Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-19T09:24:41.986Z Has data issue: false hasContentIssue false

Carbon Isotope Measurements of Surface Seawater from a Time-Series Site Off Southern California

Published online by Cambridge University Press:  18 July 2016

Elise N Hinger*
Affiliation:
Earth System Science, Keck Carbon Cycle AMS Laboratory, University of California, Irvine, California 92697-3100, USA
Guaciara M Santos
Affiliation:
Earth System Science, Keck Carbon Cycle AMS Laboratory, University of California, Irvine, California 92697-3100, USA
Ellen R M Druffel
Affiliation:
Earth System Science, Keck Carbon Cycle AMS Laboratory, University of California, Irvine, California 92697-3100, USA
Sheila Griffin
Affiliation:
Earth System Science, Keck Carbon Cycle AMS Laboratory, University of California, Irvine, California 92697-3100, USA
*
Corresponding author. Email: [email protected].
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

We report carbon isotope abundances of dissolved inorganic carbon (DIC) in surface seawater collected from a time-series site off the Newport Beach Pier in Orange County, California. These data represent the first time series of Δ14C data for a coastal southern California site. From a suite of samples collected daily from 16 October to 11 November 2004, Δ14C values averaged 32.1 ± 4.4‰. Freshwater input from the Santa Ana River to our site caused Δ14C and δ13C values to decrease. Since this initial set of measurements, a time-series site has been maintained from November 2004 to the present. Surface seawater has been collected bimonthly and analyzed for Δ14C, δ13C, salinity, and ΣCO2 concentrations. Water samples from the Santa Ana River were collected during the wet season. California sea mussels and barnacle shells, ranging from 4 to 6 months old, were also collected and analyzed. Results from May 2005 to January 2008 show no long-term changes in δ13C DIC values. Δ14C DIC values over the 2005–2006 period averaged 33.7‰; high Δ14C values were observed sporadically (every 6–7 months), suggesting the presence of open water eddies at our site. Finally, in 2007, a stronger upwelling signal was apparent as indicated by correlations between Δ14C, salinity, and the Bakun index, suggesting that the Δ14C record is an indicator of upwelling in the Southern California Bight.

