saint Louis, Mars 1999.
J.M. Lombard, B. Baschung, D. Grune, A. Carrière, P. André, Analysis of ETC or classical manometric closed vessel tests with coupling of thermodynamic equilibrium calculations: combustion rate, energy losses, 19th International Symposium of Ballistics, 7-11 Mai, Interlaken, Switzerland, 2001, pp. 171-178.
C.E. Moore, Atomic Energy Levels, Circular of the National Bureau of Standards 467 (1949).
NIST Database 61, Database for Atomic Spectroscopy (DAS), 1995, National Institute of Standards an Technology: http://aeldata.phy.nist.gov/archive/el.html.
Drellishak, K.S., Aeschliman, D.P., Ali Bulent Cambel, Phys. Fluids 8, 1590 (1965). CrossRef
G.F.R.S. Herzberg, Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecules, 2nd edn. (D. Van Nostrand Company, Inc., Princeton, 1950).
K.P. Huber, G. Herzberg, Molecular Spectra and Molecular Structure I.V Constants of diatomic molecules (Van Nostrand Reinhold Company, Inc., Princeton, 1979).
Biolsi, L., Rainwater, J.C., Holland, P.M., J. Chem. Phys. 77, 448 (1982). CrossRef
Hulburt, H.M., Hirschfelder, J.O., J. Chem. Phys. 9, 61 (1941)
K. Kappen, Berechnung der Materialfunktionen von Hochdruckplasmen am Beispiel von Methanol, Lehrstuhl f ür Technische Elecktrophysik, Technische Universit ät M ünchen, 1994.
Z. Koalaga, Contribution à l'étude expérimentale et théorique des plasmas d'arcs électrique laminés, Thèse de l'Université Blaise Pascal, Clermont Ferrand, 1991.
Yukikazu Itikawa, , Atomic Data and Nuclear Data Tables 21, 69 (1978).
CRC Handbook of Chemistry and Physics, 77 edition, CRC Press, 1996-1997.
Mason, E.A., Munn, R.J., Smith, F.J., Phys. Fluids 10, 1827 (1967). CrossRef