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The 14C Content of Lithium Metal Used in Benzene Synthesis

Published online by Cambridge University Press:  18 July 2016

C. J. Eastoe
Affiliation:
Department of Geosciences, The University of Arizona, Tucson, Arizona 85721 USA
Austin Long
Affiliation:
Department of Geosciences, The University of Arizona, Tucson, Arizona 85721 USA
Charles S. Tucek
Affiliation:
Department of Geosciences, The University of Arizona, Tucson, Arizona 85721 USA
A. J. T. Jull
Affiliation:
Department of Geosciences, The University of Arizona, Tucson, Arizona 85721 USA
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Abstract

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The lithium reagent used in the synthesis of benzene for 14C dating contributes insignificant 14C in high-precision measurements on 7 g benzene samples. Blank experiments on three different batches of lithium yielded small amounts of carbon, most of which probably originated as “memory” in the reaction vessel.

Type
Notes and Comments
Copyright
Copyright © The American Journal of Science 

References

Polach, H., Gower, J. and Fraser, I. 1973 Synthesis of high-purity benzene for radiocarbon dating. In Rafter, T. A. and Grant-Taylor, T., eds., Proceedings of the 8th International 14 C Conference. Vol. 1. Wellington, Royal Society of New Zealand: B36B49.Google Scholar
Slota, P. J. Jr., Jull, A. J. T., Linick, T. W. and Toolin, L. J. 1987 Preparation of small samples for 14C accelerator targets by catalytic reduction of CO. Radiocarbon. 29(2): 303306.CrossRefGoogle Scholar