Type
Marine Studies
Copyright
Copyright © 2010 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Bakun, A. 1973. Coastal upwelling indices, west coast of North America, 1946–71. US Department of Commerce, NOAA Technical Report, NMFS SSRF-671.Google Scholar
Beaupré, SR. 2007. Dissolved organic carbon concentrations and isotope ratios in the northeast Pacific Ocean [PhD dissertation]. Earth System Science Department, University of California, Irvine. 142 p.Google Scholar
Bray, NA, Keyes, A, Morawitz, WML. 1991. The California Current system in the Southern California Bight and the Santa Barbara Channel. Journal of Geophysical Research 104(C4):7695–714.Google Scholar
Coe, WR, Fox, DL. 1942. Biology of the California sea-mussel (Mytilus Californianus). I. Influence of temperature, food supply, sex and age on the rate of growth. Journal of Experimental Zoology 90(1):130.CrossRefGoogle Scholar
DiGiacomo, PM, Holt, B. 2001. Satellite observations of small coastal ocean eddies in the Southern California Bight. Journal Geophysical Research 106(C10):22,521–43.CrossRefGoogle Scholar
Druffel, ERM, Williams, PM. 1991. Radiocarbon in seawater and organisms from the Pacific coast of Baja California. Radiocarbon 33(3):291–6.CrossRefGoogle Scholar
Goericke, R, Venrick, E, Koslow, T, Sydeman, WJ, Schwing, FB, Bograd, SJ, Peterson, WT, Emmett, R, Rubén, LLJ, Castro, GG, Valdez, JG, Hyrenbach, KD, Bradley, RW, Weise, MJ, Harvey, JT, Collins, C, Lo, NCH. 2007. The state of the California Current, 2006–2007: regional and local processes dominate. California Cooperative Oceanic Fisheries Investigations Report 48:3366.Google Scholar
Gucinski, HRT, Lackey, RT, Spence, BC. 1990. Global climate change: policy implications for fisheries. Fisheries 15(6):33–8.2.0.CO;2>CrossRefGoogle Scholar
Guilderson, T, Roark, EB, Quay, PD, Flood Page, SR, Moy, C. 2006. Seawater radiocarbon evolution in the Gulf of Alaska: 2002 observations. Radiocarbon 48(1):115.CrossRefGoogle Scholar
Hutchings, L, Pitcher, GC, Probyn, TA, Bailey, GW. 1995. The chemical and biological consequences of coastal upwelling. In: Summerhayes, CP, Emeis, KC, Angel, MV, Smith, RL, Zeitzschel, B, editors. Upwelling in the Ocean: Modern Processes and Ancient Records. Environmental Science Research Report ES 18. New York: Wiley. p 6583.Google Scholar
Key, RM, Quay, PD, Jones, GA, Schneider, RJ, McNichol, AP, von Reden, K, Schneider, RJ. 1996. WOCE AMS radiocarbon I: Pacific Ocean results (P6, P16, and P17). Radiocarbon 38(3):425518.CrossRefGoogle Scholar
Killingley, JS, Berger, WH. 1979. Stable isotopes in a mollusk shell: detection of upwelling events. Science 205(4402):186–8.CrossRefGoogle Scholar
Kroopnick, P, Deuser, WG, Craig, H. 1970. Carbon 13 measurements on dissolved inorganic carbon at the North Pacific (1969) Geosecs Station. Journal Geophysical Research 75(36):7668–71.CrossRefGoogle Scholar
McGowan, JA, Cayan, DR, Dorman, LM. 1998. Climate-ocean variability and ecosystem response in the Northeast Pacific. Science 281(5374):210–7.CrossRefGoogle ScholarPubMed
Masiello, CA, Druffel, ERM, Bauer, JE. 1998. Physical controls on dissolved inorganic radiocarbon variability in the California Current. Deep-Sea Research II 45(4–5):617–42.Google Scholar
McNaught, AD, Wilkinson, A. 1997. Compendium of Chemical Terminology. 2nd edition. Oxford: Blackwell Scientific.Google Scholar
McNichol, AP, Jones, GA. 1991. Measuring 14C in seawater ΣCO2 by accelerator mass spectrometry, WHP operations and methods. In: Joyce, T, Corry, C, Stalcup, M, editors. WOCE Operations and Methods Manual. Woods Hole, Massachusetts: WHPO Publication 90–1:71.Google Scholar
McNichol, AP, Jones, GA, Hutton, DL, Gagnon, AR. 1994. The rapid preparation of seawater ΣCO2 for radiocarbon analysis at the National Ocean Sciences AMS Facility. Radiocarbon 36(2):237–46.CrossRefGoogle Scholar
Östlund, HG, Stuiver, M. 1980. GEOSECS Pacific radiocarbon. Radiocarbon 22(1):2553.CrossRefGoogle Scholar
Panel on the Southern California Bight of the Committee on a Systems Assessment of Marine Environmental Monitoring (PSCB). 1990. Monitoring Southern California's Coastal Waters. National Research Council (U.S.): Commission on Engineering and Technical Systems. Washington, DC: National Academy Press, Marine Board.Google Scholar
Peterson, B, Emmett, R, Goerlicke, R, Venrick, E, Mantyla, A, Bogard, S, Schwing, F, Ralston, S, Forney, K, Hewitt, R, Lo, N, Watson, W, Barlow, J, Lowry, M, Lavaniegos, BE, Chavez, F, Sydeman, WJ, Hyrenbach, D, Bradley, RW, Warzybok, P, Hunter, K, Benson, S, Weise, M, Harvey, JT. 2006. The state of the California Current, 2005–2006: Warm in the north, cool in the south. California Cooperative Oceanographic Fisheries Investigation Data Report 47:3075.Google Scholar
Pickett, MH, Schwing, FB. 2006. Evaluating upwelling estimates off the west coasts of North and South America. Fisheries Oceanography 15(3): 256–9.CrossRefGoogle Scholar
Robinson, SW. 1981. Natural and man-made radiocarbon as a tracer for coastal upwelling processes. In: Richards, FA, editor. Coastal Upwelling. Washington, DC: American Geophysical Union. p 298302.CrossRefGoogle Scholar
Roemmich, D, McGowan, J. 1995. Climatic warming and the decline of zooplankton in the California Current. Science 267(5202):1324–6.CrossRefGoogle ScholarPubMed
Santos, GM, Southon, JR, Druffel-Rodriguez, KC, Griffin, S, Mazon, M. 2004. Magnesium perchlorate as an alternative water trap in AMS graphite sample preparation: a report on sample preparation at the KCCAMS Facility at the University of California, Irvine. Radiocarbon 46(1):165–73.CrossRefGoogle Scholar
Santos, GM, Moore, RB, Southon, JR, Griffin, S, Hinger, E, Zhang, D. 2007. AMS 14C sample preparation at the KCCAMS/UCI Facility: status report and performance of small samples. Radiocarbon 49(2):255–69.CrossRefGoogle Scholar
Schwing, FB, O'Farrell, M, Steger, JM, Baltz, KA. 1996. Coastal upwelling indices, west coast of North America, 1946–95. US Department of Commerce. NOAA-TM-NMFS-SWFSC-231. p 132.Google Scholar
Scott, ME, Boaretto, E, Bryant, C, Cook, GT, Gulliksen, S, Harkness, DD, Heinemeier, J, McGee, E, Naysmith, P, Possnert, G, van der Plicht, H, van Strydonck, M. 2004. Future needs and requirements for AMS 14C standards and reference materials. Nuclear Instruments and Methods in Physics Research B 223–224:382–7.Google Scholar
Sheu, DD, Lee, WY, Wang, CH, Wei, CL, Chen, CTA, Cherng, C, Huang, MH. 1996. Depth distribution of δ13C of dissolved ΣCO2 in seawater off eastern Taiwan: effects of Kuroshio current and its associated upwelling phenomenon. Continental Shelf Research 16(12):1609–19.CrossRefGoogle Scholar
Stuvier, M, Polach, H. 1977. Discussion: reporting of 14C data. Radiocarbon 19(3):355–63.Google Scholar
Tsuchiya, M. 1975. California Undercurrent in the South-em California Bight. California Cooperative Oceanographic Fisheries Investigation 18:155–8.Google Scholar