The 3-PS structure features one rigid body (platform) connected to another rigid body (base) by means of three kinematic chains (limbs) of type PS (P and S stand for prismatic pair and spherical pair, respectively). All the 3-degree-of-freedom parallel manipulators with three connectivity-5 limbs, each one constituted of one passive (i.e. not actuated) prismatic pair, one passive spherical pair and one actuated kinematic pair of any type, become 3-PS structures when the actuated pairs are locked. Direct kinematics of this class of manipulators is tied to the properties of the 3-PS structure. In particular, the direct position analysis is tied to the assembly modes of the 3-PS structure; whereas the determination of the singularities of the direct instantaneous problem is tied to the determination of the singular geometries of the 3-PS structure, where instantaneous relative motions between platform and base are possible. The solution of these two problems is necessary both for designing the manipulators and for controlling them during motion. This paper deal with the determination of the singular geometries of the 3-PS structure.