Strontium-isotopic ratios of dated corals have been obtained from submerged reefs formed during Quaternary glacial periods off the Hawaiian islands. These data, combined with data from deep-sea sediments, tightly constrain the secular variation of marine 87Sr/86Sr for the past 800,000 yr. Although long-term trends are apparent, no significant (>0.02‰), rapid (<100,000 yr) excursions in 87Sr/86Sr were resolved nor did we observe any samples with 87Sr/86Sr greater than that of modern seawater. Strontium in mollusks from elevated marine terraces formed during interglacial periods on the southern California coast show resolvable and consistent variations in 87Sr/86Sr which, when compared to the trend of Quaternary marine 87Sr/86Sr, can be used to infer uplift rates and define approximate ages for the higher terraces. The Sr-isotope age estimates indicate that uplift rates vary among crustal blocks and were not necessarily constant with time. No contrast in Sr-isotopic ratios between similar-age Hawaiian and California fossils was observed, confirming that any change in marine 87Sr/86Sr from glacial to interglacial periods must be small. A realistic appraisal of the potential of Sr-isotope stratigraphy for chronometric applications in the Quaternary suggests that the technique will be limited to relatively coarse distinctions in age.

Thirty-two distal tephra layers that are interbedded in Quaternary loess at 13 sites in the Channeled Scabland and Palouse were sampled as part of a regional study of the stratigraphy and chronology of dominantly windblown sediments on the Columbia Plateau. An electron microprobe was used to determine the elemental composition of volcanic glass in all of the samples and also to determine the composition of ilmenite in 14 of them. Two of the distal tephra layers correlate with Glacier Peak eruptions (11,200 yr B.P.), five with Mount St. Helens tephra set S (13,000 yr B.P.), and nine with Mount St. Helens tephra set C (ca. 36,000 yr B.P.) based on analysis of glass and ilmenite in reference pumices from Glacier Peak, Mount St. Helens, Mount Mazama, Mount Rainier, and Mount Jefferson, on the calculation of similarity coefficients for comparisons of both glass and ilmenite reference compositions with those of distal tephras, and on considerations of stratigraphic position. The composition of glass and ilmenite and the stratigraphic position of one distal tephra layer in the loess suggests that it is from an eruption of Mount St. Helens at least several thousand years older than the set C eruptions. Glass composition and stratigraphic position of a distal tephra at another site in loess suggested a possible correlation with some layers of the Pumice Castle eruptive sequence at Mount Mazama (ca. 70,000 yr B.P.), but similarity coefficients on ilmenite of only 45 and 48 fail to support the correlation and show why multiple correlation methods should be used. Similarity coefficients higher than 96 for both glass and ilmenite establish a correlation with Mount St. Helens layer Cw for distal layers in two widely separated sites. These layers are in sedimentary successions that are closely associated with giant floods in the Channeled Scabland. The 36,000 yr B.P. radiocarbon age of the Mount St. Helens set C establishes a minimum limiting date for an episode of flooding that predates the widespread late Wisconsin floods. A correlation of distal tephra layers at two other sites in the Scabland and Palouse establishes a chronostratigraphic link to a still-older episode of flooding within the Brunhes Normal Polarity Chron. Six distal tephra layers in pre-late Quaternary loess that are not correlated with known or dated eruptions have compositions and distinctive stratigraphic positions relative to magnetic reversal boundaries that make them key markers for future work.

The δ18O and δ13C values of the calcites associated with E-W and NE-SW transverse faults in the Negev, Israel, indicate that calcite was deposited from meteoric water. A regional change in the δ18O and δ13C values was observed. The 18O content in the calcite increases, from the southwestern (δ18O = −17.8‰) to the northeastern (δ18O = −2.9‰) part of the region. The δ13C values show the opposite trend of the 13C content decrease: from +2‰ in the south to −10‰ in the northeast. These trends had to reflect changes in regional paleoclimate, suggesting a change in the isotopic composition of the solution from which the calcite was deposited in different periods. The variations in the δ18O values reflect shifts in the δ18O values of precipitation and are associated with a change in the source of moist air masses which came from the equatorial Atlantic in the early Pleistocene and from the Mediterranean during a later period. Variations in δ13C values reflect changes from humid to arid conditions. Two modes of calcite deposition are suggested: (1) precipitation of calcite minerals in the unsaturated zone following the dissolution in the soil or (2) calcite deposition that occurred as CO2 was lost during emergence of paleogroundwater from Lower Cretaceous and Jurassic aquifers.

Alluvium in one reach of the Republican River valley, south-central Nebraska, dates to the Holocene. Radiocarbon dating of fills underlying the two terraces in the valley reveals that entrenchment between 4500 and 3700 yr B.P. formed the high terrace. Subsequently, alternating aggradation and stability occurred until sometime between 1800 and 1100 yr B.P. Following another period of alluviation, channel incision formed the low terrace. General synchrony between this chronology and other late Holocene fluvial chronologies of the central Great Plains suggests climatic control of fluvial activity. The episodes of incision are tentatively correlated with different climate regimes, illustrating the difficulty of attributing a given fluvial response to a particular direction of climatic change.

As the age of the soils in a chronosequence on the California coast increases, the difference between the magnetic susceptibility of eluvial and illuvial horizons increases, and the residual susceptibility after extraction with citrate-bicarbonate-dithionite (CBD) decreases. Enhanced susceptibility results from the conversion of nonferrimagnetic minerals to secondary ferrimagnetic forms (most likely maghemite) and the preferential accumulation of inherited and pedogenic magnetic minerals. Little enhancement occurs for pedons younger than 40,000 yr. By 124,000 yr, most of the magnetic susceptibility can be attributed to forms soluble in CBD. Magnetic susceptibility appears to vary systematically over time for three chronosequences from areas with mean annual precipitation ranging from 650 to 1500 mm yr−1. Magnetic susceptibility enhancement may be a useful parameter for estimating soil age in certain climates.

