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An Experimental Study of the Products of Dissociative Recombination of Molecular Ions with Electrons

Published online by Cambridge University Press:  04 August 2017

F. Vallée
Affiliation:
*Département de Physique Atomique et Moléculaire, U.A. CNRS 1203, Université de Rennes I, 35042 Rennes Cédex, France
J.C. Gomet
Affiliation:
*Département de Physique Atomique et Moléculaire, U.A. CNRS 1203, Université de Rennes I, 35042 Rennes Cédex, France
B.R. Rowe
Affiliation:
**Laboratoire d'Aérothermique du C.N.R.S., 4 ter route des Gardes, 92190 Meudon, France
J.L. Quéffelec
Affiliation:
*Département de Physique Atomique et Moléculaire, U.A. CNRS 1203, Université de Rennes I, 35042 Rennes Cédex, France
M. Morlais
Affiliation:
*Département de Physique Atomique et Moléculaire, U.A. CNRS 1203, Université de Rennes I, 35042 Rennes Cédex, France

Abstract

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A new experimental method has been developed which allows determination of the products nature in dissociative recombination (D.R.) of molecular ions. Results are presented on H2O+ D.R. which show that there is a large yield of oxygen atoms in this reaction. the measurements give a total yield for the two channel O + H + H and O + H2 of 0.45 and therefore a yield of 0.55 for OH + H. H2O+ ions are formed by charge exchange from N+ ions and are probably vibrationally excited in this experiment.

Type
Basic Studies
Copyright
Copyright © Reidel 1987 

References

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