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The Radiocarbon Dating and Authentication of Iron Artifacts

Published online by Cambridge University Press:  18 July 2016

P T Craddock
Affiliation:
Department of Scientific Research, The British Museum, London WC1B 3DG, United Kingdom.
M L Wayman
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton T6G 2G6, Canada.
A J T Jull
Affiliation:
NSF–Arizona AMS Laboratory, The University of Arizona, Tucson, Arizona 85712-1201, USA.
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Abstract

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The continuing improvements in accelerator mass spectrometry (AMS) dating technology mean that it is possible to work on ever smaller samples, which in turn, make an ever wider range of sample potentially available for dating. This paper discusses some of the difficulties arising with the interpretation of AMS dates obtained from carbon in iron. The overriding problem is that the carbon, now in chemical combination with the iron, could have come from a variety of sources with very different origins. These are now potentially an iressolvable mixture in the iron. For iron made over the last millennium, there are the additional problems associated with the use of both fossil fuel and biomass fuel in different stages of the iron making, leading to great confusion, especially with authenticity studies.

Type
Articles
Copyright
Copyright © The Arizona Board of Regents on behalf of the University of Arizona 

References

Allan, J. 1979. Persian metal technology. London: Ithaca Press.Google Scholar
Allan, J, Gilmour, B. 2000. Persian steel. Oxford: Oxford University Press.Google Scholar
Barraclough, KC. 1984a. Steelmaking before Bessemer 1. Blister Steel. London: The Metals Society.Google Scholar
Barraclough, KC. 1984b. Steelmaking before Bessemer 2. Crucible Steel. London: The Metals Society.Google Scholar
Barraclough, KC. 1990. Steelmaking: 1850–1900. London: The Metals Society.Google Scholar
Bronson, B. 1986. The making and selling of Wootz: a crucible steel of India. Archeomaterials 1(1)1351.Google Scholar
Carnegie, D. 1913. Liquid steel: its manufacture and cost. London: Longmans Green.Google Scholar
Cleere, H, Crossley, D. 1985. The iron industry of the Weald. Leicester: Leicester University Press.Google Scholar
Cook, AC, Wadsworth, J, Southon, JR. 2001. AMS radiocarbon dating of ancient iron artifacts: a new carbon extraction method in use at LLNL. In: Carmi, I and Boaretto, E, editors. Proceedings of the 17th International 14C Conference. Radiocarbon 43(2A):221227.CrossRefGoogle Scholar
Cook, AC, Wadsworth, J, Southon, JR, van der Merwe, NJ. 2003. AMS radiocarbon dating of rusty iron. Journal of Archaeological Science 30(1):95102.CrossRefGoogle Scholar
Craddock, PT. 1995. Early metal mining and production. Edinburgh: Edinburgh University Press.Google Scholar
Craddock, PT. 1998. New light on the production of crucible steel in Asia. Bulletin of the Metals Museum of the Japan Institute of Metals 29:4166.Google Scholar
Craddock, PT. 2003. Cast iron, fined iron, crucible steel: liquid iron in the ancient world. In: Craddock, PT, Lang, J, editors. Mining and Metal Production Through the Ages. London: BMP. p 223–48.Google Scholar
Craddock, PT, Lang, J. 1993. Gizeh iron revisited. Journal of the Historical Metallurgy Society 27(2)57–9.Google Scholar
Craddock, PT, Wayman, ML. 2000. The development of European ferrous metallurgy. In: Wayman, ML, editor. The Ferrous Metallurgy of Early Clocks and Watches, X. London: British Museum Occasional Paper 136. p 1329.Google Scholar