Carbon-13 profiles and radiocarbon dates were obtained from two Canadian kettle basins having similar geological and hydrological characteristics to develop criteria for evaluating the validity of radiocarbon dates on lake sediment from basins in calcareous terrain. Radiocarbon dates from a site in Alberta show a variable hard-water effect related to local hydrological changes during postglacial history of the lake basin, whereas radiocarbon dates from the other site in Ontario show no noticeable influence of old carbon during its history. These differences are mainly related to lake water residence time, which has influenced carbon isotopic exchange between atmospheric CO2 and dissolved inorganic carbon in lake water. δ13C values for bulk organic sediment and terrestrial and aquatic macrofossils reveal that the main component of lake sediment at both sites is autocthonous in origin. Furthermore, each site supported different submerged aquatic plant communities that used different sources of carbon for photosynthesis, thereby imprinting the organic sediments with a characteristic 13C composition. Both sites reflect a clear relationship between 13C values and paleoproductivity. This study shows the individualistic response of the developing lake system to the hydrology, lake biota, and local geology, and demonstrates the problem of using 13C in lake sediments as a single criterion to recognize the validity of radiocarbon dates of lake sediment without supporting paleoecological information.

The Japan Sea was profoundly different during glacial times than today. Available δ18O evidence indicates that sea surface salinity was lower by several per mil. This probably increased the stability of the water column and caused anoxic sedimentary conditions in the deep sea, as shown by the absence of benthic microfossils and the presence of laminated sediment. These changes are likely related to the effects of late Quaternary sea-level change on the shallow sills (ca. 130 m) across which the Japan Sea exchanges with the open ocean. The Hwang He (Yellow River) has previously been implicated as the source of fresh water to the Japan Sea during glaciation, but the possible roles of the Amur River and excess precipitation over evaporation must also be considered. Ambiguous radiocarbon chronologies for the latest Quaternary of Japan Sea cores do not adequately constrain the timing of salinity lowering. Previous studies have suggested that lowest sea surface salinity was achieved 27,000 to 20,000 14C yr B.P. However, if global sea-level fall restricted exchange with the open ocean circulation, then lowest salinity in the Japan Sea may have occurred as recently as 15,000 to 20,000 yr ago when sea level was lowest. If this alternative is correct, then as sea level abruptly rose about 12,000 yr ago, relatively fresh water must have been discharged to the open Pacific. This might have affected the dynamics of outflow, local faunal and floral expression of the polar front, and stable isotope ratios in foraminifera. These environmental changes could be misinterpreted as evidence for the cooling of Younger Dryas age, which has not been identified in nearby terrestrial records.

A transfer function has been established to quantify the dissolution of diatom silica in Southern Ocean sediments. The relationship between the amount of silica dissolution and changes in diatom species distribution is built by controlled progressive dissolution of biogenic silica in five recent sediment samples from box-core tops, each representative of a modern diatom species sediment assemblage. The amount of dissolved silica was measured for each experiment. The resulting data set of species abundances (42 samples containing 32 diatom species and 2 silicoflagellate genera) was added to the modern data base of diatom species distributed over the Southern Ocean (124 core tops). Q-mode factor analysis individualizes four factors explaining 83% of the variance. The first three factors are controlled by surface water properties (mostly temperature). The fourth factor is the only one correlated with loss of silica in the reference samples (R = 0.900). We quantified the dissolution factor using this correlation: superficial sediments of the Southeast Indian Ocean are characterized, from low to high latitudes, by a decrease in silica loss by dissolution (from >50 to 10%) from the Subantarctic Zone (40°S) to around 55°S, followed by an increase of silica loss to values larger than 60% between 63° and 68°S. Application of the dissolution factor in two cores from the Southern Ocean (≈44° and 55°S) shows enhanced opal dissolution during the last glaciation, particularly during Emiliani's stage 3 (from 40,000 to 30,000 yr B.P.).

Four pollen sequences along a transect from north-central Iowa to southeast Wisconsin reveal the distribution of prairie and forest during the Holocene and test the use of pollen isopolls in locating the Holocene prairie-forest border. Prairie was dominant in central Iowa and climate was drier than present from about 8000 to 3000 yr B.P. During the driest part of this period in central Iowa (6500-5500 yr B.P.), mesic forest prevailed in eastern Iowa and Wisconsin, suggesting conditions wetter than at present. Prairie replaced the mesic forest about 5400 yr B.P. in eastern Iowa but did not extend much farther east; mesic forests were replaced in southern Wisconsin and northern Illinois about 5400 yr B.P. by xeric oak forests. This change from mesic to xeric conditions at 5400 yr B.P. was widespread and suggests that the intrusion of drier Pacific air was blocked by maritime tropical air from the Gulf of Mexico until the late Holocene in this area.

TL dating of both quartz and potassium feldspar grains from the Pleistocene beach of Sangatte, at the southern limit of the North Sea Basin, give self-consistent ages of 200,000 ± 45,000, 205,000 ± 14,000, and 229,000 ± 18,000 years, respectively. These results allow the beach deposits to be correlated with oxygen isotope stage 7 (244,000–190,000 yr) (Martinson et al., 1987). The existence of a fossil beach cliff line at 10 m above French O.D. demonstrates that the Strait of Dover was open during the penultimate interglaciation.