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Atmospheric pressure generation of O2(a1Δg ) by microplasmas

Published online by Cambridge University Press:  05 June 2009

J. S. Sousa*
Affiliation:
Laboratoire de Physique des Gaz et des Plasmas, UMR 8578 CNRS/Université Paris-Sud, Bât. 210, 91405 Orsay, France Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal
G. Bauville
Affiliation:
Laboratoire de Physique des Gaz et des Plasmas, UMR 8578 CNRS/Université Paris-Sud, Bât. 210, 91405 Orsay, France
B. Lacour
Affiliation:
Laboratoire de Physique des Gaz et des Plasmas, UMR 8578 CNRS/Université Paris-Sud, Bât. 210, 91405 Orsay, France
V. Puech
Affiliation:
Laboratoire de Physique des Gaz et des Plasmas, UMR 8578 CNRS/Université Paris-Sud, Bât. 210, 91405 Orsay, France
M. Touzeau
Affiliation:
Laboratoire des Techniques de la Microélectronique, UMR 5129 CNRS/Université Joseph Fourier/INPG, 17 av. des Martyrs, 38054 Grenoble, France
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Abstract

The generation of singlet delta oxygen states (O2(a1Δg )) by microplasmas has been studied experimentally. In the present paper, it is shown that micro-cathode sustained discharges (MCSD's) can be used to produce high fluxes of O2(a1Δg ) at atmospheric pressure. In He/O2/NO mixtures, O2(a1Δg ) number densities higher than 1016 cm−3 can be generated by this 3-electrode configuration and transported over distances of some tens of cm. In fact, at total flow rates up to 30 ln/min, O2(a1Δg ) fluxes above 10 mmol/h were measured in the MCSD afterglow, at 26 cm downstream. As a result, MCSD's appear to be very efficient and suitable tools for the continuous production of large amounts of O2(a1Δg ) at atmospheric pressure, which could give rise to a wide range of new applications, namely biological. The effect of different parameters such as gas flows and mixtures, and discharge current are discussed in the paper.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2009

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