Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-29T19:44:34.204Z Has data issue: false hasContentIssue false
  • English
  • Français

Isotopic Analysis of Groundwater and Carbonate System in the Surdulica Geothermal Aquifer1

Published online by Cambridge University Press:  18 July 2016

Munevera Hadžišehović ,
Nada Miljević ,
Vojislava Šipka ,
Dušan Golobočanin  and
Radule Popović
Munevera Hadžišehović
Affiliation:
Boris Kidrič Institute of Nuclear Sciences, Vinča, P. O. Box 522, 11001 Belgrade, Yugoslavia
Nada Miljević
Affiliation:
Boris Kidrič Institute of Nuclear Sciences, Vinča, P. O. Box 522, 11001 Belgrade, Yugoslavia
Vojislava Šipka
Affiliation:
Boris Kidrič Institute of Nuclear Sciences, Vinča, P. O. Box 522, 11001 Belgrade, Yugoslavia
Dušan Golobočanin
Affiliation:
Boris Kidrič Institute of Nuclear Sciences, Vinča, P. O. Box 522, 11001 Belgrade, Yugoslavia
Radule Popović*
Affiliation:
Boris Kidrič Institute of Nuclear Sciences, Vinča, P. O. Box 522, 11001 Belgrade, Yugoslavia
*
Geoinstitute, Rovinjska 12, 11000 Belgrade, Yugoslavia
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

We present here results of our investigation of the isotopic chemical composition of groundwater and carbonates in the Surdulica geothermal aquifer, Serbia. We considered the effects of carbonate dissolution and measured 13C, 14C, D, 18O, 3H, field pH, temperature, Na+, Ca2+, Mg2+, HCO−3; and other aqueous species from 30 springs and boreholes. Geothermal waters are supersaturated with calcite. Carbon isotope compositions vary with carbonate mineral dissolution. The δD and δ18O of groundwater samples fit the meteoric water line, and indicate that groundwater is recharged mainly from higher altitudes and the cold season. Different groundwater residence times point out two mechanisms for their formation: fissure flow for young waters and standard diffusion processes for old ones.

Type
Articles
Information
Radiocarbon , Volume 35 , Issue 2 , 1993 , pp. 277 - 286
Copyright
Copyright © The American Journal of Science 

Footnotes

1

This paper was presented at the 14th International 14C Conference, 20-24 May 1991, Tucson, Arizona.

References

Anderson, E. 1985 Review of Vranjska Banja Geothermal Prospect, Scientific and Engineering Aspects. Wellington, New Zealand, GENZ-Geothermal Energy New Zealand, Ltd.: 12 P.Google Scholar
Babović, M., Vukanović, M., Krajačić, V., Rakić, M. and Dimitrijević, M. 1970 Basic Geological Map, Chart Vranje 1: 1000–000. Geozavod, Federal Geological Institute, Belgrade.Google Scholar
Coleman, M. L., Shepherd, T. J., Durham, J. J., Rouse, J. B. and Moore, G. R. 1982 Reduction of water with zinc for hydrogen isotope analysis. Analytical Chemistry 54: 993–995.CrossRefGoogle Scholar
Dimitrijević, M., Petrović, B., Cikin, M., Mozina, A., Vikanović, M. and Karajičić, L. J. 1965 Interpreter of the Basic Geological Map of the SFRJ, Chart Leskovac 1: 100000. Federal Geological Institute, Belgrade.Google Scholar
Fontes, J. Ch. and Garnier, J. M. 1979 Determination of the initial 14C activity of the total dissolved carbon: A review of the existing models and a new approach. Water Resources Research 15: 399–413.CrossRefGoogle Scholar
Henley, R. W., Truesdell, A. H., Barton, P. B., Whitney, J. A. and Robertson, J. M., eds., 1985 Fluid-mineral equilibrium in hydrothermal systems. Review of Economic Geology 1: 31–43.Google Scholar
Hut, G. 1986 Intercomparison of Low-Level Tritium Measurements in Water. Vienna, IAEA.Google Scholar
IAEA (ms.) 1980 Preparation of carbon dioxide for C-14 measurements. Technical Procedure Note: 25 p.Google Scholar
Milovanović, B., Stanković, S., Komatina, M., Hadžišehović, M., Zupančić, M., Miljević, N., Stepić, R. and Obelić, B. 1989 Isotopic investigation of the Surdulica geothermal system. in Long, A. and Kra, R. S., eds., Proceeding of the 13th International 14C Conference, Radiocarbon 31(3): 893–901.Google Scholar
Popović, R. 1990 The Serbian-Macedonian mass - yes or no? Records of the Serbia Geological Society, 1990, Belgrade.Google Scholar
Srdoč, D., Breyer, B. and Sliepčević, A. 1971 Rudjer Bošković Institute radiocarbon measurements I. Radiocarbon 13(1): 35–140.Google Scholar
Yurtsever, Y. 1983 Models for tracer data analysis. in IAEA/UNESCO Guidebook in Nuclear Techniques in Hydrology. IAEA Technical Reports Series 91: 381–400.Google Scholar
Žujović, J. M. 1893 Thermal springs of Vranjska Spa. In Geology of Serbia Vol. II-Granite. Belgrade, Serbian Royal Academy: 54–73.Google Scholar