Craddock, PT, Wayman, ML, Wang, H, Michaelson, C. Chinese cast iron through 2500 Years. In: Jett, P, editor. Scientific Research in the Field of Asian Art. London: Archtype Books. Forthcoming.Google Scholar
Creswell, RG. 1991. The radiocarbon dating of iron artefacts using accelerator mass spectrometry. Journal of the Historical Metallurgy Society 25(2):7685.Google Scholar
Cresswell, RG. 1992. Radiocarbon dating of iron artefacts. In: Long, A, Kra, RS. Proceedings of the 14th International 14C Conference. Radiocarbon 34(3):898905.Google Scholar
Donahue, DJ, Jull, A.JT, Linick, TW, Toolin, LJ. 1990a. Some archaeological applications of accelerator radiocarbon analysis. Nuclear Instrumentation Methods B45:561564.Google Scholar
Donahue, DJ, Linick, TW, Jull, AJT. 1990b. Isotope-ratio and background corrections for accelerator mass spectrometry radiocarbon measurements. Radiocarbon 32(2)135142.Google Scholar
Eylon, D. 2002. On the radiocarbon dating of iron. In: Kim, G-H, Yi, K-W, Kang, H-T, editors. BUMA-V. Messages from the History of Metals to the Future Metal Age. Seoul: Korean Institute of Metals and Materials. p 161168.Google Scholar
Fitzhugh, WW. 1993. Exploration after Frobisher. In: Fitzhugh, WW and Olin, JS, editors. 1993. Archeology of the Frobisher voyages, Washington DC: Smithsonian Institution Press.Google Scholar
Fitzhugh, WW, Olin, JS, editors. 1993. Archeology of the Frobisher voyages. Washington DC: Smithsonian Institution Press.Google Scholar
Freestone, IC, Tite, MS. 1986. Refractories from the ancient and preindustrial world. In: Kingery, W, editor. Ceramics and Civilisation III, Westerville, Ohio: American Ceramic Society. p 3563.Google Scholar
Fulford, MG, Allen, JRL. 1992. Iron-making at the Chesters Roman Villa, Woolaston, Gloucestershire. Survey and excavation 1987–91. Britannia 23. Appendix by I. Figueiral on the fuels. p 188–91.Google Scholar
Gassman, G, Yalçin, Ü, Hauptmann, A. 1995. Frühemittelalterliche Eisenproduktion in Kippenheim, Subaden: Ein “missing link” zwischen Rennverfahren und Röhleisentechnologie. Metalla 2(2)4352.Google Scholar
Gordon, RB. 1996. American iron 1607–1900. Baltimore: John Hopkins University Press.Google Scholar
Han Rubin. 1996. The development of Chinese ancient blast furnace. In: Igaki, K, editor. The Proceedings of the Forum for the Fourth International Conference on the Beginnings of the Use of Metals and Alloys. Sendai: The Japan Institute of Metals. p 151–74.Google Scholar
Harbottle, G, Cresswell, RG, Stoenner, RW. 1993. Carbon-14 dating of iron blooms from Kodlunarn Island. In: Fitzhugh, WW and Olin, JS, editors. 1993. Archeology of the Frobisher Voyages. Washington DC: Smithsonian Institution Press. p 173–80.Google Scholar
Hart, C. 1971. The industrial history of Dean. Newton Abbot, Devon: David and Charles.Google Scholar
Hartwell, R. 1966. Markets, technology, and the structure of enterprise in the development of the eleventh century Chinese iron and steel industry. Journal of Economic History 26:2958.CrossRefGoogle Scholar
Hartwell, R. 1967. A cycle of economic change in imperial China: coal and iron in northeast China, 750–1350. Journal of Economic and Social History of the Orient 10:102–59.Google Scholar
Kenyon, M. 1975. Tokens of possession: the northern voyages of Martin Frobisher. Ontario: Royal Ontario Museum.Google Scholar
Knau, HL, Sönnecken, M. 1994. Rennfeuer, Massenhütte, Hammerwerk. In: Mangin, M, editor. La sidérgie ancienne de l'Est de la France dans son contexte européen. Paris: Les Belles Lettres. p 121–30.Google Scholar
Kusimba, CM, Killick, DJ, Cresswell, RG. 1994. Indigenous and imported metals at Swahili sites on the coast of Kenya. Society, Culture and Technology in Africa, 11(Supplement):6377.Google Scholar
