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Spatial Radiocarbon and Stable Carbon Isotope Variability of Mineral and Thermal Waters in Slovakia

Published online by Cambridge University Press:  18 July 2016

P P Povinec ,
O Franko ,
A Šivo ,
M Richtáriková ,
R Breier ,
P K Aggarwal  and
L Araguás-Araguás
P P Povinec*
Affiliation:
Department of Nuclear Physics and Biophysics, Faculty of Mathematics, Physics and Informatics, Comenius University, SK-84248 Bratislava, Slovakia
O Franko
Affiliation:
State Geological Institute of Dionýz Štúr, Bratislava, Slovakia
A Šivo
Affiliation:
Department of Nuclear Physics and Biophysics, Faculty of Mathematics, Physics and Informatics, Comenius University, SK-84248 Bratislava, Slovakia
M Richtáriková
Affiliation:
Department of Nuclear Physics and Biophysics, Faculty of Mathematics, Physics and Informatics, Comenius University, SK-84248 Bratislava, Slovakia
R Breier
Affiliation:
Department of Nuclear Physics and Biophysics, Faculty of Mathematics, Physics and Informatics, Comenius University, SK-84248 Bratislava, Slovakia
P K Aggarwal
Affiliation:
Isotope Hydrology Section, International Atomic Energy Agency, A-1400 Vienna, Austria
L Araguás-Araguás
Affiliation:
Isotope Hydrology Section, International Atomic Energy Agency, A-1400 Vienna, Austria
*
Corresponding author. Email: [email protected].
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Abstract

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Isotope hydrology investigations were carried out with the aim to study isotope variability in mineral and thermal waters (MTW) of Slovakia. The aquifers of MTW were formed by Triassic limestones and dolomites, which are found in the mountains as well as in the pre-Tertiary substratum of depressions and lowlands. The MTW were of artesian and/or open structures. At present, there are only boreholes available, as natural outflows have already been captured by them. Large spatial isotope variability (14C between 2 and 33.6 pMC, δ18O between −11.8‰ and −9.8‰, and δ13C between −12.7‰ and +3.4‰ for bicarbonates and −21‰ and –4.9‰ for free CO2) and heterogeneity of MTW was observed, indicating different origins of MTW. Corrected radiocarbon apparent ages of MTW indicate that they mostly infiltrated during the Würm and Holocene periods.