Laeyendecker, D. 1993. Wood and charcoal remains from Kodlunarn. In: Fitzhugh, WW and Olin, JS, editors. 1993. Archeology of the Frobisher Voyages. Washington DC: Smithsonian Institution Press. p 155–72.Google Scholar
Lang, J, Craddock, PT, Simpson St, J. 1998. New evidence for early crucible steel. Journal of the Historical Metallurgy Society 32(1)714.Google Scholar
McFee, W. 1928. The life of Sir Martin Frobisher. New York: Harper and Brothers.Google Scholar
Mack, I, McDonnell, G, Murphy, S, Andrews, P, Wardley, K. 2000. Liquid steel in Anglo-Saxon England. Journal of the Historical Metallurgy Society 34(2):8796.Google Scholar
Magnusson, G. 1985. Lapphyttan—an example of medieval iron production. In: Hook, E and Palsson, R, editors. Medieval Iron in Society. Stockholm: Jernkontoret and Riksantikvarinëambetet. p 2257.Google Scholar
Maréchal, J-R. 1985. Methods of ore roasting and the furnaces used. In: Craddock, PT and Hughes, MJ, editors. Furnaces and Smelting Technology in Antiquity. London: British Museum Occasional Paper 48. p 2942.Google Scholar
van der Merwe, N. 1969. The Carbon-14 dating of iron. Chicago: University of Chicago Press.Google Scholar
Pounds, NJG. 1971. The geography of iron and steel. London: Hutchinson.Google Scholar
Shihua, Qui, Liazhen, Cai. 1986. Woguo gudai yetie ranliao de tan-shisi jianding (Use of radiocarbon dating to determine the fuel used in ancient Chinese iron-smelting). In: Zhongshu, Wang and Zhimin, An, editors. Zhongguo kaoguxue yanjiu. Beijing: Wenwu Chubanshe. p 359–63. In Chinese.Google Scholar
Rostoker, W, Bronson, B. 1990. Pre-industrial iron. Philadelphia: Archeomaterials Monograph 1.Google Scholar
Rostoker, W, Dvorak, J. 1990. Wrought iron: distinguishing between processes. Archeomaterials 4(2):153–66.Google Scholar
Sayre, EV, Harbottle, G, Stoenner, RW, Washburn, W, Olin, JS, Fitzhugh, WW. 1982. The Carbon-14 dating of an iron bloom associated with the voyages of Sir Martin Frobisher. In: Currie, L, editor. Nuclear and Chemical Dating Techniques. ACS Symposium Series 176. Washington DC: American Chemical Society. p 441–51.Google Scholar
Sherby, OD, Wadsworth, J. 2001. Ancient blacksmiths, the Iron Age, Damascus steels, and modern metallurgy. Journal of Materials Processing Technology 117(3):347–53.CrossRefGoogle Scholar
Smith, CS, Gnudi, MT, translators and editors. 1942. The pirotechnia of Vannoccio Biringuccio. New York: Basic Books.Google Scholar
Starley, D. 1999. Determining the technological origins of iron and steel. Journal of Archaeological Science 26(8):1127–33.CrossRefGoogle Scholar
Stuiver, M, Pearson, GW. 1986. High-precision calibration of the radiocarbon time scale AD 1950–5000 BC. Radiocarbon 28(2B):805–38.Google Scholar
Tylecote, R F. 1992. A history of metallurgy, 2nd ed. London: The Metals Society.Google Scholar
Unglik, H. 1993. Metallurgical study of an iron bloom and associated finds from Kodlunarn Island. In: Fitzhugh, WW and Olin, JS, editors. 1993. Archeology of the Frobisher Voyages. Washington DC: Smithsonian Institution Press. p 173–80.Google Scholar
Wagner, D. 1993. Iron and steel in ancient China. Leiden: Brill.Google Scholar
Wagner, D. 2001. Blast furnaces in Song-Yuan China. East Asian Science, Technology and Medicine 18:4174.Google Scholar
Wayman, ML, Ehrenreich, RM. 1993. Metallurgical study of small iron finds. In: Fitzhugh, WW and Olin, JS, editors. 1993. Archeology of the Frobisher Voyages. Washington DC: Smithsonian Institution Press. p 213–20.Google Scholar
Webster, G. 1955. A note of the use of coal in Roman Britain. Antiquaries Journal 35(3/4):199217.CrossRefGoogle Scholar