Type
Freshwater and Groundwater
Information
Radiocarbon , Volume 52 , Issue 3: 20th Int. Radiocarbon Conference Proceedings , 2010 , pp. 1056 - 1067
Copyright
Copyright © 2010 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Aggarwal, PK, Gat, JR, Froehlich, KFO, editors. 2006. Isotopes in the Water Cycle. Heidelberg: Springer. 381 p.Google Scholar
Böhlke, JK, Révész, K, Busenberg, E, Deák, J, Deseö, E, Stute, M. 1997. Groundwater record of halocarbon transport by the Danube River. Environmental Science and Technology 31(11):3293–9.CrossRefGoogle Scholar
Bowen, GJ, Wassenaar, LI, Hobson, KA. 2005. Global application of stable hydrogen and oxygen isotopes to wildlife forensics. Oecologia 143(3):337–48.Google Scholar
Deák, J. 2003. Isotope-hydrogeology studies in Hungary focusing on the requirements of the EU Water Framework Directive. In: Proceedings of the Isotopenmethoden in der Hydrogeologie und Wasserwirtschaft. Vienna: Universität für Bodenkultur Wien. p 1–9.Google Scholar
Deák, J, Deseoe, E, Böhlke, JK, Révész, K. 1995. Isotope hydrology studies in the Szigetköz region, northwest Hungary. In: Proceedings of Isotopes in Water Resources Management. Vienna: IAEA. p 419–32.Google Scholar
Fontes, J-C, Garnier, J-M. 1979. Determination of the initial 14C activity of the total dissolved carbon: a review of the existing models and a new approach. Water Resources Research 15:399–413.Google Scholar
Franko, O, Franko, J. 2000. Thermal waters of the Hornonitrianska kotlina depression and their utilization. Enviromental Geology 39(5):501–15.Google Scholar
Franko, O, Melioris, L. 1999. Conditions for formation and extension of mineral and thermal waters in the Western Carpathians. Slovak Geological Magazine 5:93–107.Google Scholar
Franko, O, Michalko, J, Šivo, A. 2000. Isotopes of oxygen and 14C in the geothermal waters of Pliocene sediments of Danube basin. In: Proceedings of Conference Nr. 45. Kraków: PAN. p 229–40.Google Scholar
Franko, O, Šivo, A, Richtáriková, M, Povinec, PP. 2008. Radiocarbon ages of mineral and thermal waters of Slovakia. Acta Physica Universitatis Comeniana 49:125–32.Google Scholar
Geyh, MA. 1991. The 14C time-scale of groundwater. Correction and linearity. In: Isotope Techniques in Water Resources Development 1991. Vienna: IAEA. p 167–77.Google Scholar
Geyh, MA. 2004. Radiocarbon dating of old groundwater— history, potential, limits and future. In: Isotope Hydrology and Integrated Water Resources Management. Vienna: IAEA. p 23–5.Google Scholar
Geyh, MA, Wendt, I. 1965. Results of water sample dating by means of the model by Münnich and Vogel. In: Radiocarbon and Tritium Dating, Pulmann, Washington, USA. p 597–603.Google Scholar
Kendall, C, McDonnell, J, editors. 1999. Isotope Tracers in Catchment Hydrology. Amsterdam: Elsevier.Google Scholar
Lukniš, M. 1959. Relief und Gliederung der quartären gebilde in der Hohen Tatra und deren vorlande. Geologicky Zbornik SAV 10:233–68.Google Scholar
Lukniš, M. 1964. The course of the last glaciation of the western Carpathians in relation to the Alps, to the glaciation of the northern Europe, and to the division of the central European Würm periods. Geografickýčasopis SAV 16:127–42.Google Scholar
Malík, P, Michalko, J, Mansell, SJ, Fendeková, M. 1996. Stable isotopes in karstic groundwaters of Vel'ká Fatra mountains, Slovakia. In: Proceedings of Isotopes in Water Resources Management. Vienna: IAEA.Google Scholar
Melioris, L. 2000. Mineral and thermal waters of the Ipelská pahorkatina highland. Enviromental Geology 39:448–62.Google Scholar
Michalko, J. 1999. Stable isotopes of hydrogen, oxygen and sulphur in the waters of Slovakia. Slovak Geology Magazine 5:63–7.Google Scholar
Michalko, J, Malík, P. 1998. Isotope geochemistry applications in the process of study of Slovak natural waters genesis. Pozemná voda 4:42–50. In Slovak.Google Scholar
Plummer, LN, Prestemon, EC, Parkhurst, DL. 1994. An interactive computer code NETPATH for modeling NET geochemical reactions along a flow PATH. Reston: US Geological Survey Water-Resources Investigations Report 94–4169. 130 p.Google Scholar
Pospíšil, P. 1978. A contribution of tritium analyses to the study of groundwater flow in the sediments of Źitný ostrov. Annals of the Hungarian Geological Institute 59:601–11.Google Scholar
Povinec, P. 1972. Preparation of methane gas filing for proportional 3H and 14C counters. Radiochemical and Radioanalytical Letters 9:127–35.Google Scholar
Povinec, P. 1978. Multiwire proportional counters for low-level 14C and 3H measurements. Nuclear Instruments and Methods 156(3):441–5.CrossRefGoogle Scholar
Povinec, PP, Šivo, A, Richtáriková, M, Breier, R, Lúčan, L, Aggarwal, PK, Araguás-Araguás, L. 2010. Spatial distribution of isotopes in groundwater of Slovakia. Acta Physica Universitatis Comeniana 51:143–53.Google Scholar
Rank, D, Pepesch, W, Rainer, V. 1995. Environmental isotope study at research landfill (Breitenan, Austria). In: Proceedings of Isotopes in Water Resources Management. Vienna: IAEA. p 379–81.Google Scholar
Stute, M, Deák, J, Révesz, K, Böhlke, JK, Deseö, E, Weppernig, R, Schlosser, P. 1997. Tritium/3He dating of river infiltration: an example from the Danube in the Szigetköz area, Hungary. Ground Water 35(5):905–11.Google Scholar
Usačev, S, Povinec, P, Chudý, M, Šeliga, M. 1973. Bratislava radiocarbon measurements I. Radiocarbon 15(3):443–50.Google Scholar
Vogel, JC. 1970. Carbon-14 dating of groundwater. In: Isotope Hydrology 1970. Vienna: IAEA. p 235–27.Google Scholar